Hexakis(2-amino-4-methyl­pyridine-κN (1))dioxidohexa-μ(4)-sulfido-hexa­copper(I)divanadium(V)

The title compound, [Cu(6)V(2)O(2)S(6)(C(6)H(8)N(2))(6)], is constructed from six CuS(3)N and two VOS(3) distorted tetra­hedra, forming an octa­nuclear V/S/Cu cluster with C (i) symmetry. The geometry around the V atoms is slightly distorted tetra­hedral, while there are large distortions from ideal...

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Detalles Bibliográficos
Autores principales: Yu, Zhang, Tang, Guodong, Zhao, Jianying, Jiang, Zhengjing
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960477/
https://www.ncbi.nlm.nih.gov/pubmed/21201649
http://dx.doi.org/10.1107/S1600536808027165
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author Yu, Zhang
Tang, Guodong
Zhao, Jianying
Jiang, Zhengjing
author_facet Yu, Zhang
Tang, Guodong
Zhao, Jianying
Jiang, Zhengjing
author_sort Yu, Zhang
collection PubMed
description The title compound, [Cu(6)V(2)O(2)S(6)(C(6)H(8)N(2))(6)], is constructed from six CuS(3)N and two VOS(3) distorted tetra­hedra, forming an octa­nuclear V/S/Cu cluster with C (i) symmetry. The geometry around the V atoms is slightly distorted tetra­hedral, while there are large distortions from ideal tetra­hedral geometry for the Cu atoms. Adjacent metal–metal distances range from 2.693 (1) to 2.772 (10) Å, indicating weak metal–metal inter­actions in the cluster.
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spelling pubmed-29604772010-12-30 Hexakis(2-amino-4-methyl­pyridine-κN (1))dioxidohexa-μ(4)-sulfido-hexa­copper(I)divanadium(V) Yu, Zhang Tang, Guodong Zhao, Jianying Jiang, Zhengjing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(6)V(2)O(2)S(6)(C(6)H(8)N(2))(6)], is constructed from six CuS(3)N and two VOS(3) distorted tetra­hedra, forming an octa­nuclear V/S/Cu cluster with C (i) symmetry. The geometry around the V atoms is slightly distorted tetra­hedral, while there are large distortions from ideal tetra­hedral geometry for the Cu atoms. Adjacent metal–metal distances range from 2.693 (1) to 2.772 (10) Å, indicating weak metal–metal inter­actions in the cluster. International Union of Crystallography 2008-08-30 /pmc/articles/PMC2960477/ /pubmed/21201649 http://dx.doi.org/10.1107/S1600536808027165 Text en © Yu et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yu, Zhang
Tang, Guodong
Zhao, Jianying
Jiang, Zhengjing
Hexakis(2-amino-4-methyl­pyridine-κN (1))dioxidohexa-μ(4)-sulfido-hexa­copper(I)divanadium(V)
title Hexakis(2-amino-4-methyl­pyridine-κN (1))dioxidohexa-μ(4)-sulfido-hexa­copper(I)divanadium(V)
title_full Hexakis(2-amino-4-methyl­pyridine-κN (1))dioxidohexa-μ(4)-sulfido-hexa­copper(I)divanadium(V)
title_fullStr Hexakis(2-amino-4-methyl­pyridine-κN (1))dioxidohexa-μ(4)-sulfido-hexa­copper(I)divanadium(V)
title_full_unstemmed Hexakis(2-amino-4-methyl­pyridine-κN (1))dioxidohexa-μ(4)-sulfido-hexa­copper(I)divanadium(V)
title_short Hexakis(2-amino-4-methyl­pyridine-κN (1))dioxidohexa-μ(4)-sulfido-hexa­copper(I)divanadium(V)
title_sort hexakis(2-amino-4-methyl­pyridine-κn (1))dioxidohexa-μ(4)-sulfido-hexa­copper(i)divanadium(v)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960477/
https://www.ncbi.nlm.nih.gov/pubmed/21201649
http://dx.doi.org/10.1107/S1600536808027165
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