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The cocrystal μ-oxalato-κ(4) O (1),O (2):O (1′),O (2′)-bis(aqua(nitrato-κO){[1-(2-pyridyl-κN)ethylidene]hydrazine-κN}copper(II)) μ-oxalato-κ(4) O (1),O (2):O (1′),O (2′)-bis((methanol-κO)(nitrato-κO){[1-(2-pyridyl-κN)ethylidene]hydrazine-κN}copper(II)) (1/1)
The title cocrystal, [Cu(2)(C(2)O(4))(NO(3))(2)(C(7)H(9)N(3))(2)(H(2)O)(2)][Cu(2)(C(2)O(4))(NO(3))(2)(C(7)H(9)N(3))(2)(CH(4)O)(2)], is a 1:1 cocrystal of two centrosymmetric Cu(II) complexes with oxalate dianions and Schiff base ligands. In each molecule, the Cu(II) centre is in a distorted octahe...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960478/ https://www.ncbi.nlm.nih.gov/pubmed/21201585 http://dx.doi.org/10.1107/S1600536808024550 |
| _version_ | 1782188749389561856 |
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| author | Diallo, Madina Tamboura, Farba Bouyagui Gaye, Mohamed Barry, Aliou Hamady Bah, Youssouph |
| author_facet | Diallo, Madina Tamboura, Farba Bouyagui Gaye, Mohamed Barry, Aliou Hamady Bah, Youssouph |
| author_sort | Diallo, Madina |
| collection | PubMed |
| description | The title cocrystal, [Cu(2)(C(2)O(4))(NO(3))(2)(C(7)H(9)N(3))(2)(H(2)O)(2)][Cu(2)(C(2)O(4))(NO(3))(2)(C(7)H(9)N(3))(2)(CH(4)O)(2)], is a 1:1 cocrystal of two centrosymmetric Cu(II) complexes with oxalate dianions and Schiff base ligands. In each molecule, the Cu(II) centre is in a distorted octahedral cis-CuN(2)O(4) environment, the donor atoms of the N,N′-bidentate Schiff base ligand and the bridging O,O′-bidentate oxalate group lying in the equatorial plane. In one molecule, a monodentate nitrate anion and a water molecule occupy the axial sites, and in the other, a monodentate nitrate anion and a methanol molecule occupy these sites. In the crystal structure, intermolecular N—H⋯O, O—H⋯O and N—H⋯N hydrogen bonds link the molecules into a network. Weak intramolecular N—H⋯O interactions are also observed. |
| format | Text |
| id | pubmed-2960478 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29604782010-12-30 The cocrystal μ-oxalato-κ(4) O (1),O (2):O (1′),O (2′)-bis(aqua(nitrato-κO){[1-(2-pyridyl-κN)ethylidene]hydrazine-κN}copper(II)) μ-oxalato-κ(4) O (1),O (2):O (1′),O (2′)-bis((methanol-κO)(nitrato-κO){[1-(2-pyridyl-κN)ethylidene]hydrazine-κN}copper(II)) (1/1) Diallo, Madina Tamboura, Farba Bouyagui Gaye, Mohamed Barry, Aliou Hamady Bah, Youssouph Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title cocrystal, [Cu(2)(C(2)O(4))(NO(3))(2)(C(7)H(9)N(3))(2)(H(2)O)(2)][Cu(2)(C(2)O(4))(NO(3))(2)(C(7)H(9)N(3))(2)(CH(4)O)(2)], is a 1:1 cocrystal of two centrosymmetric Cu(II) complexes with oxalate dianions and Schiff base ligands. In each molecule, the Cu(II) centre is in a distorted octahedral cis-CuN(2)O(4) environment, the donor atoms of the N,N′-bidentate Schiff base ligand and the bridging O,O′-bidentate oxalate group lying in the equatorial plane. In one molecule, a monodentate nitrate anion and a water molecule occupy the axial sites, and in the other, a monodentate nitrate anion and a methanol molecule occupy these sites. In the crystal structure, intermolecular N—H⋯O, O—H⋯O and N—H⋯N hydrogen bonds link the molecules into a network. Weak intramolecular N—H⋯O interactions are also observed. International Union of Crystallography 2008-08-06 /pmc/articles/PMC2960478/ /pubmed/21201585 http://dx.doi.org/10.1107/S1600536808024550 Text en © Diallo et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Diallo, Madina Tamboura, Farba Bouyagui Gaye, Mohamed Barry, Aliou Hamady Bah, Youssouph The cocrystal μ-oxalato-κ(4) O (1),O (2):O (1′),O (2′)-bis(aqua(nitrato-κO){[1-(2-pyridyl-κN)ethylidene]hydrazine-κN}copper(II)) μ-oxalato-κ(4) O (1),O (2):O (1′),O (2′)-bis((methanol-κO)(nitrato-κO){[1-(2-pyridyl-κN)ethylidene]hydrazine-κN}copper(II)) (1/1) |
| title | The cocrystal μ-oxalato-κ(4)
O
(1),O
(2):O
(1′),O
(2′)-bis(aqua(nitrato-κO){[1-(2-pyridyl-κN)ethylidene]hydrazine-κN}copper(II)) μ-oxalato-κ(4)
O
(1),O
(2):O
(1′),O
(2′)-bis((methanol-κO)(nitrato-κO){[1-(2-pyridyl-κN)ethylidene]hydrazine-κN}copper(II)) (1/1) |
| title_full | The cocrystal μ-oxalato-κ(4)
O
(1),O
(2):O
(1′),O
(2′)-bis(aqua(nitrato-κO){[1-(2-pyridyl-κN)ethylidene]hydrazine-κN}copper(II)) μ-oxalato-κ(4)
O
(1),O
(2):O
(1′),O
(2′)-bis((methanol-κO)(nitrato-κO){[1-(2-pyridyl-κN)ethylidene]hydrazine-κN}copper(II)) (1/1) |
| title_fullStr | The cocrystal μ-oxalato-κ(4)
O
(1),O
(2):O
(1′),O
(2′)-bis(aqua(nitrato-κO){[1-(2-pyridyl-κN)ethylidene]hydrazine-κN}copper(II)) μ-oxalato-κ(4)
O
(1),O
(2):O
(1′),O
(2′)-bis((methanol-κO)(nitrato-κO){[1-(2-pyridyl-κN)ethylidene]hydrazine-κN}copper(II)) (1/1) |
| title_full_unstemmed | The cocrystal μ-oxalato-κ(4)
O
(1),O
(2):O
(1′),O
(2′)-bis(aqua(nitrato-κO){[1-(2-pyridyl-κN)ethylidene]hydrazine-κN}copper(II)) μ-oxalato-κ(4)
O
(1),O
(2):O
(1′),O
(2′)-bis((methanol-κO)(nitrato-κO){[1-(2-pyridyl-κN)ethylidene]hydrazine-κN}copper(II)) (1/1) |
| title_short | The cocrystal μ-oxalato-κ(4)
O
(1),O
(2):O
(1′),O
(2′)-bis(aqua(nitrato-κO){[1-(2-pyridyl-κN)ethylidene]hydrazine-κN}copper(II)) μ-oxalato-κ(4)
O
(1),O
(2):O
(1′),O
(2′)-bis((methanol-κO)(nitrato-κO){[1-(2-pyridyl-κN)ethylidene]hydrazine-κN}copper(II)) (1/1) |
| title_sort | cocrystal μ-oxalato-κ(4)
o
(1),o
(2):o
(1′),o
(2′)-bis(aqua(nitrato-κo){[1-(2-pyridyl-κn)ethylidene]hydrazine-κn}copper(ii)) μ-oxalato-κ(4)
o
(1),o
(2):o
(1′),o
(2′)-bis((methanol-κo)(nitrato-κo){[1-(2-pyridyl-κn)ethylidene]hydrazine-κn}copper(ii)) (1/1) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960478/ https://www.ncbi.nlm.nih.gov/pubmed/21201585 http://dx.doi.org/10.1107/S1600536808024550 |
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