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(E)-N′-Benzylidene-p-toluenesulfonohydrazide
In the title compound, C(14)H(14)N(2)O(2)S, a novel sulfonamide derivative, an intramolecular C—H⋯O hydrogen bond generates an S(5) ring motif. The molecule adopts a twisted E configuration around the C=N bond. An intermolecular N—H⋯O hydrogen bond generates an R (2) (2)(8) ring motif. The dihedr...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960482/ https://www.ncbi.nlm.nih.gov/pubmed/21201816 http://dx.doi.org/10.1107/S1600536808027219 |
Sumario: | In the title compound, C(14)H(14)N(2)O(2)S, a novel sulfonamide derivative, an intramolecular C—H⋯O hydrogen bond generates an S(5) ring motif. The molecule adopts a twisted E configuration around the C=N bond. An intermolecular N—H⋯O hydrogen bond generates an R (2) (2)(8) ring motif. The dihedral angle between the rings is 85.37 (9)°. The H atoms of the methyl group have rotational disorder with refined site occupancies of ca 0.63/0.37. In the crystal structure, intermolecular N—H⋯O hydrogen bonds link neighbouring molecules into dimers which stack along the a axis with a centroid–centroid distance of 3.8856 (10) Å. |
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