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(E)-N′-Benzyl­idene-p-toluene­sulfono­hydrazide

In the title compound, C(14)H(14)N(2)O(2)S, a novel sulfonamide derivative, an intra­molecular C—H⋯O hydrogen bond generates an S(5) ring motif. The mol­ecule adopts a twisted E configuration around the C=N bond. An inter­molecular N—H⋯O hydrogen bond generates an R (2) (2)(8) ring motif. The dihedr...

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Detalles Bibliográficos
Autores principales: Mehrabi, Hossein, Kia, Reza, Hassanzadeh, Ali, Ghobadi, Samaneh, Khavasi, Hamid Reza
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960482/
https://www.ncbi.nlm.nih.gov/pubmed/21201816
http://dx.doi.org/10.1107/S1600536808027219
Descripción
Sumario:In the title compound, C(14)H(14)N(2)O(2)S, a novel sulfonamide derivative, an intra­molecular C—H⋯O hydrogen bond generates an S(5) ring motif. The mol­ecule adopts a twisted E configuration around the C=N bond. An inter­molecular N—H⋯O hydrogen bond generates an R (2) (2)(8) ring motif. The dihedral angle between the rings is 85.37 (9)°. The H atoms of the methyl group have rotational disorder with refined site occupancies of ca 0.63/0.37. In the crystal structure, inter­molecular N—H⋯O hydrogen bonds link neighbouring mol­ecules into dimers which stack along the a axis with a centroid–centroid distance of 3.8856 (10) Å.