(E)-N′-Benzyl­idene-p-toluene­sulfono­hydrazide

In the title compound, C(14)H(14)N(2)O(2)S, a novel sulfonamide derivative, an intra­molecular C—H⋯O hydrogen bond generates an S(5) ring motif. The mol­ecule adopts a twisted E configuration around the C=N bond. An inter­molecular N—H⋯O hydrogen bond generates an R (2) (2)(8) ring motif. The dihedr...

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Autores principales: Mehrabi, Hossein, Kia, Reza, Hassanzadeh, Ali, Ghobadi, Samaneh, Khavasi, Hamid Reza
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960482/
https://www.ncbi.nlm.nih.gov/pubmed/21201816
http://dx.doi.org/10.1107/S1600536808027219
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author Mehrabi, Hossein
Kia, Reza
Hassanzadeh, Ali
Ghobadi, Samaneh
Khavasi, Hamid Reza
author_facet Mehrabi, Hossein
Kia, Reza
Hassanzadeh, Ali
Ghobadi, Samaneh
Khavasi, Hamid Reza
author_sort Mehrabi, Hossein
collection PubMed
description In the title compound, C(14)H(14)N(2)O(2)S, a novel sulfonamide derivative, an intra­molecular C—H⋯O hydrogen bond generates an S(5) ring motif. The mol­ecule adopts a twisted E configuration around the C=N bond. An inter­molecular N—H⋯O hydrogen bond generates an R (2) (2)(8) ring motif. The dihedral angle between the rings is 85.37 (9)°. The H atoms of the methyl group have rotational disorder with refined site occupancies of ca 0.63/0.37. In the crystal structure, inter­molecular N—H⋯O hydrogen bonds link neighbouring mol­ecules into dimers which stack along the a axis with a centroid–centroid distance of 3.8856 (10) Å.
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spelling pubmed-29604822010-12-30 (E)-N′-Benzyl­idene-p-toluene­sulfono­hydrazide Mehrabi, Hossein Kia, Reza Hassanzadeh, Ali Ghobadi, Samaneh Khavasi, Hamid Reza Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(14)N(2)O(2)S, a novel sulfonamide derivative, an intra­molecular C—H⋯O hydrogen bond generates an S(5) ring motif. The mol­ecule adopts a twisted E configuration around the C=N bond. An inter­molecular N—H⋯O hydrogen bond generates an R (2) (2)(8) ring motif. The dihedral angle between the rings is 85.37 (9)°. The H atoms of the methyl group have rotational disorder with refined site occupancies of ca 0.63/0.37. In the crystal structure, inter­molecular N—H⋯O hydrogen bonds link neighbouring mol­ecules into dimers which stack along the a axis with a centroid–centroid distance of 3.8856 (10) Å. International Union of Crystallography 2008-08-30 /pmc/articles/PMC2960482/ /pubmed/21201816 http://dx.doi.org/10.1107/S1600536808027219 Text en © Mehrabi et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Mehrabi, Hossein
Kia, Reza
Hassanzadeh, Ali
Ghobadi, Samaneh
Khavasi, Hamid Reza
(E)-N′-Benzyl­idene-p-toluene­sulfono­hydrazide
title (E)-N′-Benzyl­idene-p-toluene­sulfono­hydrazide
title_full (E)-N′-Benzyl­idene-p-toluene­sulfono­hydrazide
title_fullStr (E)-N′-Benzyl­idene-p-toluene­sulfono­hydrazide
title_full_unstemmed (E)-N′-Benzyl­idene-p-toluene­sulfono­hydrazide
title_short (E)-N′-Benzyl­idene-p-toluene­sulfono­hydrazide
title_sort (e)-n′-benzyl­idene-p-toluene­sulfono­hydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960482/
https://www.ncbi.nlm.nih.gov/pubmed/21201816
http://dx.doi.org/10.1107/S1600536808027219
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AT ghobadisamaneh enbenzylideneptoluenesulfonohydrazide
AT khavasihamidreza enbenzylideneptoluenesulfonohydrazide

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