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(E)-3-(2,4-Dichloro­phen­yl)-1-(2-thien­yl)prop-2-en-1-one

In the title chalcone derivative, C(13)H(8)Cl(2)OS, the prop-2-en-1-one unit and the thio­phene and 2,4-dichloro­phenyl rings are each essentially planar. The inter­planar angle between the thio­phene and 2,4-dichloro­phenyl rings is 19.87 (6)°. Weak intra­molecular C—H⋯O and C—H⋯Cl inter­actions in...

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Autores principales: Fun, Hoong-Kun, Patil, P. S., Dharmaprakash, S. M., Chantrapromma, Suchada, Razak, Ibrahim Abdul
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960483/
https://www.ncbi.nlm.nih.gov/pubmed/21201791
http://dx.doi.org/10.1107/S1600536808026524
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author Fun, Hoong-Kun
Patil, P. S.
Dharmaprakash, S. M.
Chantrapromma, Suchada
Razak, Ibrahim Abdul
author_facet Fun, Hoong-Kun
Patil, P. S.
Dharmaprakash, S. M.
Chantrapromma, Suchada
Razak, Ibrahim Abdul
author_sort Fun, Hoong-Kun
collection PubMed
description In the title chalcone derivative, C(13)H(8)Cl(2)OS, the prop-2-en-1-one unit and the thio­phene and 2,4-dichloro­phenyl rings are each essentially planar. The inter­planar angle between the thio­phene and 2,4-dichloro­phenyl rings is 19.87 (6)°. Weak intra­molecular C—H⋯O and C—H⋯Cl inter­actions involving the prop-2-en-1-one unit generate an S(5)S(5) ring motif. In the crystal structure, mol­ecules are linked into head-to-tail zigzag chains along the a axis and adjacent chains are cross-linked. These cross-linked chains are arranged into sheets parallel to the ab plane. The crystal structure is stabilized by weak C—H⋯O, C—H⋯Cl and C—H⋯π inter­actions. A π–π inter­action was also observed with a centroid–centroid distance of 3.6845 (6) Å.
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spelling pubmed-29604832010-12-30 (E)-3-(2,4-Dichloro­phen­yl)-1-(2-thien­yl)prop-2-en-1-one Fun, Hoong-Kun Patil, P. S. Dharmaprakash, S. M. Chantrapromma, Suchada Razak, Ibrahim Abdul Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title chalcone derivative, C(13)H(8)Cl(2)OS, the prop-2-en-1-one unit and the thio­phene and 2,4-dichloro­phenyl rings are each essentially planar. The inter­planar angle between the thio­phene and 2,4-dichloro­phenyl rings is 19.87 (6)°. Weak intra­molecular C—H⋯O and C—H⋯Cl inter­actions involving the prop-2-en-1-one unit generate an S(5)S(5) ring motif. In the crystal structure, mol­ecules are linked into head-to-tail zigzag chains along the a axis and adjacent chains are cross-linked. These cross-linked chains are arranged into sheets parallel to the ab plane. The crystal structure is stabilized by weak C—H⋯O, C—H⋯Cl and C—H⋯π inter­actions. A π–π inter­action was also observed with a centroid–centroid distance of 3.6845 (6) Å. International Union of Crystallography 2008-08-23 /pmc/articles/PMC2960483/ /pubmed/21201791 http://dx.doi.org/10.1107/S1600536808026524 Text en © Fun et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Patil, P. S.
Dharmaprakash, S. M.
Chantrapromma, Suchada
Razak, Ibrahim Abdul
(E)-3-(2,4-Dichloro­phen­yl)-1-(2-thien­yl)prop-2-en-1-one
title (E)-3-(2,4-Dichloro­phen­yl)-1-(2-thien­yl)prop-2-en-1-one
title_full (E)-3-(2,4-Dichloro­phen­yl)-1-(2-thien­yl)prop-2-en-1-one
title_fullStr (E)-3-(2,4-Dichloro­phen­yl)-1-(2-thien­yl)prop-2-en-1-one
title_full_unstemmed (E)-3-(2,4-Dichloro­phen­yl)-1-(2-thien­yl)prop-2-en-1-one
title_short (E)-3-(2,4-Dichloro­phen­yl)-1-(2-thien­yl)prop-2-en-1-one
title_sort (e)-3-(2,4-dichloro­phen­yl)-1-(2-thien­yl)prop-2-en-1-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960483/
https://www.ncbi.nlm.nih.gov/pubmed/21201791
http://dx.doi.org/10.1107/S1600536808026524
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