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(E)-3-(2,4-Dichlorophenyl)-1-(2-thienyl)prop-2-en-1-one
In the title chalcone derivative, C(13)H(8)Cl(2)OS, the prop-2-en-1-one unit and the thiophene and 2,4-dichlorophenyl rings are each essentially planar. The interplanar angle between the thiophene and 2,4-dichlorophenyl rings is 19.87 (6)°. Weak intramolecular C—H⋯O and C—H⋯Cl interactions in...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960483/ https://www.ncbi.nlm.nih.gov/pubmed/21201791 http://dx.doi.org/10.1107/S1600536808026524 |
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author | Fun, Hoong-Kun Patil, P. S. Dharmaprakash, S. M. Chantrapromma, Suchada Razak, Ibrahim Abdul |
author_facet | Fun, Hoong-Kun Patil, P. S. Dharmaprakash, S. M. Chantrapromma, Suchada Razak, Ibrahim Abdul |
author_sort | Fun, Hoong-Kun |
collection | PubMed |
description | In the title chalcone derivative, C(13)H(8)Cl(2)OS, the prop-2-en-1-one unit and the thiophene and 2,4-dichlorophenyl rings are each essentially planar. The interplanar angle between the thiophene and 2,4-dichlorophenyl rings is 19.87 (6)°. Weak intramolecular C—H⋯O and C—H⋯Cl interactions involving the prop-2-en-1-one unit generate an S(5)S(5) ring motif. In the crystal structure, molecules are linked into head-to-tail zigzag chains along the a axis and adjacent chains are cross-linked. These cross-linked chains are arranged into sheets parallel to the ab plane. The crystal structure is stabilized by weak C—H⋯O, C—H⋯Cl and C—H⋯π interactions. A π–π interaction was also observed with a centroid–centroid distance of 3.6845 (6) Å. |
format | Text |
id | pubmed-2960483 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29604832010-12-30 (E)-3-(2,4-Dichlorophenyl)-1-(2-thienyl)prop-2-en-1-one Fun, Hoong-Kun Patil, P. S. Dharmaprakash, S. M. Chantrapromma, Suchada Razak, Ibrahim Abdul Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title chalcone derivative, C(13)H(8)Cl(2)OS, the prop-2-en-1-one unit and the thiophene and 2,4-dichlorophenyl rings are each essentially planar. The interplanar angle between the thiophene and 2,4-dichlorophenyl rings is 19.87 (6)°. Weak intramolecular C—H⋯O and C—H⋯Cl interactions involving the prop-2-en-1-one unit generate an S(5)S(5) ring motif. In the crystal structure, molecules are linked into head-to-tail zigzag chains along the a axis and adjacent chains are cross-linked. These cross-linked chains are arranged into sheets parallel to the ab plane. The crystal structure is stabilized by weak C—H⋯O, C—H⋯Cl and C—H⋯π interactions. A π–π interaction was also observed with a centroid–centroid distance of 3.6845 (6) Å. International Union of Crystallography 2008-08-23 /pmc/articles/PMC2960483/ /pubmed/21201791 http://dx.doi.org/10.1107/S1600536808026524 Text en © Fun et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Fun, Hoong-Kun Patil, P. S. Dharmaprakash, S. M. Chantrapromma, Suchada Razak, Ibrahim Abdul (E)-3-(2,4-Dichlorophenyl)-1-(2-thienyl)prop-2-en-1-one |
title | (E)-3-(2,4-Dichlorophenyl)-1-(2-thienyl)prop-2-en-1-one |
title_full | (E)-3-(2,4-Dichlorophenyl)-1-(2-thienyl)prop-2-en-1-one |
title_fullStr | (E)-3-(2,4-Dichlorophenyl)-1-(2-thienyl)prop-2-en-1-one |
title_full_unstemmed | (E)-3-(2,4-Dichlorophenyl)-1-(2-thienyl)prop-2-en-1-one |
title_short | (E)-3-(2,4-Dichlorophenyl)-1-(2-thienyl)prop-2-en-1-one |
title_sort | (e)-3-(2,4-dichlorophenyl)-1-(2-thienyl)prop-2-en-1-one |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960483/ https://www.ncbi.nlm.nih.gov/pubmed/21201791 http://dx.doi.org/10.1107/S1600536808026524 |
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