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4,4′-Dimethoxy-2,2′-[1,1′-(propane-1,3-diyldinitrilo)diethylidyne]diphenol

In the crystal structure, the title Schiff base compound, C(21)H(26)N(2)O(4), has twofold rotation symmetry. The imino group is coplanar with the aromatic ring. An intra­molecular O—H⋯N hydrogen bond forms a six- membered ring, producing an S(6) ring motif. The two benzene rings are almost perpendic...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Kia, Reza
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960484/
https://www.ncbi.nlm.nih.gov/pubmed/21201652
http://dx.doi.org/10.1107/S1600536808023738
Descripción
Sumario:In the crystal structure, the title Schiff base compound, C(21)H(26)N(2)O(4), has twofold rotation symmetry. The imino group is coplanar with the aromatic ring. An intra­molecular O—H⋯N hydrogen bond forms a six- membered ring, producing an S(6) ring motif. The two benzene rings are almost perpendicular to each other, making a dihedral angle of 85.00 (2)°. The meth­oxy group is approximately coplanar with the benzene ring, with a C—O—C—C torsion angle of 2.34 (12)°. Neighbouring mol­ecules are linked together by weak inter­molecular C—H⋯O hydrogen bonds and a C—H⋯π inter­action, forming a sheet parallel to the ab plane. The mol­ecules also adopt a zigzag arrangement along the c axis.