Cargando…

4,4′-Dimethoxy-2,2′-[1,1′-(propane-1,3-diyldinitrilo)diethylidyne]diphenol

In the crystal structure, the title Schiff base compound, C(21)H(26)N(2)O(4), has twofold rotation symmetry. The imino group is coplanar with the aromatic ring. An intra­molecular O—H⋯N hydrogen bond forms a six- membered ring, producing an S(6) ring motif. The two benzene rings are almost perpendic...

Descripción completa

Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Kia, Reza
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960484/
https://www.ncbi.nlm.nih.gov/pubmed/21201652
http://dx.doi.org/10.1107/S1600536808023738
_version_ 1782188750798848000
author Fun, Hoong-Kun
Kia, Reza
author_facet Fun, Hoong-Kun
Kia, Reza
author_sort Fun, Hoong-Kun
collection PubMed
description In the crystal structure, the title Schiff base compound, C(21)H(26)N(2)O(4), has twofold rotation symmetry. The imino group is coplanar with the aromatic ring. An intra­molecular O—H⋯N hydrogen bond forms a six- membered ring, producing an S(6) ring motif. The two benzene rings are almost perpendicular to each other, making a dihedral angle of 85.00 (2)°. The meth­oxy group is approximately coplanar with the benzene ring, with a C—O—C—C torsion angle of 2.34 (12)°. Neighbouring mol­ecules are linked together by weak inter­molecular C—H⋯O hydrogen bonds and a C—H⋯π inter­action, forming a sheet parallel to the ab plane. The mol­ecules also adopt a zigzag arrangement along the c axis.
format Text
id pubmed-2960484
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29604842010-12-30 4,4′-Dimethoxy-2,2′-[1,1′-(propane-1,3-diyldinitrilo)diethylidyne]diphenol Fun, Hoong-Kun Kia, Reza Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure, the title Schiff base compound, C(21)H(26)N(2)O(4), has twofold rotation symmetry. The imino group is coplanar with the aromatic ring. An intra­molecular O—H⋯N hydrogen bond forms a six- membered ring, producing an S(6) ring motif. The two benzene rings are almost perpendicular to each other, making a dihedral angle of 85.00 (2)°. The meth­oxy group is approximately coplanar with the benzene ring, with a C—O—C—C torsion angle of 2.34 (12)°. Neighbouring mol­ecules are linked together by weak inter­molecular C—H⋯O hydrogen bonds and a C—H⋯π inter­action, forming a sheet parallel to the ab plane. The mol­ecules also adopt a zigzag arrangement along the c axis. International Union of Crystallography 2008-08-06 /pmc/articles/PMC2960484/ /pubmed/21201652 http://dx.doi.org/10.1107/S1600536808023738 Text en © Fun and Kia 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Kia, Reza
4,4′-Dimethoxy-2,2′-[1,1′-(propane-1,3-diyldinitrilo)diethylidyne]diphenol
title 4,4′-Dimethoxy-2,2′-[1,1′-(propane-1,3-diyldinitrilo)diethylidyne]diphenol
title_full 4,4′-Dimethoxy-2,2′-[1,1′-(propane-1,3-diyldinitrilo)diethylidyne]diphenol
title_fullStr 4,4′-Dimethoxy-2,2′-[1,1′-(propane-1,3-diyldinitrilo)diethylidyne]diphenol
title_full_unstemmed 4,4′-Dimethoxy-2,2′-[1,1′-(propane-1,3-diyldinitrilo)diethylidyne]diphenol
title_short 4,4′-Dimethoxy-2,2′-[1,1′-(propane-1,3-diyldinitrilo)diethylidyne]diphenol
title_sort 4,4′-dimethoxy-2,2′-[1,1′-(propane-1,3-diyldinitrilo)diethylidyne]diphenol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960484/
https://www.ncbi.nlm.nih.gov/pubmed/21201652
http://dx.doi.org/10.1107/S1600536808023738
work_keys_str_mv AT funhoongkun 44dimethoxy2211propane13diyldinitrilodiethylidynediphenol
AT kiareza 44dimethoxy2211propane13diyldinitrilodiethylidynediphenol