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{μ-N,N′-Bis[(E)-4-pyridylmethylidene]naphthalene-1,5-diamine}bis[dichlorido(dimethyl sulfide)platinum(II)]
The title dinuclear platinum compound, [Pt(2)Cl(4)(C(22)H(16)N(4))(C(2)H(6)S)(2)], with a long bridging bipyridyl-type ligand, is centrosymmetric and the Pt(II) cation shows a slightly distorted square-planar coordination geometry. The Cl ligands are trans to each other, with a Cl—Pt—Cl angle of 178...
| Autores principales: | , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960488/ https://www.ncbi.nlm.nih.gov/pubmed/21201595 http://dx.doi.org/10.1107/S1600536808024914 |
| _version_ | 1782188751728934912 |
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| author | Huh, Hyun Sue Lee, Soon W. |
| author_facet | Huh, Hyun Sue Lee, Soon W. |
| author_sort | Huh, Hyun Sue |
| collection | PubMed |
| description | The title dinuclear platinum compound, [Pt(2)Cl(4)(C(22)H(16)N(4))(C(2)H(6)S)(2)], with a long bridging bipyridyl-type ligand, is centrosymmetric and the Pt(II) cation shows a slightly distorted square-planar coordination geometry. The Cl ligands are trans to each other, with a Cl—Pt—Cl angle of 178.83 (8)°. The pyridine ring forms a dihedral angle of 48.8 (2)° with the planar PtCl(2)SN unit. Within the molecule, the distance between Pt atoms is 20.262 (5) Å and the N⋯N separation between the terminal pyridyl rings is 16.23 (1)Å. |
| format | Text |
| id | pubmed-2960488 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29604882010-12-30 {μ-N,N′-Bis[(E)-4-pyridylmethylidene]naphthalene-1,5-diamine}bis[dichlorido(dimethyl sulfide)platinum(II)] Huh, Hyun Sue Lee, Soon W. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title dinuclear platinum compound, [Pt(2)Cl(4)(C(22)H(16)N(4))(C(2)H(6)S)(2)], with a long bridging bipyridyl-type ligand, is centrosymmetric and the Pt(II) cation shows a slightly distorted square-planar coordination geometry. The Cl ligands are trans to each other, with a Cl—Pt—Cl angle of 178.83 (8)°. The pyridine ring forms a dihedral angle of 48.8 (2)° with the planar PtCl(2)SN unit. Within the molecule, the distance between Pt atoms is 20.262 (5) Å and the N⋯N separation between the terminal pyridyl rings is 16.23 (1)Å. International Union of Crystallography 2008-08-09 /pmc/articles/PMC2960488/ /pubmed/21201595 http://dx.doi.org/10.1107/S1600536808024914 Text en © Huh and Lee 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Huh, Hyun Sue Lee, Soon W. {μ-N,N′-Bis[(E)-4-pyridylmethylidene]naphthalene-1,5-diamine}bis[dichlorido(dimethyl sulfide)platinum(II)] |
| title | {μ-N,N′-Bis[(E)-4-pyridylmethylidene]naphthalene-1,5-diamine}bis[dichlorido(dimethyl sulfide)platinum(II)] |
| title_full | {μ-N,N′-Bis[(E)-4-pyridylmethylidene]naphthalene-1,5-diamine}bis[dichlorido(dimethyl sulfide)platinum(II)] |
| title_fullStr | {μ-N,N′-Bis[(E)-4-pyridylmethylidene]naphthalene-1,5-diamine}bis[dichlorido(dimethyl sulfide)platinum(II)] |
| title_full_unstemmed | {μ-N,N′-Bis[(E)-4-pyridylmethylidene]naphthalene-1,5-diamine}bis[dichlorido(dimethyl sulfide)platinum(II)] |
| title_short | {μ-N,N′-Bis[(E)-4-pyridylmethylidene]naphthalene-1,5-diamine}bis[dichlorido(dimethyl sulfide)platinum(II)] |
| title_sort | {μ-n,n′-bis[(e)-4-pyridylmethylidene]naphthalene-1,5-diamine}bis[dichlorido(dimethyl sulfide)platinum(ii)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960488/ https://www.ncbi.nlm.nih.gov/pubmed/21201595 http://dx.doi.org/10.1107/S1600536808024914 |
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