Cargando…

{μ-N-[(Diphenyl­phosphino)meth­yl]pyridin-2-amine-κ(2) N (1):P}bis­{[2-(2,2′-bipyridin-6-yl)phenyl-κ(3) N,N′,C (1)]platinum(II)} bis­(perchlorate)

The title compound, [Pt(2)(C(16)H(11)N(2))(2)(C(18)H(17)N(2)P)](ClO(4))(2), contains two Pt(II) atoms, bridged by an N-[(diphenyl­phosphino)meth­yl]pyridin-2-amine (dppmp) ligand. One Pt atom is coordinated by one P atom from the dppmp ligand, and one C atom and two N atoms from a 6-phenyl-2,2′-bipy...

Descripción completa

Detalles Bibliográficos
Autores principales: Du, Xiang-Dang, Mo, Juan, Li, Xin-Sheng, Pan, Yu-Shan, Zhang, Su-Mei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960491/
https://www.ncbi.nlm.nih.gov/pubmed/21201601
http://dx.doi.org/10.1107/S1600536808024525
_version_ 1782188752439869440
author Du, Xiang-Dang
Mo, Juan
Li, Xin-Sheng
Pan, Yu-Shan
Zhang, Su-Mei
author_facet Du, Xiang-Dang
Mo, Juan
Li, Xin-Sheng
Pan, Yu-Shan
Zhang, Su-Mei
author_sort Du, Xiang-Dang
collection PubMed
description The title compound, [Pt(2)(C(16)H(11)N(2))(2)(C(18)H(17)N(2)P)](ClO(4))(2), contains two Pt(II) atoms, bridged by an N-[(diphenyl­phosphino)meth­yl]pyridin-2-amine (dppmp) ligand. One Pt atom is coordinated by one P atom from the dppmp ligand, and one C atom and two N atoms from a 6-phenyl-2,2′-bipyridine (pbpy) ligand in a square-planar geometry. The other Pt atom is coordinated by one N atom from the dppmp ligand, and one C atom and two N atoms from another pbpy ligand in a square-planar geometry. There are intra­molecular π–π inter­actions between the pbpy ligands, with a centroid–centroid distance of 3.62 (1) Å between two pyridyl rings. The oxygen atoms of both perchlorate anions are disordered, each over two different positions [occupanicies 0.49 (3)/0.51 (3) and 0.48 (2)/0.52 (2)].
format Text
id pubmed-2960491
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29604912010-12-30 {μ-N-[(Diphenyl­phosphino)meth­yl]pyridin-2-amine-κ(2) N (1):P}bis­{[2-(2,2′-bipyridin-6-yl)phenyl-κ(3) N,N′,C (1)]platinum(II)} bis­(perchlorate) Du, Xiang-Dang Mo, Juan Li, Xin-Sheng Pan, Yu-Shan Zhang, Su-Mei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Pt(2)(C(16)H(11)N(2))(2)(C(18)H(17)N(2)P)](ClO(4))(2), contains two Pt(II) atoms, bridged by an N-[(diphenyl­phosphino)meth­yl]pyridin-2-amine (dppmp) ligand. One Pt atom is coordinated by one P atom from the dppmp ligand, and one C atom and two N atoms from a 6-phenyl-2,2′-bipyridine (pbpy) ligand in a square-planar geometry. The other Pt atom is coordinated by one N atom from the dppmp ligand, and one C atom and two N atoms from another pbpy ligand in a square-planar geometry. There are intra­molecular π–π inter­actions between the pbpy ligands, with a centroid–centroid distance of 3.62 (1) Å between two pyridyl rings. The oxygen atoms of both perchlorate anions are disordered, each over two different positions [occupanicies 0.49 (3)/0.51 (3) and 0.48 (2)/0.52 (2)]. International Union of Crystallography 2008-08-09 /pmc/articles/PMC2960491/ /pubmed/21201601 http://dx.doi.org/10.1107/S1600536808024525 Text en © Du et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Du, Xiang-Dang
Mo, Juan
Li, Xin-Sheng
Pan, Yu-Shan
Zhang, Su-Mei
{μ-N-[(Diphenyl­phosphino)meth­yl]pyridin-2-amine-κ(2) N (1):P}bis­{[2-(2,2′-bipyridin-6-yl)phenyl-κ(3) N,N′,C (1)]platinum(II)} bis­(perchlorate)
title {μ-N-[(Diphenyl­phosphino)meth­yl]pyridin-2-amine-κ(2) N (1):P}bis­{[2-(2,2′-bipyridin-6-yl)phenyl-κ(3) N,N′,C (1)]platinum(II)} bis­(perchlorate)
title_full {μ-N-[(Diphenyl­phosphino)meth­yl]pyridin-2-amine-κ(2) N (1):P}bis­{[2-(2,2′-bipyridin-6-yl)phenyl-κ(3) N,N′,C (1)]platinum(II)} bis­(perchlorate)
title_fullStr {μ-N-[(Diphenyl­phosphino)meth­yl]pyridin-2-amine-κ(2) N (1):P}bis­{[2-(2,2′-bipyridin-6-yl)phenyl-κ(3) N,N′,C (1)]platinum(II)} bis­(perchlorate)
title_full_unstemmed {μ-N-[(Diphenyl­phosphino)meth­yl]pyridin-2-amine-κ(2) N (1):P}bis­{[2-(2,2′-bipyridin-6-yl)phenyl-κ(3) N,N′,C (1)]platinum(II)} bis­(perchlorate)
title_short {μ-N-[(Diphenyl­phosphino)meth­yl]pyridin-2-amine-κ(2) N (1):P}bis­{[2-(2,2′-bipyridin-6-yl)phenyl-κ(3) N,N′,C (1)]platinum(II)} bis­(perchlorate)
title_sort {μ-n-[(diphenyl­phosphino)meth­yl]pyridin-2-amine-κ(2) n (1):p}bis­{[2-(2,2′-bipyridin-6-yl)phenyl-κ(3) n,n′,c (1)]platinum(ii)} bis­(perchlorate)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960491/
https://www.ncbi.nlm.nih.gov/pubmed/21201601
http://dx.doi.org/10.1107/S1600536808024525
work_keys_str_mv AT duxiangdang mndiphenylphosphinomethylpyridin2aminek2n1pbis222bipyridin6ylphenylk3nnc1platinumiibisperchlorate
AT mojuan mndiphenylphosphinomethylpyridin2aminek2n1pbis222bipyridin6ylphenylk3nnc1platinumiibisperchlorate
AT lixinsheng mndiphenylphosphinomethylpyridin2aminek2n1pbis222bipyridin6ylphenylk3nnc1platinumiibisperchlorate
AT panyushan mndiphenylphosphinomethylpyridin2aminek2n1pbis222bipyridin6ylphenylk3nnc1platinumiibisperchlorate
AT zhangsumei mndiphenylphosphinomethylpyridin2aminek2n1pbis222bipyridin6ylphenylk3nnc1platinumiibisperchlorate