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{μ-N-[(Diphenylphosphino)methyl]pyridin-2-amine-κ(2) N (1):P}bis{[2-(2,2′-bipyridin-6-yl)phenyl-κ(3) N,N′,C (1)]platinum(II)} bis(perchlorate)
The title compound, [Pt(2)(C(16)H(11)N(2))(2)(C(18)H(17)N(2)P)](ClO(4))(2), contains two Pt(II) atoms, bridged by an N-[(diphenylphosphino)methyl]pyridin-2-amine (dppmp) ligand. One Pt atom is coordinated by one P atom from the dppmp ligand, and one C atom and two N atoms from a 6-phenyl-2,2′-bipy...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960491/ https://www.ncbi.nlm.nih.gov/pubmed/21201601 http://dx.doi.org/10.1107/S1600536808024525 |
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author | Du, Xiang-Dang Mo, Juan Li, Xin-Sheng Pan, Yu-Shan Zhang, Su-Mei |
author_facet | Du, Xiang-Dang Mo, Juan Li, Xin-Sheng Pan, Yu-Shan Zhang, Su-Mei |
author_sort | Du, Xiang-Dang |
collection | PubMed |
description | The title compound, [Pt(2)(C(16)H(11)N(2))(2)(C(18)H(17)N(2)P)](ClO(4))(2), contains two Pt(II) atoms, bridged by an N-[(diphenylphosphino)methyl]pyridin-2-amine (dppmp) ligand. One Pt atom is coordinated by one P atom from the dppmp ligand, and one C atom and two N atoms from a 6-phenyl-2,2′-bipyridine (pbpy) ligand in a square-planar geometry. The other Pt atom is coordinated by one N atom from the dppmp ligand, and one C atom and two N atoms from another pbpy ligand in a square-planar geometry. There are intramolecular π–π interactions between the pbpy ligands, with a centroid–centroid distance of 3.62 (1) Å between two pyridyl rings. The oxygen atoms of both perchlorate anions are disordered, each over two different positions [occupanicies 0.49 (3)/0.51 (3) and 0.48 (2)/0.52 (2)]. |
format | Text |
id | pubmed-2960491 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29604912010-12-30 {μ-N-[(Diphenylphosphino)methyl]pyridin-2-amine-κ(2) N (1):P}bis{[2-(2,2′-bipyridin-6-yl)phenyl-κ(3) N,N′,C (1)]platinum(II)} bis(perchlorate) Du, Xiang-Dang Mo, Juan Li, Xin-Sheng Pan, Yu-Shan Zhang, Su-Mei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Pt(2)(C(16)H(11)N(2))(2)(C(18)H(17)N(2)P)](ClO(4))(2), contains two Pt(II) atoms, bridged by an N-[(diphenylphosphino)methyl]pyridin-2-amine (dppmp) ligand. One Pt atom is coordinated by one P atom from the dppmp ligand, and one C atom and two N atoms from a 6-phenyl-2,2′-bipyridine (pbpy) ligand in a square-planar geometry. The other Pt atom is coordinated by one N atom from the dppmp ligand, and one C atom and two N atoms from another pbpy ligand in a square-planar geometry. There are intramolecular π–π interactions between the pbpy ligands, with a centroid–centroid distance of 3.62 (1) Å between two pyridyl rings. The oxygen atoms of both perchlorate anions are disordered, each over two different positions [occupanicies 0.49 (3)/0.51 (3) and 0.48 (2)/0.52 (2)]. International Union of Crystallography 2008-08-09 /pmc/articles/PMC2960491/ /pubmed/21201601 http://dx.doi.org/10.1107/S1600536808024525 Text en © Du et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Du, Xiang-Dang Mo, Juan Li, Xin-Sheng Pan, Yu-Shan Zhang, Su-Mei {μ-N-[(Diphenylphosphino)methyl]pyridin-2-amine-κ(2) N (1):P}bis{[2-(2,2′-bipyridin-6-yl)phenyl-κ(3) N,N′,C (1)]platinum(II)} bis(perchlorate) |
title | {μ-N-[(Diphenylphosphino)methyl]pyridin-2-amine-κ(2)
N
(1):P}bis{[2-(2,2′-bipyridin-6-yl)phenyl-κ(3)
N,N′,C
(1)]platinum(II)} bis(perchlorate) |
title_full | {μ-N-[(Diphenylphosphino)methyl]pyridin-2-amine-κ(2)
N
(1):P}bis{[2-(2,2′-bipyridin-6-yl)phenyl-κ(3)
N,N′,C
(1)]platinum(II)} bis(perchlorate) |
title_fullStr | {μ-N-[(Diphenylphosphino)methyl]pyridin-2-amine-κ(2)
N
(1):P}bis{[2-(2,2′-bipyridin-6-yl)phenyl-κ(3)
N,N′,C
(1)]platinum(II)} bis(perchlorate) |
title_full_unstemmed | {μ-N-[(Diphenylphosphino)methyl]pyridin-2-amine-κ(2)
N
(1):P}bis{[2-(2,2′-bipyridin-6-yl)phenyl-κ(3)
N,N′,C
(1)]platinum(II)} bis(perchlorate) |
title_short | {μ-N-[(Diphenylphosphino)methyl]pyridin-2-amine-κ(2)
N
(1):P}bis{[2-(2,2′-bipyridin-6-yl)phenyl-κ(3)
N,N′,C
(1)]platinum(II)} bis(perchlorate) |
title_sort | {μ-n-[(diphenylphosphino)methyl]pyridin-2-amine-κ(2)
n
(1):p}bis{[2-(2,2′-bipyridin-6-yl)phenyl-κ(3)
n,n′,c
(1)]platinum(ii)} bis(perchlorate) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960491/ https://www.ncbi.nlm.nih.gov/pubmed/21201601 http://dx.doi.org/10.1107/S1600536808024525 |
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