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catena-Poly[[[diaquacobalt(II)]bis(μ-1,3-di-4-pyridylpropane-κ(2) N:N′)] bis(perchlorate) bis(1,3-di-4-pyridylpropane) bis(2-methyl-4-nitroaniline)]
In the title compound, {[Co(C(13)H(14)N(2))(2)(H(2)O)(2)](ClO(4))(2)·2C(13)H(14)N(2)·2C(7)H(8)N(2)O(2)}(n), the Co(II) ion lies on a crystallographic inversion center and is coordinated by four N atoms from four symmetry-related 1,3-di-4-pyridylpropane ligands and two O atoms from two water ligands...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960494/ https://www.ncbi.nlm.nih.gov/pubmed/21201638 http://dx.doi.org/10.1107/S1600536808026470 |
Sumario: | In the title compound, {[Co(C(13)H(14)N(2))(2)(H(2)O)(2)](ClO(4))(2)·2C(13)H(14)N(2)·2C(7)H(8)N(2)O(2)}(n), the Co(II) ion lies on a crystallographic inversion center and is coordinated by four N atoms from four symmetry-related 1,3-di-4-pyridylpropane ligands and two O atoms from two water ligands in a slightly distorted octahedral coordination environment. The 1,3-di-4-pyridylpropane ligands are doubly bridging and connect the Co(II) ions into one-dimensional chains. The asymmetric unit also contains one uncoordinated 1,3-di-4-pyridylpropane molecule, one 2-methyl-4-nitroaniline molecule and one perchlorate anion. In the crystal structure, intermolecular O—H⋯N hydrogen bonds connect the one-dimensional chains into a two-dimensional network. |
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