Cargando…
catena-Poly[[[diaquacobalt(II)]bis(μ-1,3-di-4-pyridylpropane-κ(2) N:N′)] bis(perchlorate) bis(1,3-di-4-pyridylpropane) bis(2-methyl-4-nitroaniline)]
In the title compound, {[Co(C(13)H(14)N(2))(2)(H(2)O)(2)](ClO(4))(2)·2C(13)H(14)N(2)·2C(7)H(8)N(2)O(2)}(n), the Co(II) ion lies on a crystallographic inversion center and is coordinated by four N atoms from four symmetry-related 1,3-di-4-pyridylpropane ligands and two O atoms from two water ligands...
Autores principales: | , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960494/ https://www.ncbi.nlm.nih.gov/pubmed/21201638 http://dx.doi.org/10.1107/S1600536808026470 |
_version_ | 1782188753164435456 |
---|---|
author | Fu, Zhiyong Chen, Yuan Yi, Jianglong |
author_facet | Fu, Zhiyong Chen, Yuan Yi, Jianglong |
author_sort | Fu, Zhiyong |
collection | PubMed |
description | In the title compound, {[Co(C(13)H(14)N(2))(2)(H(2)O)(2)](ClO(4))(2)·2C(13)H(14)N(2)·2C(7)H(8)N(2)O(2)}(n), the Co(II) ion lies on a crystallographic inversion center and is coordinated by four N atoms from four symmetry-related 1,3-di-4-pyridylpropane ligands and two O atoms from two water ligands in a slightly distorted octahedral coordination environment. The 1,3-di-4-pyridylpropane ligands are doubly bridging and connect the Co(II) ions into one-dimensional chains. The asymmetric unit also contains one uncoordinated 1,3-di-4-pyridylpropane molecule, one 2-methyl-4-nitroaniline molecule and one perchlorate anion. In the crystal structure, intermolecular O—H⋯N hydrogen bonds connect the one-dimensional chains into a two-dimensional network. |
format | Text |
id | pubmed-2960494 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29604942010-12-30 catena-Poly[[[diaquacobalt(II)]bis(μ-1,3-di-4-pyridylpropane-κ(2) N:N′)] bis(perchlorate) bis(1,3-di-4-pyridylpropane) bis(2-methyl-4-nitroaniline)] Fu, Zhiyong Chen, Yuan Yi, Jianglong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Co(C(13)H(14)N(2))(2)(H(2)O)(2)](ClO(4))(2)·2C(13)H(14)N(2)·2C(7)H(8)N(2)O(2)}(n), the Co(II) ion lies on a crystallographic inversion center and is coordinated by four N atoms from four symmetry-related 1,3-di-4-pyridylpropane ligands and two O atoms from two water ligands in a slightly distorted octahedral coordination environment. The 1,3-di-4-pyridylpropane ligands are doubly bridging and connect the Co(II) ions into one-dimensional chains. The asymmetric unit also contains one uncoordinated 1,3-di-4-pyridylpropane molecule, one 2-methyl-4-nitroaniline molecule and one perchlorate anion. In the crystal structure, intermolecular O—H⋯N hydrogen bonds connect the one-dimensional chains into a two-dimensional network. International Union of Crystallography 2008-08-23 /pmc/articles/PMC2960494/ /pubmed/21201638 http://dx.doi.org/10.1107/S1600536808026470 Text en © Fu et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Fu, Zhiyong Chen, Yuan Yi, Jianglong catena-Poly[[[diaquacobalt(II)]bis(μ-1,3-di-4-pyridylpropane-κ(2) N:N′)] bis(perchlorate) bis(1,3-di-4-pyridylpropane) bis(2-methyl-4-nitroaniline)] |
title |
catena-Poly[[[diaquacobalt(II)]bis(μ-1,3-di-4-pyridylpropane-κ(2)
N:N′)] bis(perchlorate) bis(1,3-di-4-pyridylpropane) bis(2-methyl-4-nitroaniline)] |
title_full |
catena-Poly[[[diaquacobalt(II)]bis(μ-1,3-di-4-pyridylpropane-κ(2)
N:N′)] bis(perchlorate) bis(1,3-di-4-pyridylpropane) bis(2-methyl-4-nitroaniline)] |
title_fullStr |
catena-Poly[[[diaquacobalt(II)]bis(μ-1,3-di-4-pyridylpropane-κ(2)
N:N′)] bis(perchlorate) bis(1,3-di-4-pyridylpropane) bis(2-methyl-4-nitroaniline)] |
title_full_unstemmed |
catena-Poly[[[diaquacobalt(II)]bis(μ-1,3-di-4-pyridylpropane-κ(2)
N:N′)] bis(perchlorate) bis(1,3-di-4-pyridylpropane) bis(2-methyl-4-nitroaniline)] |
title_short |
catena-Poly[[[diaquacobalt(II)]bis(μ-1,3-di-4-pyridylpropane-κ(2)
N:N′)] bis(perchlorate) bis(1,3-di-4-pyridylpropane) bis(2-methyl-4-nitroaniline)] |
title_sort | catena-poly[[[diaquacobalt(ii)]bis(μ-1,3-di-4-pyridylpropane-κ(2)
n:n′)] bis(perchlorate) bis(1,3-di-4-pyridylpropane) bis(2-methyl-4-nitroaniline)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960494/ https://www.ncbi.nlm.nih.gov/pubmed/21201638 http://dx.doi.org/10.1107/S1600536808026470 |
work_keys_str_mv | AT fuzhiyong catenapolydiaquacobaltiibism13di4pyridylpropanek2nnbisperchloratebis13di4pyridylpropanebis2methyl4nitroaniline AT chenyuan catenapolydiaquacobaltiibism13di4pyridylpropanek2nnbisperchloratebis13di4pyridylpropanebis2methyl4nitroaniline AT yijianglong catenapolydiaquacobaltiibism13di4pyridylpropanek2nnbisperchloratebis13di4pyridylpropanebis2methyl4nitroaniline |