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catena-Poly[[[diaqua­cobalt(II)]bis­(μ-1,3-di-4-pyridylpropane-κ(2) N:N′)] bis­(perchlorate) bis­(1,3-di-4-pyridyl­propane) bis­(2-methyl-4-nitro­aniline)]

In the title compound, {[Co(C(13)H(14)N(2))(2)(H(2)O)(2)](ClO(4))(2)·2C(13)H(14)N(2)·2C(7)H(8)N(2)O(2)}(n), the Co(II) ion lies on a crystallographic inversion center and is coordinated by four N atoms from four symmetry-related 1,3-di-4-pyridylpropane ligands and two O atoms from two water ligands...

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Detalles Bibliográficos
Autores principales: Fu, Zhiyong, Chen, Yuan, Yi, Jianglong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960494/
https://www.ncbi.nlm.nih.gov/pubmed/21201638
http://dx.doi.org/10.1107/S1600536808026470
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author Fu, Zhiyong
Chen, Yuan
Yi, Jianglong
author_facet Fu, Zhiyong
Chen, Yuan
Yi, Jianglong
author_sort Fu, Zhiyong
collection PubMed
description In the title compound, {[Co(C(13)H(14)N(2))(2)(H(2)O)(2)](ClO(4))(2)·2C(13)H(14)N(2)·2C(7)H(8)N(2)O(2)}(n), the Co(II) ion lies on a crystallographic inversion center and is coordinated by four N atoms from four symmetry-related 1,3-di-4-pyridylpropane ligands and two O atoms from two water ligands in a slightly distorted octa­hedral coordination environment. The 1,3-di-4-pyridylpropane ligands are doubly bridging and connect the Co(II) ions into one-dimensional chains. The asymmetric unit also contains one uncoordinated 1,3-di-4-pyridylpropane mol­ecule, one 2-methyl-4-nitro­aniline mol­ecule and one perchlorate anion. In the crystal structure, inter­molecular O—H⋯N hydrogen bonds connect the one-dimensional chains into a two-dimensional network.
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spelling pubmed-29604942010-12-30 catena-Poly[[[diaqua­cobalt(II)]bis­(μ-1,3-di-4-pyridylpropane-κ(2) N:N′)] bis­(perchlorate) bis­(1,3-di-4-pyridyl­propane) bis­(2-methyl-4-nitro­aniline)] Fu, Zhiyong Chen, Yuan Yi, Jianglong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Co(C(13)H(14)N(2))(2)(H(2)O)(2)](ClO(4))(2)·2C(13)H(14)N(2)·2C(7)H(8)N(2)O(2)}(n), the Co(II) ion lies on a crystallographic inversion center and is coordinated by four N atoms from four symmetry-related 1,3-di-4-pyridylpropane ligands and two O atoms from two water ligands in a slightly distorted octa­hedral coordination environment. The 1,3-di-4-pyridylpropane ligands are doubly bridging and connect the Co(II) ions into one-dimensional chains. The asymmetric unit also contains one uncoordinated 1,3-di-4-pyridylpropane mol­ecule, one 2-methyl-4-nitro­aniline mol­ecule and one perchlorate anion. In the crystal structure, inter­molecular O—H⋯N hydrogen bonds connect the one-dimensional chains into a two-dimensional network. International Union of Crystallography 2008-08-23 /pmc/articles/PMC2960494/ /pubmed/21201638 http://dx.doi.org/10.1107/S1600536808026470 Text en © Fu et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Fu, Zhiyong
Chen, Yuan
Yi, Jianglong
catena-Poly[[[diaqua­cobalt(II)]bis­(μ-1,3-di-4-pyridylpropane-κ(2) N:N′)] bis­(perchlorate) bis­(1,3-di-4-pyridyl­propane) bis­(2-methyl-4-nitro­aniline)]
title catena-Poly[[[diaqua­cobalt(II)]bis­(μ-1,3-di-4-pyridylpropane-κ(2) N:N′)] bis­(perchlorate) bis­(1,3-di-4-pyridyl­propane) bis­(2-methyl-4-nitro­aniline)]
title_full catena-Poly[[[diaqua­cobalt(II)]bis­(μ-1,3-di-4-pyridylpropane-κ(2) N:N′)] bis­(perchlorate) bis­(1,3-di-4-pyridyl­propane) bis­(2-methyl-4-nitro­aniline)]
title_fullStr catena-Poly[[[diaqua­cobalt(II)]bis­(μ-1,3-di-4-pyridylpropane-κ(2) N:N′)] bis­(perchlorate) bis­(1,3-di-4-pyridyl­propane) bis­(2-methyl-4-nitro­aniline)]
title_full_unstemmed catena-Poly[[[diaqua­cobalt(II)]bis­(μ-1,3-di-4-pyridylpropane-κ(2) N:N′)] bis­(perchlorate) bis­(1,3-di-4-pyridyl­propane) bis­(2-methyl-4-nitro­aniline)]
title_short catena-Poly[[[diaqua­cobalt(II)]bis­(μ-1,3-di-4-pyridylpropane-κ(2) N:N′)] bis­(perchlorate) bis­(1,3-di-4-pyridyl­propane) bis­(2-methyl-4-nitro­aniline)]
title_sort catena-poly[[[diaqua­cobalt(ii)]bis­(μ-1,3-di-4-pyridylpropane-κ(2) n:n′)] bis­(perchlorate) bis­(1,3-di-4-pyridyl­propane) bis­(2-methyl-4-nitro­aniline)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960494/
https://www.ncbi.nlm.nih.gov/pubmed/21201638
http://dx.doi.org/10.1107/S1600536808026470
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