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Dichlorido(4,7-diphenyl-1,10-phenanthroline-κ(2) N,N′)gold(III) tetrachloridoaurate(III)
In the cation of the title compound, [AuCl(2)(C(24)H(16)N(2))][AuCl(4)], the Au(III) atom is four-coordinated in a distorted square-planar configuration by two N atoms from a 4,7-diphenyl-1,10-phenanthroline ligand and two terminal Cl atoms. In the anion, the Au(III) atom has a square-planar coordin...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960497/ https://www.ncbi.nlm.nih.gov/pubmed/21201607 http://dx.doi.org/10.1107/S1600536808025476 |
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author | Ahmadi, Roya Amani, Vahid Khavasi, Hamid Reza |
author_facet | Ahmadi, Roya Amani, Vahid Khavasi, Hamid Reza |
author_sort | Ahmadi, Roya |
collection | PubMed |
description | In the cation of the title compound, [AuCl(2)(C(24)H(16)N(2))][AuCl(4)], the Au(III) atom is four-coordinated in a distorted square-planar configuration by two N atoms from a 4,7-diphenyl-1,10-phenanthroline ligand and two terminal Cl atoms. In the anion, the Au(III) atom has a square-planar coordination. In the crystal structure, intra- and intermolecular C—H⋯Cl hydrogen bonds are found. |
format | Text |
id | pubmed-2960497 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29604972010-12-30 Dichlorido(4,7-diphenyl-1,10-phenanthroline-κ(2) N,N′)gold(III) tetrachloridoaurate(III) Ahmadi, Roya Amani, Vahid Khavasi, Hamid Reza Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the cation of the title compound, [AuCl(2)(C(24)H(16)N(2))][AuCl(4)], the Au(III) atom is four-coordinated in a distorted square-planar configuration by two N atoms from a 4,7-diphenyl-1,10-phenanthroline ligand and two terminal Cl atoms. In the anion, the Au(III) atom has a square-planar coordination. In the crystal structure, intra- and intermolecular C—H⋯Cl hydrogen bonds are found. International Union of Crystallography 2008-08-13 /pmc/articles/PMC2960497/ /pubmed/21201607 http://dx.doi.org/10.1107/S1600536808025476 Text en © Ahmadi et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ahmadi, Roya Amani, Vahid Khavasi, Hamid Reza Dichlorido(4,7-diphenyl-1,10-phenanthroline-κ(2) N,N′)gold(III) tetrachloridoaurate(III) |
title | Dichlorido(4,7-diphenyl-1,10-phenanthroline-κ(2)
N,N′)gold(III) tetrachloridoaurate(III) |
title_full | Dichlorido(4,7-diphenyl-1,10-phenanthroline-κ(2)
N,N′)gold(III) tetrachloridoaurate(III) |
title_fullStr | Dichlorido(4,7-diphenyl-1,10-phenanthroline-κ(2)
N,N′)gold(III) tetrachloridoaurate(III) |
title_full_unstemmed | Dichlorido(4,7-diphenyl-1,10-phenanthroline-κ(2)
N,N′)gold(III) tetrachloridoaurate(III) |
title_short | Dichlorido(4,7-diphenyl-1,10-phenanthroline-κ(2)
N,N′)gold(III) tetrachloridoaurate(III) |
title_sort | dichlorido(4,7-diphenyl-1,10-phenanthroline-κ(2)
n,n′)gold(iii) tetrachloridoaurate(iii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960497/ https://www.ncbi.nlm.nih.gov/pubmed/21201607 http://dx.doi.org/10.1107/S1600536808025476 |
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