Dichlorido(dimethyl­formamide-κO)[1,4,7-tris­(2-cyano­ethyl)-1,4,7-triaza­cyclo­nonane-κ(3) N (1),N (4),N (7)]nickel(II)

The title complex, [NiCl(2)(C(15)H(24)N(6))(C(3)H(7)NO)], is isomorphous with the Co(II) analogue. Three N-atom donors from the facially coordinating triaza macrocyclic ligand, one O-atom donor from dimethyl­formamide and two Cl(−) anions surround the Ni(II) ion in a distorted octa­hedral coordinati...

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Detalles Bibliográficos
Autores principales: Zhang, Zhong, Wu, Li-Zhen, Geng, Zhi-Rong, Wang, Zhi-Lin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960500/
https://www.ncbi.nlm.nih.gov/pubmed/21201578
http://dx.doi.org/10.1107/S1600536808024422
Descripción
Sumario:The title complex, [NiCl(2)(C(15)H(24)N(6))(C(3)H(7)NO)], is isomorphous with the Co(II) analogue. Three N-atom donors from the facially coordinating triaza macrocyclic ligand, one O-atom donor from dimethyl­formamide and two Cl(−) anions surround the Ni(II) ion in a distorted octa­hedral coordination geometry. Inter­molecular C—H⋯Cl and C—H⋯N hydrogen-bonding inter­actions link the complex mol­ecules into a three-dimensional supra­molecular architecture.

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