Dichlorido(dimethyl­formamide-κO)[1,4,7-tris­(2-cyano­ethyl)-1,4,7-triaza­cyclo­nonane-κ(3) N (1),N (4),N (7)]nickel(II)

The title complex, [NiCl(2)(C(15)H(24)N(6))(C(3)H(7)NO)], is isomorphous with the Co(II) analogue. Three N-atom donors from the facially coordinating triaza macrocyclic ligand, one O-atom donor from dimethyl­formamide and two Cl(−) anions surround the Ni(II) ion in a distorted octa­hedral coordinati...

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Detalles Bibliográficos
Autores principales: Zhang, Zhong, Wu, Li-Zhen, Geng, Zhi-Rong, Wang, Zhi-Lin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960500/
https://www.ncbi.nlm.nih.gov/pubmed/21201578
http://dx.doi.org/10.1107/S1600536808024422
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author Zhang, Zhong
Wu, Li-Zhen
Geng, Zhi-Rong
Wang, Zhi-Lin
author_facet Zhang, Zhong
Wu, Li-Zhen
Geng, Zhi-Rong
Wang, Zhi-Lin
author_sort Zhang, Zhong
collection PubMed
description The title complex, [NiCl(2)(C(15)H(24)N(6))(C(3)H(7)NO)], is isomorphous with the Co(II) analogue. Three N-atom donors from the facially coordinating triaza macrocyclic ligand, one O-atom donor from dimethyl­formamide and two Cl(−) anions surround the Ni(II) ion in a distorted octa­hedral coordination geometry. Inter­molecular C—H⋯Cl and C—H⋯N hydrogen-bonding inter­actions link the complex mol­ecules into a three-dimensional supra­molecular architecture.
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spelling pubmed-29605002010-12-30 Dichlorido(dimethyl­formamide-κO)[1,4,7-tris­(2-cyano­ethyl)-1,4,7-triaza­cyclo­nonane-κ(3) N (1),N (4),N (7)]nickel(II) Zhang, Zhong Wu, Li-Zhen Geng, Zhi-Rong Wang, Zhi-Lin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [NiCl(2)(C(15)H(24)N(6))(C(3)H(7)NO)], is isomorphous with the Co(II) analogue. Three N-atom donors from the facially coordinating triaza macrocyclic ligand, one O-atom donor from dimethyl­formamide and two Cl(−) anions surround the Ni(II) ion in a distorted octa­hedral coordination geometry. Inter­molecular C—H⋯Cl and C—H⋯N hydrogen-bonding inter­actions link the complex mol­ecules into a three-dimensional supra­molecular architecture. International Union of Crystallography 2008-08-06 /pmc/articles/PMC2960500/ /pubmed/21201578 http://dx.doi.org/10.1107/S1600536808024422 Text en © Zhang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Zhong
Wu, Li-Zhen
Geng, Zhi-Rong
Wang, Zhi-Lin
Dichlorido(dimethyl­formamide-κO)[1,4,7-tris­(2-cyano­ethyl)-1,4,7-triaza­cyclo­nonane-κ(3) N (1),N (4),N (7)]nickel(II)
title Dichlorido(dimethyl­formamide-κO)[1,4,7-tris­(2-cyano­ethyl)-1,4,7-triaza­cyclo­nonane-κ(3) N (1),N (4),N (7)]nickel(II)
title_full Dichlorido(dimethyl­formamide-κO)[1,4,7-tris­(2-cyano­ethyl)-1,4,7-triaza­cyclo­nonane-κ(3) N (1),N (4),N (7)]nickel(II)
title_fullStr Dichlorido(dimethyl­formamide-κO)[1,4,7-tris­(2-cyano­ethyl)-1,4,7-triaza­cyclo­nonane-κ(3) N (1),N (4),N (7)]nickel(II)
title_full_unstemmed Dichlorido(dimethyl­formamide-κO)[1,4,7-tris­(2-cyano­ethyl)-1,4,7-triaza­cyclo­nonane-κ(3) N (1),N (4),N (7)]nickel(II)
title_short Dichlorido(dimethyl­formamide-κO)[1,4,7-tris­(2-cyano­ethyl)-1,4,7-triaza­cyclo­nonane-κ(3) N (1),N (4),N (7)]nickel(II)
title_sort dichlorido(dimethyl­formamide-κo)[1,4,7-tris­(2-cyano­ethyl)-1,4,7-triaza­cyclo­nonane-κ(3) n (1),n (4),n (7)]nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960500/
https://www.ncbi.nlm.nih.gov/pubmed/21201578
http://dx.doi.org/10.1107/S1600536808024422
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