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Hexa-μ(2)-acetato-1:2κ(4) O:O′;1:2κ(2) O:O;2:3κ(4) O:O′;2:3κ(2) O:O-bis(2-amino-7-chloro-5-methyl-1,8-naphthyridine)-1κN (1),3κN (1)-trizinc(II)
The title complex, [Zn(3)(C(2)H(3)O(2))(6)(C(9)H(8)ClN(3))(2)], contains three Zn(II) atoms bridged by six acetate ligands. The central Zn(II) ion, located on an inversion centre, is surrounded by six O atoms from acetate ligands in a distorted octahedral geometry [Zn—O = 1.9588 (12)–2.1237 (12) Å]...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960502/ https://www.ncbi.nlm.nih.gov/pubmed/21201587 http://dx.doi.org/10.1107/S1600536808024549 |
| _version_ | 1782188755072843776 |
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| author | Li, Xin-Sheng Mo, Juan Yuan, Li Liu, Jian-Hua Zhang, Su-Mei |
| author_facet | Li, Xin-Sheng Mo, Juan Yuan, Li Liu, Jian-Hua Zhang, Su-Mei |
| author_sort | Li, Xin-Sheng |
| collection | PubMed |
| description | The title complex, [Zn(3)(C(2)H(3)O(2))(6)(C(9)H(8)ClN(3))(2)], contains three Zn(II) atoms bridged by six acetate ligands. The central Zn(II) ion, located on an inversion centre, is surrounded by six O atoms from acetate ligands in a distorted octahedral geometry [Zn—O = 1.9588 (12)–2.1237 (12) Å]. The terminal Zn(II) ions are coordinated by one N atom of 2-amino-7-chloro-5-methyl-1,8-naphthyridine and three O atoms of three acetate ligands in a distorted tetrahedral geometry. The separation between the central and terminal Zn(II) ions is 3.245 (3) Å. |
| format | Text |
| id | pubmed-2960502 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29605022010-12-30 Hexa-μ(2)-acetato-1:2κ(4) O:O′;1:2κ(2) O:O;2:3κ(4) O:O′;2:3κ(2) O:O-bis(2-amino-7-chloro-5-methyl-1,8-naphthyridine)-1κN (1),3κN (1)-trizinc(II) Li, Xin-Sheng Mo, Juan Yuan, Li Liu, Jian-Hua Zhang, Su-Mei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Zn(3)(C(2)H(3)O(2))(6)(C(9)H(8)ClN(3))(2)], contains three Zn(II) atoms bridged by six acetate ligands. The central Zn(II) ion, located on an inversion centre, is surrounded by six O atoms from acetate ligands in a distorted octahedral geometry [Zn—O = 1.9588 (12)–2.1237 (12) Å]. The terminal Zn(II) ions are coordinated by one N atom of 2-amino-7-chloro-5-methyl-1,8-naphthyridine and three O atoms of three acetate ligands in a distorted tetrahedral geometry. The separation between the central and terminal Zn(II) ions is 3.245 (3) Å. International Union of Crystallography 2008-08-06 /pmc/articles/PMC2960502/ /pubmed/21201587 http://dx.doi.org/10.1107/S1600536808024549 Text en © Li et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Li, Xin-Sheng Mo, Juan Yuan, Li Liu, Jian-Hua Zhang, Su-Mei Hexa-μ(2)-acetato-1:2κ(4) O:O′;1:2κ(2) O:O;2:3κ(4) O:O′;2:3κ(2) O:O-bis(2-amino-7-chloro-5-methyl-1,8-naphthyridine)-1κN (1),3κN (1)-trizinc(II) |
| title | Hexa-μ(2)-acetato-1:2κ(4)
O:O′;1:2κ(2)
O:O;2:3κ(4)
O:O′;2:3κ(2)
O:O-bis(2-amino-7-chloro-5-methyl-1,8-naphthyridine)-1κN
(1),3κN
(1)-trizinc(II) |
| title_full | Hexa-μ(2)-acetato-1:2κ(4)
O:O′;1:2κ(2)
O:O;2:3κ(4)
O:O′;2:3κ(2)
O:O-bis(2-amino-7-chloro-5-methyl-1,8-naphthyridine)-1κN
(1),3κN
(1)-trizinc(II) |
| title_fullStr | Hexa-μ(2)-acetato-1:2κ(4)
O:O′;1:2κ(2)
O:O;2:3κ(4)
O:O′;2:3κ(2)
O:O-bis(2-amino-7-chloro-5-methyl-1,8-naphthyridine)-1κN
(1),3κN
(1)-trizinc(II) |
| title_full_unstemmed | Hexa-μ(2)-acetato-1:2κ(4)
O:O′;1:2κ(2)
O:O;2:3κ(4)
O:O′;2:3κ(2)
O:O-bis(2-amino-7-chloro-5-methyl-1,8-naphthyridine)-1κN
(1),3κN
(1)-trizinc(II) |
| title_short | Hexa-μ(2)-acetato-1:2κ(4)
O:O′;1:2κ(2)
O:O;2:3κ(4)
O:O′;2:3κ(2)
O:O-bis(2-amino-7-chloro-5-methyl-1,8-naphthyridine)-1κN
(1),3κN
(1)-trizinc(II) |
| title_sort | hexa-μ(2)-acetato-1:2κ(4)
o:o′;1:2κ(2)
o:o;2:3κ(4)
o:o′;2:3κ(2)
o:o-bis(2-amino-7-chloro-5-methyl-1,8-naphthyridine)-1κn
(1),3κn
(1)-trizinc(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960502/ https://www.ncbi.nlm.nih.gov/pubmed/21201587 http://dx.doi.org/10.1107/S1600536808024549 |
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