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(E)-Ethyl N′-[1-(2-hydroxy­phen­yl)ethyl­idene]hydrazinecarboxyl­ate

In the mol­ecule of the title compound, C(11)H(14)N(2)O(3), the dihedral angle between the benzene ring and the hydrazinecarboxyl­ate mean plane is 3.65 (12)°. Intra­molecular C—H⋯N and O—H⋯N hydrogen bonds result in the formation of a nearly planar six-membered ring, which is oriented at a dihedral...

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Detalles Bibliográficos
Autor principal: Gao, Bo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960505/
https://www.ncbi.nlm.nih.gov/pubmed/21201748
http://dx.doi.org/10.1107/S1600536808025191
Descripción
Sumario:In the mol­ecule of the title compound, C(11)H(14)N(2)O(3), the dihedral angle between the benzene ring and the hydrazinecarboxyl­ate mean plane is 3.65 (12)°. Intra­molecular C—H⋯N and O—H⋯N hydrogen bonds result in the formation of a nearly planar six-membered ring, which is oriented at a dihedral angle of 2.38 (3)° with respect to the benzene ring, and a five-membered ring having an envelope conformation. In the crystal structure, inter­molecular N—H⋯O and C—H⋯N hydrogen bonds link the mol­ecules. There is a C—H⋯π contact between the benzene ring and the methyl group of the ethyl substituent.