Cargando…
(E)-Ethyl N′-[1-(2-hydroxyphenyl)ethylidene]hydrazinecarboxylate
In the molecule of the title compound, C(11)H(14)N(2)O(3), the dihedral angle between the benzene ring and the hydrazinecarboxylate mean plane is 3.65 (12)°. Intramolecular C—H⋯N and O—H⋯N hydrogen bonds result in the formation of a nearly planar six-membered ring, which is oriented at a dihedral...
Autor principal: | |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960505/ https://www.ncbi.nlm.nih.gov/pubmed/21201748 http://dx.doi.org/10.1107/S1600536808025191 |
Sumario: | In the molecule of the title compound, C(11)H(14)N(2)O(3), the dihedral angle between the benzene ring and the hydrazinecarboxylate mean plane is 3.65 (12)°. Intramolecular C—H⋯N and O—H⋯N hydrogen bonds result in the formation of a nearly planar six-membered ring, which is oriented at a dihedral angle of 2.38 (3)° with respect to the benzene ring, and a five-membered ring having an envelope conformation. In the crystal structure, intermolecular N—H⋯O and C—H⋯N hydrogen bonds link the molecules. There is a C—H⋯π contact between the benzene ring and the methyl group of the ethyl substituent. |
---|