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(E)-Ethyl N′-[1-(2-hydroxy­phen­yl)ethyl­idene]hydrazinecarboxyl­ate

In the mol­ecule of the title compound, C(11)H(14)N(2)O(3), the dihedral angle between the benzene ring and the hydrazinecarboxyl­ate mean plane is 3.65 (12)°. Intra­molecular C—H⋯N and O—H⋯N hydrogen bonds result in the formation of a nearly planar six-membered ring, which is oriented at a dihedral...

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Autor principal: Gao, Bo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960505/
https://www.ncbi.nlm.nih.gov/pubmed/21201748
http://dx.doi.org/10.1107/S1600536808025191
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author Gao, Bo
author_facet Gao, Bo
author_sort Gao, Bo
collection PubMed
description In the mol­ecule of the title compound, C(11)H(14)N(2)O(3), the dihedral angle between the benzene ring and the hydrazinecarboxyl­ate mean plane is 3.65 (12)°. Intra­molecular C—H⋯N and O—H⋯N hydrogen bonds result in the formation of a nearly planar six-membered ring, which is oriented at a dihedral angle of 2.38 (3)° with respect to the benzene ring, and a five-membered ring having an envelope conformation. In the crystal structure, inter­molecular N—H⋯O and C—H⋯N hydrogen bonds link the mol­ecules. There is a C—H⋯π contact between the benzene ring and the methyl group of the ethyl substituent.
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spelling pubmed-29605052010-12-30 (E)-Ethyl N′-[1-(2-hydroxy­phen­yl)ethyl­idene]hydrazinecarboxyl­ate Gao, Bo Acta Crystallogr Sect E Struct Rep Online Organic Papers In the mol­ecule of the title compound, C(11)H(14)N(2)O(3), the dihedral angle between the benzene ring and the hydrazinecarboxyl­ate mean plane is 3.65 (12)°. Intra­molecular C—H⋯N and O—H⋯N hydrogen bonds result in the formation of a nearly planar six-membered ring, which is oriented at a dihedral angle of 2.38 (3)° with respect to the benzene ring, and a five-membered ring having an envelope conformation. In the crystal structure, inter­molecular N—H⋯O and C—H⋯N hydrogen bonds link the mol­ecules. There is a C—H⋯π contact between the benzene ring and the methyl group of the ethyl substituent. International Union of Crystallography 2008-08-16 /pmc/articles/PMC2960505/ /pubmed/21201748 http://dx.doi.org/10.1107/S1600536808025191 Text en © Bo Gao 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gao, Bo
(E)-Ethyl N′-[1-(2-hydroxy­phen­yl)ethyl­idene]hydrazinecarboxyl­ate
title (E)-Ethyl N′-[1-(2-hydroxy­phen­yl)ethyl­idene]hydrazinecarboxyl­ate
title_full (E)-Ethyl N′-[1-(2-hydroxy­phen­yl)ethyl­idene]hydrazinecarboxyl­ate
title_fullStr (E)-Ethyl N′-[1-(2-hydroxy­phen­yl)ethyl­idene]hydrazinecarboxyl­ate
title_full_unstemmed (E)-Ethyl N′-[1-(2-hydroxy­phen­yl)ethyl­idene]hydrazinecarboxyl­ate
title_short (E)-Ethyl N′-[1-(2-hydroxy­phen­yl)ethyl­idene]hydrazinecarboxyl­ate
title_sort (e)-ethyl n′-[1-(2-hydroxy­phen­yl)ethyl­idene]hydrazinecarboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960505/
https://www.ncbi.nlm.nih.gov/pubmed/21201748
http://dx.doi.org/10.1107/S1600536808025191
work_keys_str_mv AT gaobo eethyln12hydroxyphenylethylidenehydrazinecarboxylate