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(E)-Ethyl N′-[1-(2-hydroxyphenyl)ethylidene]hydrazinecarboxylate
In the molecule of the title compound, C(11)H(14)N(2)O(3), the dihedral angle between the benzene ring and the hydrazinecarboxylate mean plane is 3.65 (12)°. Intramolecular C—H⋯N and O—H⋯N hydrogen bonds result in the formation of a nearly planar six-membered ring, which is oriented at a dihedral...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960505/ https://www.ncbi.nlm.nih.gov/pubmed/21201748 http://dx.doi.org/10.1107/S1600536808025191 |
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author | Gao, Bo |
author_facet | Gao, Bo |
author_sort | Gao, Bo |
collection | PubMed |
description | In the molecule of the title compound, C(11)H(14)N(2)O(3), the dihedral angle between the benzene ring and the hydrazinecarboxylate mean plane is 3.65 (12)°. Intramolecular C—H⋯N and O—H⋯N hydrogen bonds result in the formation of a nearly planar six-membered ring, which is oriented at a dihedral angle of 2.38 (3)° with respect to the benzene ring, and a five-membered ring having an envelope conformation. In the crystal structure, intermolecular N—H⋯O and C—H⋯N hydrogen bonds link the molecules. There is a C—H⋯π contact between the benzene ring and the methyl group of the ethyl substituent. |
format | Text |
id | pubmed-2960505 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29605052010-12-30 (E)-Ethyl N′-[1-(2-hydroxyphenyl)ethylidene]hydrazinecarboxylate Gao, Bo Acta Crystallogr Sect E Struct Rep Online Organic Papers In the molecule of the title compound, C(11)H(14)N(2)O(3), the dihedral angle between the benzene ring and the hydrazinecarboxylate mean plane is 3.65 (12)°. Intramolecular C—H⋯N and O—H⋯N hydrogen bonds result in the formation of a nearly planar six-membered ring, which is oriented at a dihedral angle of 2.38 (3)° with respect to the benzene ring, and a five-membered ring having an envelope conformation. In the crystal structure, intermolecular N—H⋯O and C—H⋯N hydrogen bonds link the molecules. There is a C—H⋯π contact between the benzene ring and the methyl group of the ethyl substituent. International Union of Crystallography 2008-08-16 /pmc/articles/PMC2960505/ /pubmed/21201748 http://dx.doi.org/10.1107/S1600536808025191 Text en © Bo Gao 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Gao, Bo (E)-Ethyl N′-[1-(2-hydroxyphenyl)ethylidene]hydrazinecarboxylate |
title | (E)-Ethyl N′-[1-(2-hydroxyphenyl)ethylidene]hydrazinecarboxylate |
title_full | (E)-Ethyl N′-[1-(2-hydroxyphenyl)ethylidene]hydrazinecarboxylate |
title_fullStr | (E)-Ethyl N′-[1-(2-hydroxyphenyl)ethylidene]hydrazinecarboxylate |
title_full_unstemmed | (E)-Ethyl N′-[1-(2-hydroxyphenyl)ethylidene]hydrazinecarboxylate |
title_short | (E)-Ethyl N′-[1-(2-hydroxyphenyl)ethylidene]hydrazinecarboxylate |
title_sort | (e)-ethyl n′-[1-(2-hydroxyphenyl)ethylidene]hydrazinecarboxylate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960505/ https://www.ncbi.nlm.nih.gov/pubmed/21201748 http://dx.doi.org/10.1107/S1600536808025191 |
work_keys_str_mv | AT gaobo eethyln12hydroxyphenylethylidenehydrazinecarboxylate |