Poly[[tetra­aqua­(μ(6)-2,2′-diiodo­biphenyl-4,4′,5,5′-tetra­carboxyl­ato)dizinc(II)] dihydrate]

In the title compound, {[Zn(2)(C(16)H(4)I(2)O(8))(H(2)O)(4)]·2H(2)O}(n), two crystallographically independent Zn(II) atoms are each located on a twofold rotation axis. Both Zn(II) atoms are in distorted octa­hedral coordination geometries: one is coordinated by six O atoms from four carboxyl­ate gro...

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Detalles Bibliográficos
Autores principales: Wang, Yan, Li, Yue-Qin, Shen, Ying-Zhong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960511/
https://www.ncbi.nlm.nih.gov/pubmed/21201640
http://dx.doi.org/10.1107/S1600536808026494
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author Wang, Yan
Li, Yue-Qin
Shen, Ying-Zhong
author_facet Wang, Yan
Li, Yue-Qin
Shen, Ying-Zhong
author_sort Wang, Yan
collection PubMed
description In the title compound, {[Zn(2)(C(16)H(4)I(2)O(8))(H(2)O)(4)]·2H(2)O}(n), two crystallographically independent Zn(II) atoms are each located on a twofold rotation axis. Both Zn(II) atoms are in distorted octa­hedral coordination geometries: one is coordinated by six O atoms from four carboxyl­ate groups, while the other is coordinated by two carboxyl­ate groups and four water mol­ecules. The tetra­carboxyl­ate ligand mol­ecules connect the Zn(II) atoms, completing a three-dimensional metal–organic framework. O—H⋯O hydrogen bonds link the metal–organic framework with the uncoord­inated water mol­ecules.
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spelling pubmed-29605112010-12-30 Poly[[tetra­aqua­(μ(6)-2,2′-diiodo­biphenyl-4,4′,5,5′-tetra­carboxyl­ato)dizinc(II)] dihydrate] Wang, Yan Li, Yue-Qin Shen, Ying-Zhong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Zn(2)(C(16)H(4)I(2)O(8))(H(2)O)(4)]·2H(2)O}(n), two crystallographically independent Zn(II) atoms are each located on a twofold rotation axis. Both Zn(II) atoms are in distorted octa­hedral coordination geometries: one is coordinated by six O atoms from four carboxyl­ate groups, while the other is coordinated by two carboxyl­ate groups and four water mol­ecules. The tetra­carboxyl­ate ligand mol­ecules connect the Zn(II) atoms, completing a three-dimensional metal–organic framework. O—H⋯O hydrogen bonds link the metal–organic framework with the uncoord­inated water mol­ecules. International Union of Crystallography 2008-08-30 /pmc/articles/PMC2960511/ /pubmed/21201640 http://dx.doi.org/10.1107/S1600536808026494 Text en © Wang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Yan
Li, Yue-Qin
Shen, Ying-Zhong
Poly[[tetra­aqua­(μ(6)-2,2′-diiodo­biphenyl-4,4′,5,5′-tetra­carboxyl­ato)dizinc(II)] dihydrate]
title Poly[[tetra­aqua­(μ(6)-2,2′-diiodo­biphenyl-4,4′,5,5′-tetra­carboxyl­ato)dizinc(II)] dihydrate]
title_full Poly[[tetra­aqua­(μ(6)-2,2′-diiodo­biphenyl-4,4′,5,5′-tetra­carboxyl­ato)dizinc(II)] dihydrate]
title_fullStr Poly[[tetra­aqua­(μ(6)-2,2′-diiodo­biphenyl-4,4′,5,5′-tetra­carboxyl­ato)dizinc(II)] dihydrate]
title_full_unstemmed Poly[[tetra­aqua­(μ(6)-2,2′-diiodo­biphenyl-4,4′,5,5′-tetra­carboxyl­ato)dizinc(II)] dihydrate]
title_short Poly[[tetra­aqua­(μ(6)-2,2′-diiodo­biphenyl-4,4′,5,5′-tetra­carboxyl­ato)dizinc(II)] dihydrate]
title_sort poly[[tetra­aqua­(μ(6)-2,2′-diiodo­biphenyl-4,4′,5,5′-tetra­carboxyl­ato)dizinc(ii)] dihydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960511/
https://www.ncbi.nlm.nih.gov/pubmed/21201640
http://dx.doi.org/10.1107/S1600536808026494
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AT liyueqin polytetraaquam622diiodobiphenyl4455tetracarboxylatodizinciidihydrate
AT shenyingzhong polytetraaquam622diiodobiphenyl4455tetracarboxylatodizinciidihydrate

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