2,8-Dibromo-4,10-dichloro-6H,12H-5,11-methano­dibenzo[b,f][1,5]diazo­cine

The title compound, C(15)H(10)Br(2)Cl(2)N(2), a 2,8-dibromo-4,10-dichloro Tröger’s base analogue derived from 4-bromo-2-chloro­aniline, has a dihedral angle of 110.9 (10)° between the two aryl rings, the largest yet measured for a simple dibenzo analogue.

Detalles Bibliográficos
Autores principales: Zhu, Kai-Xian, Craig, Donald C., Try, Andrew C.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960512/
https://www.ncbi.nlm.nih.gov/pubmed/21201776
http://dx.doi.org/10.1107/S1600536808026226
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author Zhu, Kai-Xian
Craig, Donald C.
Try, Andrew C.
author_facet Zhu, Kai-Xian
Craig, Donald C.
Try, Andrew C.
author_sort Zhu, Kai-Xian
collection PubMed
description The title compound, C(15)H(10)Br(2)Cl(2)N(2), a 2,8-dibromo-4,10-dichloro Tröger’s base analogue derived from 4-bromo-2-chloro­aniline, has a dihedral angle of 110.9 (10)° between the two aryl rings, the largest yet measured for a simple dibenzo analogue.
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spelling pubmed-29605122010-12-30 2,8-Dibromo-4,10-dichloro-6H,12H-5,11-methano­dibenzo[b,f][1,5]diazo­cine Zhu, Kai-Xian Craig, Donald C. Try, Andrew C. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(10)Br(2)Cl(2)N(2), a 2,8-dibromo-4,10-dichloro Tröger’s base analogue derived from 4-bromo-2-chloro­aniline, has a dihedral angle of 110.9 (10)° between the two aryl rings, the largest yet measured for a simple dibenzo analogue. International Union of Crystallography 2008-08-20 /pmc/articles/PMC2960512/ /pubmed/21201776 http://dx.doi.org/10.1107/S1600536808026226 Text en © Zhu et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhu, Kai-Xian
Craig, Donald C.
Try, Andrew C.
2,8-Dibromo-4,10-dichloro-6H,12H-5,11-methano­dibenzo[b,f][1,5]diazo­cine
title 2,8-Dibromo-4,10-dichloro-6H,12H-5,11-methano­dibenzo[b,f][1,5]diazo­cine
title_full 2,8-Dibromo-4,10-dichloro-6H,12H-5,11-methano­dibenzo[b,f][1,5]diazo­cine
title_fullStr 2,8-Dibromo-4,10-dichloro-6H,12H-5,11-methano­dibenzo[b,f][1,5]diazo­cine
title_full_unstemmed 2,8-Dibromo-4,10-dichloro-6H,12H-5,11-methano­dibenzo[b,f][1,5]diazo­cine
title_short 2,8-Dibromo-4,10-dichloro-6H,12H-5,11-methano­dibenzo[b,f][1,5]diazo­cine
title_sort 2,8-dibromo-4,10-dichloro-6h,12h-5,11-methano­dibenzo[b,f][1,5]diazo­cine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960512/
https://www.ncbi.nlm.nih.gov/pubmed/21201776
http://dx.doi.org/10.1107/S1600536808026226
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AT tryandrewc 28dibromo410dichloro6h12h511methanodibenzobf15diazocine

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