catena-Poly[[diaqua­[(4-tolyl­sulfan­yl)acetato-κO]cadmium(II)]-μ-4,4′-bipyridine-κ(2) N:N′]

The title complex, [Cd(C(9)H(9)O(2)S)(2)(C(10)H(8)N(2))(H(2)O)(2)](n), has a linear chain structure. The central Cd(II) ion is in a slightly disorted octa­hedral environment, coordinated by two aqua ligands, two (4-tolyl­sulfan­yl)acetate ligands and two bridging 4,4′-bipyridine ligands. The Cd(II)...

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Detalles Bibliográficos
Autores principales: Cai, Wen-Xuan, Zheng, Xiao-Yong, Geng, Xiao-Hong, Feng, Yun-Long
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960514/
https://www.ncbi.nlm.nih.gov/pubmed/21201594
http://dx.doi.org/10.1107/S1600536808024720
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author Cai, Wen-Xuan
Zheng, Xiao-Yong
Geng, Xiao-Hong
Feng, Yun-Long
author_facet Cai, Wen-Xuan
Zheng, Xiao-Yong
Geng, Xiao-Hong
Feng, Yun-Long
author_sort Cai, Wen-Xuan
collection PubMed
description The title complex, [Cd(C(9)H(9)O(2)S)(2)(C(10)H(8)N(2))(H(2)O)(2)](n), has a linear chain structure. The central Cd(II) ion is in a slightly disorted octa­hedral environment, coordinated by two aqua ligands, two (4-tolyl­sulfan­yl)acetate ligands and two bridging 4,4′-bipyridine ligands. The Cd(II) ion lies on a twofold rotation axis. Inter­molecular O—H⋯O hydrogen bonds connect adjacent chains, forming a layer structure. An intramolecular O—H⋯O hydrogen bond is also present.
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spelling pubmed-29605142010-12-30 catena-Poly[[diaqua­[(4-tolyl­sulfan­yl)acetato-κO]cadmium(II)]-μ-4,4′-bipyridine-κ(2) N:N′] Cai, Wen-Xuan Zheng, Xiao-Yong Geng, Xiao-Hong Feng, Yun-Long Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Cd(C(9)H(9)O(2)S)(2)(C(10)H(8)N(2))(H(2)O)(2)](n), has a linear chain structure. The central Cd(II) ion is in a slightly disorted octa­hedral environment, coordinated by two aqua ligands, two (4-tolyl­sulfan­yl)acetate ligands and two bridging 4,4′-bipyridine ligands. The Cd(II) ion lies on a twofold rotation axis. Inter­molecular O—H⋯O hydrogen bonds connect adjacent chains, forming a layer structure. An intramolecular O—H⋯O hydrogen bond is also present. International Union of Crystallography 2008-08-06 /pmc/articles/PMC2960514/ /pubmed/21201594 http://dx.doi.org/10.1107/S1600536808024720 Text en © Cai et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Cai, Wen-Xuan
Zheng, Xiao-Yong
Geng, Xiao-Hong
Feng, Yun-Long
catena-Poly[[diaqua­[(4-tolyl­sulfan­yl)acetato-κO]cadmium(II)]-μ-4,4′-bipyridine-κ(2) N:N′]
title catena-Poly[[diaqua­[(4-tolyl­sulfan­yl)acetato-κO]cadmium(II)]-μ-4,4′-bipyridine-κ(2) N:N′]
title_full catena-Poly[[diaqua­[(4-tolyl­sulfan­yl)acetato-κO]cadmium(II)]-μ-4,4′-bipyridine-κ(2) N:N′]
title_fullStr catena-Poly[[diaqua­[(4-tolyl­sulfan­yl)acetato-κO]cadmium(II)]-μ-4,4′-bipyridine-κ(2) N:N′]
title_full_unstemmed catena-Poly[[diaqua­[(4-tolyl­sulfan­yl)acetato-κO]cadmium(II)]-μ-4,4′-bipyridine-κ(2) N:N′]
title_short catena-Poly[[diaqua­[(4-tolyl­sulfan­yl)acetato-κO]cadmium(II)]-μ-4,4′-bipyridine-κ(2) N:N′]
title_sort catena-poly[[diaqua­[(4-tolyl­sulfan­yl)acetato-κo]cadmium(ii)]-μ-4,4′-bipyridine-κ(2) n:n′]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960514/
https://www.ncbi.nlm.nih.gov/pubmed/21201594
http://dx.doi.org/10.1107/S1600536808024720
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