Bis[tris­(ethane-1,2-diamine)nickel(II)] octa­cyanidomolybdate(IV) dihydrate

The title complex, [Ni(II)(C(2)H(8)N(2))(3)](2)[Mo(IV)(CN)(8)]·2H(2)O, crystallized from a mixture of ethane-1,2-diamine (en), octa­cyano­molybdate(IV), [Mo(CN)(8)](4−), and the transition metal ion Ni(2+). In the crystal structure, the Mo polyhedron has a square-anti­prismatic shape, while the geom...

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Detalles Bibliográficos
Autores principales: Liu, Wen-Yan, Zhou, Hu, Guo, Ji-Xi, Yuan, Ai-Hua
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960526/
https://www.ncbi.nlm.nih.gov/pubmed/21201605
http://dx.doi.org/10.1107/S1600536808024963
Descripción
Sumario:The title complex, [Ni(II)(C(2)H(8)N(2))(3)](2)[Mo(IV)(CN)(8)]·2H(2)O, crystallized from a mixture of ethane-1,2-diamine (en), octa­cyano­molybdate(IV), [Mo(CN)(8)](4−), and the transition metal ion Ni(2+). In the crystal structure, the Mo polyhedron has a square-anti­prismatic shape, while the geometry around the Ni atom is distorted octa­hedral. The complex ions and water mol­ecules are linked by hydrogen bonds.

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