Bis[tris­(ethane-1,2-diamine)nickel(II)] octa­cyanidomolybdate(IV) dihydrate

The title complex, [Ni(II)(C(2)H(8)N(2))(3)](2)[Mo(IV)(CN)(8)]·2H(2)O, crystallized from a mixture of ethane-1,2-diamine (en), octa­cyano­molybdate(IV), [Mo(CN)(8)](4−), and the transition metal ion Ni(2+). In the crystal structure, the Mo polyhedron has a square-anti­prismatic shape, while the geom...

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Detalles Bibliográficos
Autores principales: Liu, Wen-Yan, Zhou, Hu, Guo, Ji-Xi, Yuan, Ai-Hua
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960526/
https://www.ncbi.nlm.nih.gov/pubmed/21201605
http://dx.doi.org/10.1107/S1600536808024963
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author Liu, Wen-Yan
Zhou, Hu
Guo, Ji-Xi
Yuan, Ai-Hua
author_facet Liu, Wen-Yan
Zhou, Hu
Guo, Ji-Xi
Yuan, Ai-Hua
author_sort Liu, Wen-Yan
collection PubMed
description The title complex, [Ni(II)(C(2)H(8)N(2))(3)](2)[Mo(IV)(CN)(8)]·2H(2)O, crystallized from a mixture of ethane-1,2-diamine (en), octa­cyano­molybdate(IV), [Mo(CN)(8)](4−), and the transition metal ion Ni(2+). In the crystal structure, the Mo polyhedron has a square-anti­prismatic shape, while the geometry around the Ni atom is distorted octa­hedral. The complex ions and water mol­ecules are linked by hydrogen bonds.
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spelling pubmed-29605262010-12-30 Bis[tris­(ethane-1,2-diamine)nickel(II)] octa­cyanidomolybdate(IV) dihydrate Liu, Wen-Yan Zhou, Hu Guo, Ji-Xi Yuan, Ai-Hua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Ni(II)(C(2)H(8)N(2))(3)](2)[Mo(IV)(CN)(8)]·2H(2)O, crystallized from a mixture of ethane-1,2-diamine (en), octa­cyano­molybdate(IV), [Mo(CN)(8)](4−), and the transition metal ion Ni(2+). In the crystal structure, the Mo polyhedron has a square-anti­prismatic shape, while the geometry around the Ni atom is distorted octa­hedral. The complex ions and water mol­ecules are linked by hydrogen bonds. International Union of Crystallography 2008-08-13 /pmc/articles/PMC2960526/ /pubmed/21201605 http://dx.doi.org/10.1107/S1600536808024963 Text en © Liu et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Wen-Yan
Zhou, Hu
Guo, Ji-Xi
Yuan, Ai-Hua
Bis[tris­(ethane-1,2-diamine)nickel(II)] octa­cyanidomolybdate(IV) dihydrate
title Bis[tris­(ethane-1,2-diamine)nickel(II)] octa­cyanidomolybdate(IV) dihydrate
title_full Bis[tris­(ethane-1,2-diamine)nickel(II)] octa­cyanidomolybdate(IV) dihydrate
title_fullStr Bis[tris­(ethane-1,2-diamine)nickel(II)] octa­cyanidomolybdate(IV) dihydrate
title_full_unstemmed Bis[tris­(ethane-1,2-diamine)nickel(II)] octa­cyanidomolybdate(IV) dihydrate
title_short Bis[tris­(ethane-1,2-diamine)nickel(II)] octa­cyanidomolybdate(IV) dihydrate
title_sort bis[tris­(ethane-1,2-diamine)nickel(ii)] octa­cyanidomolybdate(iv) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960526/
https://www.ncbi.nlm.nih.gov/pubmed/21201605
http://dx.doi.org/10.1107/S1600536808024963
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