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(μ-2-Pyridine­aldazine-κ(4) N,N′:N′′,N′′′)bis­[bis­(N,N-di-n-propyl­dithio­carbamato-κ(2) S,S′)cadmium(II)]

The dinuclear centrosymmetric title compound, [Cd(2)(C(7)H(14)NS(2))(4)(C(12)H(10)N(4))], features a tetra­dentate 2-pyridine­aldazine ligand that chelates two Cd centres. The coordination geometry for Cd is distorted octa­hedral based on a cis-N(2)S(4) donor set. In the crystal structure, mol­ecule...

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Detalles Bibliográficos
Autores principales: Poplaukhin, Pavel, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960527/
https://www.ncbi.nlm.nih.gov/pubmed/21201620
http://dx.doi.org/10.1107/S1600536808025889
Descripción
Sumario:The dinuclear centrosymmetric title compound, [Cd(2)(C(7)H(14)NS(2))(4)(C(12)H(10)N(4))], features a tetra­dentate 2-pyridine­aldazine ligand that chelates two Cd centres. The coordination geometry for Cd is distorted octa­hedral based on a cis-N(2)S(4) donor set. In the crystal structure, mol­ecules are connected into a supra­molecular chain aligned along the a direction via C—H⋯S and C—H⋯π contacts, and by π–π contacts [centroid-to-centroid distance 3.5708 (15) Å]. The n-propyl groups are each disordered, one equally over two sites and the other with a site-occupancy factor of 0.618 (8) for the major component.