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(μ-2-Pyridinealdazine-κ(4) N,N′:N′′,N′′′)bis[bis(N,N-di-n-propyldithiocarbamato-κ(2) S,S′)cadmium(II)]
The dinuclear centrosymmetric title compound, [Cd(2)(C(7)H(14)NS(2))(4)(C(12)H(10)N(4))], features a tetradentate 2-pyridinealdazine ligand that chelates two Cd centres. The coordination geometry for Cd is distorted octahedral based on a cis-N(2)S(4) donor set. In the crystal structure, molecule...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960527/ https://www.ncbi.nlm.nih.gov/pubmed/21201620 http://dx.doi.org/10.1107/S1600536808025889 |
Sumario: | The dinuclear centrosymmetric title compound, [Cd(2)(C(7)H(14)NS(2))(4)(C(12)H(10)N(4))], features a tetradentate 2-pyridinealdazine ligand that chelates two Cd centres. The coordination geometry for Cd is distorted octahedral based on a cis-N(2)S(4) donor set. In the crystal structure, molecules are connected into a supramolecular chain aligned along the a direction via C—H⋯S and C—H⋯π contacts, and by π–π contacts [centroid-to-centroid distance 3.5708 (15) Å]. The n-propyl groups are each disordered, one equally over two sites and the other with a site-occupancy factor of 0.618 (8) for the major component. |
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