Cargando…

(μ-2-Pyridine­aldazine-κ(4) N,N′:N′′,N′′′)bis­[bis­(N,N-di-n-propyl­dithio­carbamato-κ(2) S,S′)cadmium(II)]

The dinuclear centrosymmetric title compound, [Cd(2)(C(7)H(14)NS(2))(4)(C(12)H(10)N(4))], features a tetra­dentate 2-pyridine­aldazine ligand that chelates two Cd centres. The coordination geometry for Cd is distorted octa­hedral based on a cis-N(2)S(4) donor set. In the crystal structure, mol­ecule...

Descripción completa

Detalles Bibliográficos
Autores principales: Poplaukhin, Pavel, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960527/
https://www.ncbi.nlm.nih.gov/pubmed/21201620
http://dx.doi.org/10.1107/S1600536808025889
_version_ 1782188761343328256
author Poplaukhin, Pavel
Tiekink, Edward R. T.
author_facet Poplaukhin, Pavel
Tiekink, Edward R. T.
author_sort Poplaukhin, Pavel
collection PubMed
description The dinuclear centrosymmetric title compound, [Cd(2)(C(7)H(14)NS(2))(4)(C(12)H(10)N(4))], features a tetra­dentate 2-pyridine­aldazine ligand that chelates two Cd centres. The coordination geometry for Cd is distorted octa­hedral based on a cis-N(2)S(4) donor set. In the crystal structure, mol­ecules are connected into a supra­molecular chain aligned along the a direction via C—H⋯S and C—H⋯π contacts, and by π–π contacts [centroid-to-centroid distance 3.5708 (15) Å]. The n-propyl groups are each disordered, one equally over two sites and the other with a site-occupancy factor of 0.618 (8) for the major component.
format Text
id pubmed-2960527
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29605272010-12-30 (μ-2-Pyridine­aldazine-κ(4) N,N′:N′′,N′′′)bis­[bis­(N,N-di-n-propyl­dithio­carbamato-κ(2) S,S′)cadmium(II)] Poplaukhin, Pavel Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The dinuclear centrosymmetric title compound, [Cd(2)(C(7)H(14)NS(2))(4)(C(12)H(10)N(4))], features a tetra­dentate 2-pyridine­aldazine ligand that chelates two Cd centres. The coordination geometry for Cd is distorted octa­hedral based on a cis-N(2)S(4) donor set. In the crystal structure, mol­ecules are connected into a supra­molecular chain aligned along the a direction via C—H⋯S and C—H⋯π contacts, and by π–π contacts [centroid-to-centroid distance 3.5708 (15) Å]. The n-propyl groups are each disordered, one equally over two sites and the other with a site-occupancy factor of 0.618 (8) for the major component. International Union of Crystallography 2008-08-16 /pmc/articles/PMC2960527/ /pubmed/21201620 http://dx.doi.org/10.1107/S1600536808025889 Text en © Poplaukhin and Tiekink 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Poplaukhin, Pavel
Tiekink, Edward R. T.
(μ-2-Pyridine­aldazine-κ(4) N,N′:N′′,N′′′)bis­[bis­(N,N-di-n-propyl­dithio­carbamato-κ(2) S,S′)cadmium(II)]
title (μ-2-Pyridine­aldazine-κ(4) N,N′:N′′,N′′′)bis­[bis­(N,N-di-n-propyl­dithio­carbamato-κ(2) S,S′)cadmium(II)]
title_full (μ-2-Pyridine­aldazine-κ(4) N,N′:N′′,N′′′)bis­[bis­(N,N-di-n-propyl­dithio­carbamato-κ(2) S,S′)cadmium(II)]
title_fullStr (μ-2-Pyridine­aldazine-κ(4) N,N′:N′′,N′′′)bis­[bis­(N,N-di-n-propyl­dithio­carbamato-κ(2) S,S′)cadmium(II)]
title_full_unstemmed (μ-2-Pyridine­aldazine-κ(4) N,N′:N′′,N′′′)bis­[bis­(N,N-di-n-propyl­dithio­carbamato-κ(2) S,S′)cadmium(II)]
title_short (μ-2-Pyridine­aldazine-κ(4) N,N′:N′′,N′′′)bis­[bis­(N,N-di-n-propyl­dithio­carbamato-κ(2) S,S′)cadmium(II)]
title_sort (μ-2-pyridine­aldazine-κ(4) n,n′:n′′,n′′′)bis­[bis­(n,n-di-n-propyl­dithio­carbamato-κ(2) s,s′)cadmium(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960527/
https://www.ncbi.nlm.nih.gov/pubmed/21201620
http://dx.doi.org/10.1107/S1600536808025889
work_keys_str_mv AT poplaukhinpavel m2pyridinealdazinek4nnnnbisbisnndinpropyldithiocarbamatok2sscadmiumii
AT tiekinkedwardrt m2pyridinealdazinek4nnnnbisbisnndinpropyldithiocarbamatok2sscadmiumii