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(μ-2-Pyridinealdazine-κ(4) N,N′:N′′,N′′′)bis[bis(N,N-di-n-propyldithiocarbamato-κ(2) S,S′)cadmium(II)]
The dinuclear centrosymmetric title compound, [Cd(2)(C(7)H(14)NS(2))(4)(C(12)H(10)N(4))], features a tetradentate 2-pyridinealdazine ligand that chelates two Cd centres. The coordination geometry for Cd is distorted octahedral based on a cis-N(2)S(4) donor set. In the crystal structure, molecule...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960527/ https://www.ncbi.nlm.nih.gov/pubmed/21201620 http://dx.doi.org/10.1107/S1600536808025889 |
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author | Poplaukhin, Pavel Tiekink, Edward R. T. |
author_facet | Poplaukhin, Pavel Tiekink, Edward R. T. |
author_sort | Poplaukhin, Pavel |
collection | PubMed |
description | The dinuclear centrosymmetric title compound, [Cd(2)(C(7)H(14)NS(2))(4)(C(12)H(10)N(4))], features a tetradentate 2-pyridinealdazine ligand that chelates two Cd centres. The coordination geometry for Cd is distorted octahedral based on a cis-N(2)S(4) donor set. In the crystal structure, molecules are connected into a supramolecular chain aligned along the a direction via C—H⋯S and C—H⋯π contacts, and by π–π contacts [centroid-to-centroid distance 3.5708 (15) Å]. The n-propyl groups are each disordered, one equally over two sites and the other with a site-occupancy factor of 0.618 (8) for the major component. |
format | Text |
id | pubmed-2960527 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29605272010-12-30 (μ-2-Pyridinealdazine-κ(4) N,N′:N′′,N′′′)bis[bis(N,N-di-n-propyldithiocarbamato-κ(2) S,S′)cadmium(II)] Poplaukhin, Pavel Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The dinuclear centrosymmetric title compound, [Cd(2)(C(7)H(14)NS(2))(4)(C(12)H(10)N(4))], features a tetradentate 2-pyridinealdazine ligand that chelates two Cd centres. The coordination geometry for Cd is distorted octahedral based on a cis-N(2)S(4) donor set. In the crystal structure, molecules are connected into a supramolecular chain aligned along the a direction via C—H⋯S and C—H⋯π contacts, and by π–π contacts [centroid-to-centroid distance 3.5708 (15) Å]. The n-propyl groups are each disordered, one equally over two sites and the other with a site-occupancy factor of 0.618 (8) for the major component. International Union of Crystallography 2008-08-16 /pmc/articles/PMC2960527/ /pubmed/21201620 http://dx.doi.org/10.1107/S1600536808025889 Text en © Poplaukhin and Tiekink 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Poplaukhin, Pavel Tiekink, Edward R. T. (μ-2-Pyridinealdazine-κ(4) N,N′:N′′,N′′′)bis[bis(N,N-di-n-propyldithiocarbamato-κ(2) S,S′)cadmium(II)] |
title | (μ-2-Pyridinealdazine-κ(4)
N,N′:N′′,N′′′)bis[bis(N,N-di-n-propyldithiocarbamato-κ(2)
S,S′)cadmium(II)] |
title_full | (μ-2-Pyridinealdazine-κ(4)
N,N′:N′′,N′′′)bis[bis(N,N-di-n-propyldithiocarbamato-κ(2)
S,S′)cadmium(II)] |
title_fullStr | (μ-2-Pyridinealdazine-κ(4)
N,N′:N′′,N′′′)bis[bis(N,N-di-n-propyldithiocarbamato-κ(2)
S,S′)cadmium(II)] |
title_full_unstemmed | (μ-2-Pyridinealdazine-κ(4)
N,N′:N′′,N′′′)bis[bis(N,N-di-n-propyldithiocarbamato-κ(2)
S,S′)cadmium(II)] |
title_short | (μ-2-Pyridinealdazine-κ(4)
N,N′:N′′,N′′′)bis[bis(N,N-di-n-propyldithiocarbamato-κ(2)
S,S′)cadmium(II)] |
title_sort | (μ-2-pyridinealdazine-κ(4)
n,n′:n′′,n′′′)bis[bis(n,n-di-n-propyldithiocarbamato-κ(2)
s,s′)cadmium(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960527/ https://www.ncbi.nlm.nih.gov/pubmed/21201620 http://dx.doi.org/10.1107/S1600536808025889 |
work_keys_str_mv | AT poplaukhinpavel m2pyridinealdazinek4nnnnbisbisnndinpropyldithiocarbamatok2sscadmiumii AT tiekinkedwardrt m2pyridinealdazinek4nnnnbisbisnndinpropyldithiocarbamatok2sscadmiumii |