Bis(4,6-diamino­pyrimidin-2-yl) disulfide dimethyl sufoxide disolvate

The title compound, C(8)H(10)N(8)S(2)·2C(2)H(6)SO, was obtained unintentionally during an attempt to prepare a thiol­ate derivative of trimethyl­tin. The complete disulfide mol­ecule is generated by twofold rotation symmetry and the C—S—S—C torsion angle around the S—S bond is −85.70 (10)°. The mol­...

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Autores principales: Papastavrou, Ephthymia, Shakhatreh, Saleh, Akrivos, Pericles D., Gdaniec, Maria
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960530/
https://www.ncbi.nlm.nih.gov/pubmed/21201707
http://dx.doi.org/10.1107/S160053680802480X
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author Papastavrou, Ephthymia
Shakhatreh, Saleh
Akrivos, Pericles D.
Gdaniec, Maria
author_facet Papastavrou, Ephthymia
Shakhatreh, Saleh
Akrivos, Pericles D.
Gdaniec, Maria
author_sort Papastavrou, Ephthymia
collection PubMed
description The title compound, C(8)H(10)N(8)S(2)·2C(2)H(6)SO, was obtained unintentionally during an attempt to prepare a thiol­ate derivative of trimethyl­tin. The complete disulfide mol­ecule is generated by twofold rotation symmetry and the C—S—S—C torsion angle around the S—S bond is −85.70 (10)°. The mol­ecules are connected via N—H⋯N hydrogen bonds into strongly corrugated layers parallel to (001), generating an R (2) (2)(8) motif. The solvent mol­ecule, which exhibits minor disorder of its S atom [site occupancies = 0.9591 (18) and 0.0409 (18)], is linked to this layer via a pair of N—H⋯O inter­actions.
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spelling pubmed-29605302010-12-30 Bis(4,6-diamino­pyrimidin-2-yl) disulfide dimethyl sufoxide disolvate Papastavrou, Ephthymia Shakhatreh, Saleh Akrivos, Pericles D. Gdaniec, Maria Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(8)H(10)N(8)S(2)·2C(2)H(6)SO, was obtained unintentionally during an attempt to prepare a thiol­ate derivative of trimethyl­tin. The complete disulfide mol­ecule is generated by twofold rotation symmetry and the C—S—S—C torsion angle around the S—S bond is −85.70 (10)°. The mol­ecules are connected via N—H⋯N hydrogen bonds into strongly corrugated layers parallel to (001), generating an R (2) (2)(8) motif. The solvent mol­ecule, which exhibits minor disorder of its S atom [site occupancies = 0.9591 (18) and 0.0409 (18)], is linked to this layer via a pair of N—H⋯O inter­actions. International Union of Crystallography 2008-08-09 /pmc/articles/PMC2960530/ /pubmed/21201707 http://dx.doi.org/10.1107/S160053680802480X Text en © Papastavrou et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Papastavrou, Ephthymia
Shakhatreh, Saleh
Akrivos, Pericles D.
Gdaniec, Maria
Bis(4,6-diamino­pyrimidin-2-yl) disulfide dimethyl sufoxide disolvate
title Bis(4,6-diamino­pyrimidin-2-yl) disulfide dimethyl sufoxide disolvate
title_full Bis(4,6-diamino­pyrimidin-2-yl) disulfide dimethyl sufoxide disolvate
title_fullStr Bis(4,6-diamino­pyrimidin-2-yl) disulfide dimethyl sufoxide disolvate
title_full_unstemmed Bis(4,6-diamino­pyrimidin-2-yl) disulfide dimethyl sufoxide disolvate
title_short Bis(4,6-diamino­pyrimidin-2-yl) disulfide dimethyl sufoxide disolvate
title_sort bis(4,6-diamino­pyrimidin-2-yl) disulfide dimethyl sufoxide disolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960530/
https://www.ncbi.nlm.nih.gov/pubmed/21201707
http://dx.doi.org/10.1107/S160053680802480X
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AT akrivospericlesd bis46diaminopyrimidin2yldisulfidedimethylsufoxidedisolvate
AT gdaniecmaria bis46diaminopyrimidin2yldisulfidedimethylsufoxidedisolvate

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