catena-Poly[[triaqua­zinc(II)]-μ-1H-1,2,4-triazole-3,5-dicarboxyl­ato]

In the title compound, [Zn(C(4)HN(3)O(4))(H(2)O)(3)](n), each Zn(II) atom adopts a distorted octa­hedral coordination geometry, being surrounded by one chelating and one monodentate 1H-1,2,4-triazole-3,5-dicarboxyl­ate ligand and three water mol­ecules. Adjacent Zn(II) cations are linked by a 1H-1,2...

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Detalles Bibliográficos
Autores principales: Sun, Yan-Yan, Zhang, Ya-Wen, Zhang, Gong, Cheng, Lin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960531/
https://www.ncbi.nlm.nih.gov/pubmed/21201577
http://dx.doi.org/10.1107/S1600536808023994
Descripción
Sumario:In the title compound, [Zn(C(4)HN(3)O(4))(H(2)O)(3)](n), each Zn(II) atom adopts a distorted octa­hedral coordination geometry, being surrounded by one chelating and one monodentate 1H-1,2,4-triazole-3,5-dicarboxyl­ate ligand and three water mol­ecules. Adjacent Zn(II) cations are linked by a 1H-1,2,4-triazole-3,5-dicarboxyl­ate ligand in a μ(2),κ(3) fashion to form a chain running along the c axis. The crystal packing is stabilized by N—H⋯O, O—H⋯N and O—H⋯O hydrogen bonds.

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