Cargando…
Ethyl 1’-[1-(4-methoxyphenyl)-3-phenoxy-4-phenylazetidin-1-yl]-1,3-dioxo-2′,3′,5′,6′,7′,7a′-hexahydroindan-2-spiro-3′-1′H-pyrrolizine-2′-carboxylate
In the title compound, C(34)H(32)N(2)O(7), the methyl group and methylene H atoms of the ethoxycarbonyl substituent are disordered over two positions with site occupancy factors for the major and minor conformers of 0.594 (8) and 0.406 (8), respectively. The unsubstituted ring of the pyrrolizine rin...
Autores principales: | , , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960533/ https://www.ncbi.nlm.nih.gov/pubmed/21201806 http://dx.doi.org/10.1107/S1600536808026913 |
_version_ | 1782188762791411712 |
---|---|
author | Kamala, E. Theboral Sugi Nirmala, S. Sudha, L. Arumugam, N. Raghunathan, R. |
author_facet | Kamala, E. Theboral Sugi Nirmala, S. Sudha, L. Arumugam, N. Raghunathan, R. |
author_sort | Kamala, E. Theboral Sugi |
collection | PubMed |
description | In the title compound, C(34)H(32)N(2)O(7), the methyl group and methylene H atoms of the ethoxycarbonyl substituent are disordered over two positions with site occupancy factors for the major and minor conformers of 0.594 (8) and 0.406 (8), respectively. The unsubstituted ring of the pyrrolizine ring system exhibits a twist conformation, the other an envelope conformation. In the crystal structure, molecules are linked through C—H⋯O hydrogen bonds; intramolecular C—H⋯O interactions are also observed. |
format | Text |
id | pubmed-2960533 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29605332010-12-30 Ethyl 1’-[1-(4-methoxyphenyl)-3-phenoxy-4-phenylazetidin-1-yl]-1,3-dioxo-2′,3′,5′,6′,7′,7a′-hexahydroindan-2-spiro-3′-1′H-pyrrolizine-2′-carboxylate Kamala, E. Theboral Sugi Nirmala, S. Sudha, L. Arumugam, N. Raghunathan, R. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(34)H(32)N(2)O(7), the methyl group and methylene H atoms of the ethoxycarbonyl substituent are disordered over two positions with site occupancy factors for the major and minor conformers of 0.594 (8) and 0.406 (8), respectively. The unsubstituted ring of the pyrrolizine ring system exhibits a twist conformation, the other an envelope conformation. In the crystal structure, molecules are linked through C—H⋯O hydrogen bonds; intramolecular C—H⋯O interactions are also observed. International Union of Crystallography 2008-08-30 /pmc/articles/PMC2960533/ /pubmed/21201806 http://dx.doi.org/10.1107/S1600536808026913 Text en © Kamala et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Kamala, E. Theboral Sugi Nirmala, S. Sudha, L. Arumugam, N. Raghunathan, R. Ethyl 1’-[1-(4-methoxyphenyl)-3-phenoxy-4-phenylazetidin-1-yl]-1,3-dioxo-2′,3′,5′,6′,7′,7a′-hexahydroindan-2-spiro-3′-1′H-pyrrolizine-2′-carboxylate |
title | Ethyl 1’-[1-(4-methoxyphenyl)-3-phenoxy-4-phenylazetidin-1-yl]-1,3-dioxo-2′,3′,5′,6′,7′,7a′-hexahydroindan-2-spiro-3′-1′H-pyrrolizine-2′-carboxylate |
title_full | Ethyl 1’-[1-(4-methoxyphenyl)-3-phenoxy-4-phenylazetidin-1-yl]-1,3-dioxo-2′,3′,5′,6′,7′,7a′-hexahydroindan-2-spiro-3′-1′H-pyrrolizine-2′-carboxylate |
title_fullStr | Ethyl 1’-[1-(4-methoxyphenyl)-3-phenoxy-4-phenylazetidin-1-yl]-1,3-dioxo-2′,3′,5′,6′,7′,7a′-hexahydroindan-2-spiro-3′-1′H-pyrrolizine-2′-carboxylate |
title_full_unstemmed | Ethyl 1’-[1-(4-methoxyphenyl)-3-phenoxy-4-phenylazetidin-1-yl]-1,3-dioxo-2′,3′,5′,6′,7′,7a′-hexahydroindan-2-spiro-3′-1′H-pyrrolizine-2′-carboxylate |
title_short | Ethyl 1’-[1-(4-methoxyphenyl)-3-phenoxy-4-phenylazetidin-1-yl]-1,3-dioxo-2′,3′,5′,6′,7′,7a′-hexahydroindan-2-spiro-3′-1′H-pyrrolizine-2′-carboxylate |
title_sort | ethyl 1’-[1-(4-methoxyphenyl)-3-phenoxy-4-phenylazetidin-1-yl]-1,3-dioxo-2′,3′,5′,6′,7′,7a′-hexahydroindan-2-spiro-3′-1′h-pyrrolizine-2′-carboxylate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960533/ https://www.ncbi.nlm.nih.gov/pubmed/21201806 http://dx.doi.org/10.1107/S1600536808026913 |
work_keys_str_mv | AT kamalaetheboralsugi ethyl114methoxyphenyl3phenoxy4phenylazetidin1yl13dioxo235677ahexahydroindan2spiro31hpyrrolizine2carboxylate AT nirmalas ethyl114methoxyphenyl3phenoxy4phenylazetidin1yl13dioxo235677ahexahydroindan2spiro31hpyrrolizine2carboxylate AT sudhal ethyl114methoxyphenyl3phenoxy4phenylazetidin1yl13dioxo235677ahexahydroindan2spiro31hpyrrolizine2carboxylate AT arumugamn ethyl114methoxyphenyl3phenoxy4phenylazetidin1yl13dioxo235677ahexahydroindan2spiro31hpyrrolizine2carboxylate AT raghunathanr ethyl114methoxyphenyl3phenoxy4phenylazetidin1yl13dioxo235677ahexahydroindan2spiro31hpyrrolizine2carboxylate |