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3-(5,6,7,8-Tetrahydro-2-naphthyl)isobenzofuran-1(3H)-one
The title compound, C(18)H(16)O(2), was prepared by reduction of 2-(5,6,7,8-tetrahydro-2-naphthoyl)benzoic acid with zinc dust. The benzene ring in the tetrahydronaphthyl substituent is nearly perpendicular to the plane of the isobenzofuran-1(3H)-one ring [87.15 (4)°]. The cyclohexane unit has...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960543/ https://www.ncbi.nlm.nih.gov/pubmed/21201685 http://dx.doi.org/10.1107/S1600536808024598 |
Sumario: | The title compound, C(18)H(16)O(2), was prepared by reduction of 2-(5,6,7,8-tetrahydro-2-naphthoyl)benzoic acid with zinc dust. The benzene ring in the tetrahydronaphthyl substituent is nearly perpendicular to the plane of the isobenzofuran-1(3H)-one ring [87.15 (4)°]. The cyclohexane unit has a half-chair conformation in which two methylene groups in the tetramethylene bridge are disordered over two positions; the site-occupancy factors are 0.838 (4) and 0.162 (4). The crystal structure exhibits alternating isobenzofuran-1(3H)-one and tetrahydronaphthalene layers. |
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