3-(5,6,7,8-Tetra­hydro-2-naphth­yl)iso­benzofuran-1(3H)-one

The title compound, C(18)H(16)O(2), was prepared by reduction of 2-(5,6,7,8-tetra­hydro-2-naphtho­yl)benzoic acid with zinc dust. The benzene ring in the tetra­hydro­naphthyl substituent is nearly perpendicular to the plane of the isobenzofuran-1(3H)-one ring [87.15 (4)°]. The cyclo­hexane unit has...

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Detalles Bibliográficos
Autores principales: Kitamura, Chitoshi, Kawase, Takeshi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960543/
https://www.ncbi.nlm.nih.gov/pubmed/21201685
http://dx.doi.org/10.1107/S1600536808024598
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author Kitamura, Chitoshi
Kawase, Takeshi
author_facet Kitamura, Chitoshi
Kawase, Takeshi
author_sort Kitamura, Chitoshi
collection PubMed
description The title compound, C(18)H(16)O(2), was prepared by reduction of 2-(5,6,7,8-tetra­hydro-2-naphtho­yl)benzoic acid with zinc dust. The benzene ring in the tetra­hydro­naphthyl substituent is nearly perpendicular to the plane of the isobenzofuran-1(3H)-one ring [87.15 (4)°]. The cyclo­hexane unit has a half-chair conformation in which two methylene groups in the tetra­methyl­ene bridge are disordered over two positions; the site-occupancy factors are 0.838 (4) and 0.162 (4). The crystal structure exhibits alternating isobenzofuran-1(3H)-one and tetra­hydro­naphthalene layers.
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spelling pubmed-29605432010-12-30 3-(5,6,7,8-Tetra­hydro-2-naphth­yl)iso­benzofuran-1(3H)-one Kitamura, Chitoshi Kawase, Takeshi Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(18)H(16)O(2), was prepared by reduction of 2-(5,6,7,8-tetra­hydro-2-naphtho­yl)benzoic acid with zinc dust. The benzene ring in the tetra­hydro­naphthyl substituent is nearly perpendicular to the plane of the isobenzofuran-1(3H)-one ring [87.15 (4)°]. The cyclo­hexane unit has a half-chair conformation in which two methylene groups in the tetra­methyl­ene bridge are disordered over two positions; the site-occupancy factors are 0.838 (4) and 0.162 (4). The crystal structure exhibits alternating isobenzofuran-1(3H)-one and tetra­hydro­naphthalene layers. International Union of Crystallography 2008-08-06 /pmc/articles/PMC2960543/ /pubmed/21201685 http://dx.doi.org/10.1107/S1600536808024598 Text en © Kitamura and Kawase 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kitamura, Chitoshi
Kawase, Takeshi
3-(5,6,7,8-Tetra­hydro-2-naphth­yl)iso­benzofuran-1(3H)-one
title 3-(5,6,7,8-Tetra­hydro-2-naphth­yl)iso­benzofuran-1(3H)-one
title_full 3-(5,6,7,8-Tetra­hydro-2-naphth­yl)iso­benzofuran-1(3H)-one
title_fullStr 3-(5,6,7,8-Tetra­hydro-2-naphth­yl)iso­benzofuran-1(3H)-one
title_full_unstemmed 3-(5,6,7,8-Tetra­hydro-2-naphth­yl)iso­benzofuran-1(3H)-one
title_short 3-(5,6,7,8-Tetra­hydro-2-naphth­yl)iso­benzofuran-1(3H)-one
title_sort 3-(5,6,7,8-tetra­hydro-2-naphth­yl)iso­benzofuran-1(3h)-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960543/
https://www.ncbi.nlm.nih.gov/pubmed/21201685
http://dx.doi.org/10.1107/S1600536808024598
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AT kawasetakeshi 35678tetrahydro2naphthylisobenzofuran13hone

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