Methyl 2-(5-methyl-3-methyl­sulfinyl-1-benzofuran-2-yl)acetate

The title compound, C(13)H(14)O(4)S, was prepared by oxidation of methyl 2-(5-methyl-3-methyl­sulfanyl-1-benzofuran-2-yl)acetate with 3-chloro­peroxy­benzoic acid. The O atom and methyl group of the methyl­sulfinyl substituent lie on opposite sides of the plane of the benzofuran system. The crystal...

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Detalles Bibliográficos
Autores principales: Choi, Hong Dae, Seo, Pil Ja, Son, Byeng Wha, Lee, Uk
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960547/
https://www.ncbi.nlm.nih.gov/pubmed/21201698
http://dx.doi.org/10.1107/S1600536808024689
Descripción
Sumario:The title compound, C(13)H(14)O(4)S, was prepared by oxidation of methyl 2-(5-methyl-3-methyl­sulfanyl-1-benzofuran-2-yl)acetate with 3-chloro­peroxy­benzoic acid. The O atom and methyl group of the methyl­sulfinyl substituent lie on opposite sides of the plane of the benzofuran system. The crystal structure is stabilized by inter­molecular aromatic π–π inter­actions between the benzene rings of neighbouring mol­ecules, with a centroid–centroid separation of 3.841 (3) Å.

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