Cargando…

(Z)-3-Ferrocenyl-2-(3-pyrid­yl)­acrylo­nitrile

The mol­ecular structure of the title compound, [Fe(C(5)H(5))(C(13)H(9)N(2))], (I), is analogous to that of the compound (Z)-3-ferrocenyl-2-phenyl­acrylonitrile [Cao & Ye (2008). Acta Cryst. E64, m822], (II), with the pyridine ring in (I) replacing the benzene ring in (II). While the correspondi...

Descripción completa

Detalles Bibliográficos
Autores principales: Chen, Fang, Ye, Heng-Yun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960549/
https://www.ncbi.nlm.nih.gov/pubmed/21201613
http://dx.doi.org/10.1107/S1600536808025531
_version_ 1782188766670094336
author Chen, Fang
Ye, Heng-Yun
author_facet Chen, Fang
Ye, Heng-Yun
author_sort Chen, Fang
collection PubMed
description The mol­ecular structure of the title compound, [Fe(C(5)H(5))(C(13)H(9)N(2))], (I), is analogous to that of the compound (Z)-3-ferrocenyl-2-phenyl­acrylonitrile [Cao & Ye (2008). Acta Cryst. E64, m822], (II), with the pyridine ring in (I) replacing the benzene ring in (II). While the corresponding bond distances and angles in the two compounds show no significant differences, the two dihedral angles between the planes through the acrylonitrile group and the two rings attached to it (substituted Cp and pyridine) of 16.8 (4) and 20.1 (4)° in (I) are different from the corresponding dihedral angles [19.6 (3) and 6.5 (4)°] in (II). The unsubstituted ring is disordered over two positions, with site-occupancy factors of 0.70 (1) and 0.30 (1). The major and minor components of the disordered ring are almost coplanar and are also parallel to the substituted cyclo­penta­diene ring plane, with a dihedral angle of 0.3 (6)°.
format Text
id pubmed-2960549
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29605492010-12-30 (Z)-3-Ferrocenyl-2-(3-pyrid­yl)­acrylo­nitrile Chen, Fang Ye, Heng-Yun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The mol­ecular structure of the title compound, [Fe(C(5)H(5))(C(13)H(9)N(2))], (I), is analogous to that of the compound (Z)-3-ferrocenyl-2-phenyl­acrylonitrile [Cao & Ye (2008). Acta Cryst. E64, m822], (II), with the pyridine ring in (I) replacing the benzene ring in (II). While the corresponding bond distances and angles in the two compounds show no significant differences, the two dihedral angles between the planes through the acrylonitrile group and the two rings attached to it (substituted Cp and pyridine) of 16.8 (4) and 20.1 (4)° in (I) are different from the corresponding dihedral angles [19.6 (3) and 6.5 (4)°] in (II). The unsubstituted ring is disordered over two positions, with site-occupancy factors of 0.70 (1) and 0.30 (1). The major and minor components of the disordered ring are almost coplanar and are also parallel to the substituted cyclo­penta­diene ring plane, with a dihedral angle of 0.3 (6)°. International Union of Crystallography 2008-08-16 /pmc/articles/PMC2960549/ /pubmed/21201613 http://dx.doi.org/10.1107/S1600536808025531 Text en © Chen and Ye 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chen, Fang
Ye, Heng-Yun
(Z)-3-Ferrocenyl-2-(3-pyrid­yl)­acrylo­nitrile
title (Z)-3-Ferrocenyl-2-(3-pyrid­yl)­acrylo­nitrile
title_full (Z)-3-Ferrocenyl-2-(3-pyrid­yl)­acrylo­nitrile
title_fullStr (Z)-3-Ferrocenyl-2-(3-pyrid­yl)­acrylo­nitrile
title_full_unstemmed (Z)-3-Ferrocenyl-2-(3-pyrid­yl)­acrylo­nitrile
title_short (Z)-3-Ferrocenyl-2-(3-pyrid­yl)­acrylo­nitrile
title_sort (z)-3-ferrocenyl-2-(3-pyrid­yl)­acrylo­nitrile
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960549/
https://www.ncbi.nlm.nih.gov/pubmed/21201613
http://dx.doi.org/10.1107/S1600536808025531
work_keys_str_mv AT chenfang z3ferrocenyl23pyridylacrylonitrile
AT yehengyun z3ferrocenyl23pyridylacrylonitrile