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Tetra-μ-benzoato-bis[(3-methylquinoline)copper(II)](Cu—Cu)
In the title compound, [Cu(2)(C(7)H(5)O(2))(4)(C(10)H(9)N)(2)], the paddle-wheel-type dinuclear complex molecule contains four bridging benzoate groups and two terminal 3-methylquinoline ligands. The asymmetric unit contains one and a half molecules with a total of three independent Cu atoms; the...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960550/ https://www.ncbi.nlm.nih.gov/pubmed/21201597 http://dx.doi.org/10.1107/S1600536808024859 |
Sumario: | In the title compound, [Cu(2)(C(7)H(5)O(2))(4)(C(10)H(9)N)(2)], the paddle-wheel-type dinuclear complex molecule contains four bridging benzoate groups and two terminal 3-methylquinoline ligands. The asymmetric unit contains one and a half molecules with a total of three independent Cu atoms; there is an inversion center at the mid-point of the Cu⋯Cu bond in one molecule. The octahedral coordination of each Cu atom, with four O atoms in the equatorial plane, is completed by an N atom of a 3-methylquinoline ligand [Cu—N = 2.190 (4)–2.203 (3) Å] and by another Cu atom [Cu⋯Cu = 2.667 (1) and 2.6703 (7) Å]. The Cu atoms are all ca 0.22 Å out of the plane of the four bonded O atoms. |
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