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Tetra-μ-benzoato-bis­[(3-methyl­quinoline)copper(II)](Cu—Cu)

In the title compound, [Cu(2)(C(7)H(5)O(2))(4)(C(10)H(9)N)(2)], the paddle-wheel-type dinuclear complex mol­ecule contains four bridging benzoate groups and two terminal 3-methyl­quinoline ligands. The asymmetric unit contains one and a half mol­ecules with a total of three independent Cu atoms; the...

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Autores principales: Park, Byeong Kwon, Jang, Kyung-Hwan, Kim, Pan-Gi, Kim, Cheal, Kim, Youngmee
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960550/
https://www.ncbi.nlm.nih.gov/pubmed/21201597
http://dx.doi.org/10.1107/S1600536808024859
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author Park, Byeong Kwon
Jang, Kyung-Hwan
Kim, Pan-Gi
Kim, Cheal
Kim, Youngmee
author_facet Park, Byeong Kwon
Jang, Kyung-Hwan
Kim, Pan-Gi
Kim, Cheal
Kim, Youngmee
author_sort Park, Byeong Kwon
collection PubMed
description In the title compound, [Cu(2)(C(7)H(5)O(2))(4)(C(10)H(9)N)(2)], the paddle-wheel-type dinuclear complex mol­ecule contains four bridging benzoate groups and two terminal 3-methyl­quinoline ligands. The asymmetric unit contains one and a half mol­ecules with a total of three independent Cu atoms; there is an inversion center at the mid-point of the Cu⋯Cu bond in one molecule. The octa­hedral coordination of each Cu atom, with four O atoms in the equatorial plane, is completed by an N atom of a 3-methyl­quinoline ligand [Cu—N = 2.190 (4)–2.203 (3) Å] and by another Cu atom [Cu⋯Cu = 2.667 (1) and 2.6703 (7) Å]. The Cu atoms are all ca 0.22 Å out of the plane of the four bonded O atoms.
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spelling pubmed-29605502010-12-30 Tetra-μ-benzoato-bis­[(3-methyl­quinoline)copper(II)](Cu—Cu) Park, Byeong Kwon Jang, Kyung-Hwan Kim, Pan-Gi Kim, Cheal Kim, Youngmee Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(2)(C(7)H(5)O(2))(4)(C(10)H(9)N)(2)], the paddle-wheel-type dinuclear complex mol­ecule contains four bridging benzoate groups and two terminal 3-methyl­quinoline ligands. The asymmetric unit contains one and a half mol­ecules with a total of three independent Cu atoms; there is an inversion center at the mid-point of the Cu⋯Cu bond in one molecule. The octa­hedral coordination of each Cu atom, with four O atoms in the equatorial plane, is completed by an N atom of a 3-methyl­quinoline ligand [Cu—N = 2.190 (4)–2.203 (3) Å] and by another Cu atom [Cu⋯Cu = 2.667 (1) and 2.6703 (7) Å]. The Cu atoms are all ca 0.22 Å out of the plane of the four bonded O atoms. International Union of Crystallography 2008-08-09 /pmc/articles/PMC2960550/ /pubmed/21201597 http://dx.doi.org/10.1107/S1600536808024859 Text en © Park et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Park, Byeong Kwon
Jang, Kyung-Hwan
Kim, Pan-Gi
Kim, Cheal
Kim, Youngmee
Tetra-μ-benzoato-bis­[(3-methyl­quinoline)copper(II)](Cu—Cu)
title Tetra-μ-benzoato-bis­[(3-methyl­quinoline)copper(II)](Cu—Cu)
title_full Tetra-μ-benzoato-bis­[(3-methyl­quinoline)copper(II)](Cu—Cu)
title_fullStr Tetra-μ-benzoato-bis­[(3-methyl­quinoline)copper(II)](Cu—Cu)
title_full_unstemmed Tetra-μ-benzoato-bis­[(3-methyl­quinoline)copper(II)](Cu—Cu)
title_short Tetra-μ-benzoato-bis­[(3-methyl­quinoline)copper(II)](Cu—Cu)
title_sort tetra-μ-benzoato-bis­[(3-methyl­quinoline)copper(ii)](cu—cu)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960550/
https://www.ncbi.nlm.nih.gov/pubmed/21201597
http://dx.doi.org/10.1107/S1600536808024859
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