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(μ-Piperazine-1,4-dicarbodithioato-κ(4) S,S′:S′′,S′′′)bis­[triphenyl­tin(IV)] dichloro­methane solvate

The dinuclear centrosymmetric title compound, [Sn(2)(C(6)H(5))(6)(C(6)H(8)N(2)S(4))]·CH(2)Cl(2), features a distorted cis-trigonal–bipyramidal coordination geometry for Sn based on a C(3)S(2) donor set. The dinuclear mol­ecule lies across a centre of inversion. The solvent dichloro­methane mol­ecule...

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Detalles Bibliográficos
Autores principales: Poplaukhin, Pavel, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960554/
https://www.ncbi.nlm.nih.gov/pubmed/21201621
http://dx.doi.org/10.1107/S1600536808025890
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author Poplaukhin, Pavel
Tiekink, Edward R. T.
author_facet Poplaukhin, Pavel
Tiekink, Edward R. T.
author_sort Poplaukhin, Pavel
collection PubMed
description The dinuclear centrosymmetric title compound, [Sn(2)(C(6)H(5))(6)(C(6)H(8)N(2)S(4))]·CH(2)Cl(2), features a distorted cis-trigonal–bipyramidal coordination geometry for Sn based on a C(3)S(2) donor set. The dinuclear mol­ecule lies across a centre of inversion. The solvent dichloro­methane mol­ecule is disordered about a centre of inversion.
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spelling pubmed-29605542010-12-30 (μ-Piperazine-1,4-dicarbodithioato-κ(4) S,S′:S′′,S′′′)bis­[triphenyl­tin(IV)] dichloro­methane solvate Poplaukhin, Pavel Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The dinuclear centrosymmetric title compound, [Sn(2)(C(6)H(5))(6)(C(6)H(8)N(2)S(4))]·CH(2)Cl(2), features a distorted cis-trigonal–bipyramidal coordination geometry for Sn based on a C(3)S(2) donor set. The dinuclear mol­ecule lies across a centre of inversion. The solvent dichloro­methane mol­ecule is disordered about a centre of inversion. International Union of Crystallography 2008-08-16 /pmc/articles/PMC2960554/ /pubmed/21201621 http://dx.doi.org/10.1107/S1600536808025890 Text en © Poplaukhin and Tiekink 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Poplaukhin, Pavel
Tiekink, Edward R. T.
(μ-Piperazine-1,4-dicarbodithioato-κ(4) S,S′:S′′,S′′′)bis­[triphenyl­tin(IV)] dichloro­methane solvate
title (μ-Piperazine-1,4-dicarbodithioato-κ(4) S,S′:S′′,S′′′)bis­[triphenyl­tin(IV)] dichloro­methane solvate
title_full (μ-Piperazine-1,4-dicarbodithioato-κ(4) S,S′:S′′,S′′′)bis­[triphenyl­tin(IV)] dichloro­methane solvate
title_fullStr (μ-Piperazine-1,4-dicarbodithioato-κ(4) S,S′:S′′,S′′′)bis­[triphenyl­tin(IV)] dichloro­methane solvate
title_full_unstemmed (μ-Piperazine-1,4-dicarbodithioato-κ(4) S,S′:S′′,S′′′)bis­[triphenyl­tin(IV)] dichloro­methane solvate
title_short (μ-Piperazine-1,4-dicarbodithioato-κ(4) S,S′:S′′,S′′′)bis­[triphenyl­tin(IV)] dichloro­methane solvate
title_sort (μ-piperazine-1,4-dicarbodithioato-κ(4) s,s′:s′′,s′′′)bis­[triphenyl­tin(iv)] dichloro­methane solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960554/
https://www.ncbi.nlm.nih.gov/pubmed/21201621
http://dx.doi.org/10.1107/S1600536808025890
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