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(μ-Diphenylphosphanido-κ(2) P:P′)bis[2,2′-(pyridine-2,6-diyl)diphenyl-κ(3) C (1),N,C (1′))gold(III)] perchlorate acetonitrile solvate
The title complex, [Au(2)(C(17)H(11)N)(2)(C(12)H(10)P)]ClO(4)·C(2)H(3)N, contains two Au(III) atoms bridged by a diphenylphosphanide ligand. Each Au atom is in a square-planar environment coordinated by diphenylphosphanide and 2,6-diphenylpyridine ligands. There are weak π–π stacking interaction...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960555/ https://www.ncbi.nlm.nih.gov/pubmed/21201586 http://dx.doi.org/10.1107/S1600536808024537 |
| _version_ | 1782188768076234752 |
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| author | Li, Xin-Sheng Mo, Juan Zhang, Su-Mei Yuan, Li Liu, Jian-Hua |
| author_facet | Li, Xin-Sheng Mo, Juan Zhang, Su-Mei Yuan, Li Liu, Jian-Hua |
| author_sort | Li, Xin-Sheng |
| collection | PubMed |
| description | The title complex, [Au(2)(C(17)H(11)N)(2)(C(12)H(10)P)]ClO(4)·C(2)H(3)N, contains two Au(III) atoms bridged by a diphenylphosphanide ligand. Each Au atom is in a square-planar environment coordinated by diphenylphosphanide and 2,6-diphenylpyridine ligands. There are weak π–π stacking interactions between neighbouring molecules (the interplanar separations between two neighbouring dpp units are 3.40 and 3.57 Å). The intramolecular Au⋯Au separation is 3.788 (5) Å. The crystal structure shows weak intermolecular C—H⋯O and C—H⋯N hydrogen bonds involving an O atom of the perchlorate counter-ion and the N atom of the acetonitrile solvent molecule, respectively. |
| format | Text |
| id | pubmed-2960555 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29605552010-12-30 (μ-Diphenylphosphanido-κ(2) P:P′)bis[2,2′-(pyridine-2,6-diyl)diphenyl-κ(3) C (1),N,C (1′))gold(III)] perchlorate acetonitrile solvate Li, Xin-Sheng Mo, Juan Zhang, Su-Mei Yuan, Li Liu, Jian-Hua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Au(2)(C(17)H(11)N)(2)(C(12)H(10)P)]ClO(4)·C(2)H(3)N, contains two Au(III) atoms bridged by a diphenylphosphanide ligand. Each Au atom is in a square-planar environment coordinated by diphenylphosphanide and 2,6-diphenylpyridine ligands. There are weak π–π stacking interactions between neighbouring molecules (the interplanar separations between two neighbouring dpp units are 3.40 and 3.57 Å). The intramolecular Au⋯Au separation is 3.788 (5) Å. The crystal structure shows weak intermolecular C—H⋯O and C—H⋯N hydrogen bonds involving an O atom of the perchlorate counter-ion and the N atom of the acetonitrile solvent molecule, respectively. International Union of Crystallography 2008-08-06 /pmc/articles/PMC2960555/ /pubmed/21201586 http://dx.doi.org/10.1107/S1600536808024537 Text en © Li et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Li, Xin-Sheng Mo, Juan Zhang, Su-Mei Yuan, Li Liu, Jian-Hua (μ-Diphenylphosphanido-κ(2) P:P′)bis[2,2′-(pyridine-2,6-diyl)diphenyl-κ(3) C (1),N,C (1′))gold(III)] perchlorate acetonitrile solvate |
| title | (μ-Diphenylphosphanido-κ(2)
P:P′)bis[2,2′-(pyridine-2,6-diyl)diphenyl-κ(3)
C
(1),N,C
(1′))gold(III)] perchlorate acetonitrile solvate |
| title_full | (μ-Diphenylphosphanido-κ(2)
P:P′)bis[2,2′-(pyridine-2,6-diyl)diphenyl-κ(3)
C
(1),N,C
(1′))gold(III)] perchlorate acetonitrile solvate |
| title_fullStr | (μ-Diphenylphosphanido-κ(2)
P:P′)bis[2,2′-(pyridine-2,6-diyl)diphenyl-κ(3)
C
(1),N,C
(1′))gold(III)] perchlorate acetonitrile solvate |
| title_full_unstemmed | (μ-Diphenylphosphanido-κ(2)
P:P′)bis[2,2′-(pyridine-2,6-diyl)diphenyl-κ(3)
C
(1),N,C
(1′))gold(III)] perchlorate acetonitrile solvate |
| title_short | (μ-Diphenylphosphanido-κ(2)
P:P′)bis[2,2′-(pyridine-2,6-diyl)diphenyl-κ(3)
C
(1),N,C
(1′))gold(III)] perchlorate acetonitrile solvate |
| title_sort | (μ-diphenylphosphanido-κ(2)
p:p′)bis[2,2′-(pyridine-2,6-diyl)diphenyl-κ(3)
c
(1),n,c
(1′))gold(iii)] perchlorate acetonitrile solvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960555/ https://www.ncbi.nlm.nih.gov/pubmed/21201586 http://dx.doi.org/10.1107/S1600536808024537 |
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