(E,E)-2,2′-[1,1′-(Cyclohexane-1,2-diyl­dinitrilo)diethylidyne]diphenol

The title compound, C(22)H(26)N(2)O(2), is chiral; the absolute configuration follows from the known chirality of the input reagents. The asymmetric unit contains two crystallographically independent mol­ecules in different orientations. The two mol­ecules are related to each other by a non-crystall...

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Detalles Bibliográficos
Autores principales: Chen, Fang, Ye, Heng-Yun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960556/
https://www.ncbi.nlm.nih.gov/pubmed/21201739
http://dx.doi.org/10.1107/S160053680802552X
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author Chen, Fang
Ye, Heng-Yun
author_facet Chen, Fang
Ye, Heng-Yun
author_sort Chen, Fang
collection PubMed
description The title compound, C(22)H(26)N(2)O(2), is chiral; the absolute configuration follows from the known chirality of the input reagents. The asymmetric unit contains two crystallographically independent mol­ecules in different orientations. The two mol­ecules are related to each other by a non-crystallographic twofold rotation axis, while each mol­ecule exhibits a further pseudo-twofold axis. Bond distances and angles are similar in the two mol­ecules. Inter­molecular C—H⋯π(ring) inter­actions and intra­molecular O—H⋯N hydrogen bonds are observed in the crystal structure.
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spelling pubmed-29605562010-12-30 (E,E)-2,2′-[1,1′-(Cyclohexane-1,2-diyl­dinitrilo)diethylidyne]diphenol Chen, Fang Ye, Heng-Yun Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(22)H(26)N(2)O(2), is chiral; the absolute configuration follows from the known chirality of the input reagents. The asymmetric unit contains two crystallographically independent mol­ecules in different orientations. The two mol­ecules are related to each other by a non-crystallographic twofold rotation axis, while each mol­ecule exhibits a further pseudo-twofold axis. Bond distances and angles are similar in the two mol­ecules. Inter­molecular C—H⋯π(ring) inter­actions and intra­molecular O—H⋯N hydrogen bonds are observed in the crystal structure. International Union of Crystallography 2008-08-16 /pmc/articles/PMC2960556/ /pubmed/21201739 http://dx.doi.org/10.1107/S160053680802552X Text en © Chen and Ye 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Chen, Fang
Ye, Heng-Yun
(E,E)-2,2′-[1,1′-(Cyclohexane-1,2-diyl­dinitrilo)diethylidyne]diphenol
title (E,E)-2,2′-[1,1′-(Cyclohexane-1,2-diyl­dinitrilo)diethylidyne]diphenol
title_full (E,E)-2,2′-[1,1′-(Cyclohexane-1,2-diyl­dinitrilo)diethylidyne]diphenol
title_fullStr (E,E)-2,2′-[1,1′-(Cyclohexane-1,2-diyl­dinitrilo)diethylidyne]diphenol
title_full_unstemmed (E,E)-2,2′-[1,1′-(Cyclohexane-1,2-diyl­dinitrilo)diethylidyne]diphenol
title_short (E,E)-2,2′-[1,1′-(Cyclohexane-1,2-diyl­dinitrilo)diethylidyne]diphenol
title_sort (e,e)-2,2′-[1,1′-(cyclohexane-1,2-diyl­dinitrilo)diethylidyne]diphenol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960556/
https://www.ncbi.nlm.nih.gov/pubmed/21201739
http://dx.doi.org/10.1107/S160053680802552X
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AT yehengyun ee2211cyclohexane12diyldinitrilodiethylidynediphenol

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