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4,4′,5,5′-Tetramethyl-2,2′-[1,1′-(propane-1,3-diyldinitrilo)diethylidyne]diphenol
The title Schiff base compound, C(23)H(30)N(2)O(2), has crystallographic twofold rotation symmetry. An intramolecular O—H⋯N hydrogen bond forms a six-membered ring, producing an S(6) ring motif. The imino group is coplanar with the benzene ring. The two benzene rings are almost perpendicular to eac...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960569/ https://www.ncbi.nlm.nih.gov/pubmed/21201825 http://dx.doi.org/10.1107/S1600536808027220 |
Sumario: | The title Schiff base compound, C(23)H(30)N(2)O(2), has crystallographic twofold rotation symmetry. An intramolecular O—H⋯N hydrogen bond forms a six-membered ring, producing an S(6) ring motif. The imino group is coplanar with the benzene ring. The two benzene rings are almost perpendicular to each other, making a dihedral angle of 87.38 (4)°. In the crystal structure, neighbouring molecules are linked along the c axis by weak intermolecular C—H⋯O hydrogen bonds and are further packed into columns along the b axis, forming sheets which are parallel to the bc plane. |
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