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4,4′,5,5′-Tetra­methyl-2,2′-[1,1′-(propane-1,3-diyldinitrilo)diethyl­idyne]diphenol

The title Schiff base compound, C(23)H(30)N(2)O(2), has crystallographic twofold rotation symmetry. An intra­molecular O—H⋯N hydrogen bond forms a six-membered ring, producing an S(6) ring motif. The imino group is coplanar with the benzene ring. The two benzene rings are almost perpendicular to eac...

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Detalles Bibliográficos
Autores principales: Yeap, Chin Sing, Kia, Reza, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960569/
https://www.ncbi.nlm.nih.gov/pubmed/21201825
http://dx.doi.org/10.1107/S1600536808027220
Descripción
Sumario:The title Schiff base compound, C(23)H(30)N(2)O(2), has crystallographic twofold rotation symmetry. An intra­molecular O—H⋯N hydrogen bond forms a six-membered ring, producing an S(6) ring motif. The imino group is coplanar with the benzene ring. The two benzene rings are almost perpendicular to each other, making a dihedral angle of 87.38 (4)°. In the crystal structure, neighbouring mol­ecules are linked along the c axis by weak inter­molecular C—H⋯O hydrogen bonds and are further packed into columns along the b axis, forming sheets which are parallel to the bc plane.