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4,4′,5,5′-Tetra­methyl-2,2′-[1,1′-(propane-1,3-diyldinitrilo)diethyl­idyne]diphenol

The title Schiff base compound, C(23)H(30)N(2)O(2), has crystallographic twofold rotation symmetry. An intra­molecular O—H⋯N hydrogen bond forms a six-membered ring, producing an S(6) ring motif. The imino group is coplanar with the benzene ring. The two benzene rings are almost perpendicular to eac...

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Detalles Bibliográficos
Autores principales: Yeap, Chin Sing, Kia, Reza, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960569/
https://www.ncbi.nlm.nih.gov/pubmed/21201825
http://dx.doi.org/10.1107/S1600536808027220
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author Yeap, Chin Sing
Kia, Reza
Fun, Hoong-Kun
author_facet Yeap, Chin Sing
Kia, Reza
Fun, Hoong-Kun
author_sort Yeap, Chin Sing
collection PubMed
description The title Schiff base compound, C(23)H(30)N(2)O(2), has crystallographic twofold rotation symmetry. An intra­molecular O—H⋯N hydrogen bond forms a six-membered ring, producing an S(6) ring motif. The imino group is coplanar with the benzene ring. The two benzene rings are almost perpendicular to each other, making a dihedral angle of 87.38 (4)°. In the crystal structure, neighbouring mol­ecules are linked along the c axis by weak inter­molecular C—H⋯O hydrogen bonds and are further packed into columns along the b axis, forming sheets which are parallel to the bc plane.
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spelling pubmed-29605692010-12-30 4,4′,5,5′-Tetra­methyl-2,2′-[1,1′-(propane-1,3-diyldinitrilo)diethyl­idyne]diphenol Yeap, Chin Sing Kia, Reza Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers The title Schiff base compound, C(23)H(30)N(2)O(2), has crystallographic twofold rotation symmetry. An intra­molecular O—H⋯N hydrogen bond forms a six-membered ring, producing an S(6) ring motif. The imino group is coplanar with the benzene ring. The two benzene rings are almost perpendicular to each other, making a dihedral angle of 87.38 (4)°. In the crystal structure, neighbouring mol­ecules are linked along the c axis by weak inter­molecular C—H⋯O hydrogen bonds and are further packed into columns along the b axis, forming sheets which are parallel to the bc plane. International Union of Crystallography 2008-08-30 /pmc/articles/PMC2960569/ /pubmed/21201825 http://dx.doi.org/10.1107/S1600536808027220 Text en © Yeap et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Yeap, Chin Sing
Kia, Reza
Fun, Hoong-Kun
4,4′,5,5′-Tetra­methyl-2,2′-[1,1′-(propane-1,3-diyldinitrilo)diethyl­idyne]diphenol
title 4,4′,5,5′-Tetra­methyl-2,2′-[1,1′-(propane-1,3-diyldinitrilo)diethyl­idyne]diphenol
title_full 4,4′,5,5′-Tetra­methyl-2,2′-[1,1′-(propane-1,3-diyldinitrilo)diethyl­idyne]diphenol
title_fullStr 4,4′,5,5′-Tetra­methyl-2,2′-[1,1′-(propane-1,3-diyldinitrilo)diethyl­idyne]diphenol
title_full_unstemmed 4,4′,5,5′-Tetra­methyl-2,2′-[1,1′-(propane-1,3-diyldinitrilo)diethyl­idyne]diphenol
title_short 4,4′,5,5′-Tetra­methyl-2,2′-[1,1′-(propane-1,3-diyldinitrilo)diethyl­idyne]diphenol
title_sort 4,4′,5,5′-tetra­methyl-2,2′-[1,1′-(propane-1,3-diyldinitrilo)diethyl­idyne]diphenol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960569/
https://www.ncbi.nlm.nih.gov/pubmed/21201825
http://dx.doi.org/10.1107/S1600536808027220
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