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4,4′,5,5′-Tetramethyl-2,2′-[1,1′-(propane-1,3-diyldinitrilo)diethylidyne]diphenol
The title Schiff base compound, C(23)H(30)N(2)O(2), has crystallographic twofold rotation symmetry. An intramolecular O—H⋯N hydrogen bond forms a six-membered ring, producing an S(6) ring motif. The imino group is coplanar with the benzene ring. The two benzene rings are almost perpendicular to eac...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960569/ https://www.ncbi.nlm.nih.gov/pubmed/21201825 http://dx.doi.org/10.1107/S1600536808027220 |
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author | Yeap, Chin Sing Kia, Reza Fun, Hoong-Kun |
author_facet | Yeap, Chin Sing Kia, Reza Fun, Hoong-Kun |
author_sort | Yeap, Chin Sing |
collection | PubMed |
description | The title Schiff base compound, C(23)H(30)N(2)O(2), has crystallographic twofold rotation symmetry. An intramolecular O—H⋯N hydrogen bond forms a six-membered ring, producing an S(6) ring motif. The imino group is coplanar with the benzene ring. The two benzene rings are almost perpendicular to each other, making a dihedral angle of 87.38 (4)°. In the crystal structure, neighbouring molecules are linked along the c axis by weak intermolecular C—H⋯O hydrogen bonds and are further packed into columns along the b axis, forming sheets which are parallel to the bc plane. |
format | Text |
id | pubmed-2960569 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29605692010-12-30 4,4′,5,5′-Tetramethyl-2,2′-[1,1′-(propane-1,3-diyldinitrilo)diethylidyne]diphenol Yeap, Chin Sing Kia, Reza Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers The title Schiff base compound, C(23)H(30)N(2)O(2), has crystallographic twofold rotation symmetry. An intramolecular O—H⋯N hydrogen bond forms a six-membered ring, producing an S(6) ring motif. The imino group is coplanar with the benzene ring. The two benzene rings are almost perpendicular to each other, making a dihedral angle of 87.38 (4)°. In the crystal structure, neighbouring molecules are linked along the c axis by weak intermolecular C—H⋯O hydrogen bonds and are further packed into columns along the b axis, forming sheets which are parallel to the bc plane. International Union of Crystallography 2008-08-30 /pmc/articles/PMC2960569/ /pubmed/21201825 http://dx.doi.org/10.1107/S1600536808027220 Text en © Yeap et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Yeap, Chin Sing Kia, Reza Fun, Hoong-Kun 4,4′,5,5′-Tetramethyl-2,2′-[1,1′-(propane-1,3-diyldinitrilo)diethylidyne]diphenol |
title | 4,4′,5,5′-Tetramethyl-2,2′-[1,1′-(propane-1,3-diyldinitrilo)diethylidyne]diphenol |
title_full | 4,4′,5,5′-Tetramethyl-2,2′-[1,1′-(propane-1,3-diyldinitrilo)diethylidyne]diphenol |
title_fullStr | 4,4′,5,5′-Tetramethyl-2,2′-[1,1′-(propane-1,3-diyldinitrilo)diethylidyne]diphenol |
title_full_unstemmed | 4,4′,5,5′-Tetramethyl-2,2′-[1,1′-(propane-1,3-diyldinitrilo)diethylidyne]diphenol |
title_short | 4,4′,5,5′-Tetramethyl-2,2′-[1,1′-(propane-1,3-diyldinitrilo)diethylidyne]diphenol |
title_sort | 4,4′,5,5′-tetramethyl-2,2′-[1,1′-(propane-1,3-diyldinitrilo)diethylidyne]diphenol |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960569/ https://www.ncbi.nlm.nih.gov/pubmed/21201825 http://dx.doi.org/10.1107/S1600536808027220 |
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