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4-Methoxy-2-[(E)-(phenylimino)methyl]phenol
In the molecule of the title compound, C(14)H(13)NO(2), the two aromatic rings are oriented at a dihedral angle of 0.78 (20)°; with the exception of two methyl H atoms the molecule is essentially planar. The intramolecular O—H⋯N hydrogen bond results in the formation of a non-planar, six-membered...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960573/ https://www.ncbi.nlm.nih.gov/pubmed/21201794 http://dx.doi.org/10.1107/S1600536808026883 |
Sumario: | In the molecule of the title compound, C(14)H(13)NO(2), the two aromatic rings are oriented at a dihedral angle of 0.78 (20)°; with the exception of two methyl H atoms the molecule is essentially planar. The intramolecular O—H⋯N hydrogen bond results in the formation of a non-planar, six-membered ring, which adopts a flattened-boat conformation. In the crystal structure, intermolecular C—H⋯O hydrogen bonds link the molecules to form parallel networks. There is a C—H⋯π contact between the methyl group and the benzene ring. A π–π contact between the benzene and phenyl rings [centroid–centroid distance = 4.681 (5) Å] is also observed. |
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