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4-Meth­oxy-2-[(E)-(phenyl­imino)meth­yl]phenol

In the mol­ecule of the title compound, C(14)H(13)NO(2), the two aromatic rings are oriented at a dihedral angle of 0.78 (20)°; with the exception of two methyl H atoms the mol­ecule is essentially planar. The intra­molecular O—H⋯N hydrogen bond results in the formation of a non-planar, six-membered...

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Detalles Bibliográficos
Autores principales: Uçan, Selma, Öztürk, Aslı, Sarıkavaklı, Nursabah, Hökelek, Tuncer
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960573/
https://www.ncbi.nlm.nih.gov/pubmed/21201794
http://dx.doi.org/10.1107/S1600536808026883
Descripción
Sumario:In the mol­ecule of the title compound, C(14)H(13)NO(2), the two aromatic rings are oriented at a dihedral angle of 0.78 (20)°; with the exception of two methyl H atoms the mol­ecule is essentially planar. The intra­molecular O—H⋯N hydrogen bond results in the formation of a non-planar, six-membered ring, which adopts a flattened-boat conformation. In the crystal structure, inter­molecular C—H⋯O hydrogen bonds link the mol­ecules to form parallel networks. There is a C—H⋯π contact between the methyl group and the benzene ring. A π–π contact between the benzene and phenyl rings [centroid–centroid distance = 4.681 (5) Å] is also observed.