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4-Methoxy-2-[(E)-(phenylimino)methyl]phenol
In the molecule of the title compound, C(14)H(13)NO(2), the two aromatic rings are oriented at a dihedral angle of 0.78 (20)°; with the exception of two methyl H atoms the molecule is essentially planar. The intramolecular O—H⋯N hydrogen bond results in the formation of a non-planar, six-membered...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960573/ https://www.ncbi.nlm.nih.gov/pubmed/21201794 http://dx.doi.org/10.1107/S1600536808026883 |
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author | Uçan, Selma Öztürk, Aslı Sarıkavaklı, Nursabah Hökelek, Tuncer |
author_facet | Uçan, Selma Öztürk, Aslı Sarıkavaklı, Nursabah Hökelek, Tuncer |
author_sort | Uçan, Selma |
collection | PubMed |
description | In the molecule of the title compound, C(14)H(13)NO(2), the two aromatic rings are oriented at a dihedral angle of 0.78 (20)°; with the exception of two methyl H atoms the molecule is essentially planar. The intramolecular O—H⋯N hydrogen bond results in the formation of a non-planar, six-membered ring, which adopts a flattened-boat conformation. In the crystal structure, intermolecular C—H⋯O hydrogen bonds link the molecules to form parallel networks. There is a C—H⋯π contact between the methyl group and the benzene ring. A π–π contact between the benzene and phenyl rings [centroid–centroid distance = 4.681 (5) Å] is also observed. |
format | Text |
id | pubmed-2960573 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29605732010-12-30 4-Methoxy-2-[(E)-(phenylimino)methyl]phenol Uçan, Selma Öztürk, Aslı Sarıkavaklı, Nursabah Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Organic Papers In the molecule of the title compound, C(14)H(13)NO(2), the two aromatic rings are oriented at a dihedral angle of 0.78 (20)°; with the exception of two methyl H atoms the molecule is essentially planar. The intramolecular O—H⋯N hydrogen bond results in the formation of a non-planar, six-membered ring, which adopts a flattened-boat conformation. In the crystal structure, intermolecular C—H⋯O hydrogen bonds link the molecules to form parallel networks. There is a C—H⋯π contact between the methyl group and the benzene ring. A π–π contact between the benzene and phenyl rings [centroid–centroid distance = 4.681 (5) Å] is also observed. International Union of Crystallography 2008-08-23 /pmc/articles/PMC2960573/ /pubmed/21201794 http://dx.doi.org/10.1107/S1600536808026883 Text en © Uçan et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Uçan, Selma Öztürk, Aslı Sarıkavaklı, Nursabah Hökelek, Tuncer 4-Methoxy-2-[(E)-(phenylimino)methyl]phenol |
title | 4-Methoxy-2-[(E)-(phenylimino)methyl]phenol |
title_full | 4-Methoxy-2-[(E)-(phenylimino)methyl]phenol |
title_fullStr | 4-Methoxy-2-[(E)-(phenylimino)methyl]phenol |
title_full_unstemmed | 4-Methoxy-2-[(E)-(phenylimino)methyl]phenol |
title_short | 4-Methoxy-2-[(E)-(phenylimino)methyl]phenol |
title_sort | 4-methoxy-2-[(e)-(phenylimino)methyl]phenol |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960573/ https://www.ncbi.nlm.nih.gov/pubmed/21201794 http://dx.doi.org/10.1107/S1600536808026883 |
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