Cargando…

4-Meth­oxy-2-[(E)-(phenyl­imino)meth­yl]phenol

In the mol­ecule of the title compound, C(14)H(13)NO(2), the two aromatic rings are oriented at a dihedral angle of 0.78 (20)°; with the exception of two methyl H atoms the mol­ecule is essentially planar. The intra­molecular O—H⋯N hydrogen bond results in the formation of a non-planar, six-membered...

Descripción completa

Detalles Bibliográficos
Autores principales: Uçan, Selma, Öztürk, Aslı, Sarıkavaklı, Nursabah, Hökelek, Tuncer
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960573/
https://www.ncbi.nlm.nih.gov/pubmed/21201794
http://dx.doi.org/10.1107/S1600536808026883
_version_ 1782188772387979264
author Uçan, Selma
Öztürk, Aslı
Sarıkavaklı, Nursabah
Hökelek, Tuncer
author_facet Uçan, Selma
Öztürk, Aslı
Sarıkavaklı, Nursabah
Hökelek, Tuncer
author_sort Uçan, Selma
collection PubMed
description In the mol­ecule of the title compound, C(14)H(13)NO(2), the two aromatic rings are oriented at a dihedral angle of 0.78 (20)°; with the exception of two methyl H atoms the mol­ecule is essentially planar. The intra­molecular O—H⋯N hydrogen bond results in the formation of a non-planar, six-membered ring, which adopts a flattened-boat conformation. In the crystal structure, inter­molecular C—H⋯O hydrogen bonds link the mol­ecules to form parallel networks. There is a C—H⋯π contact between the methyl group and the benzene ring. A π–π contact between the benzene and phenyl rings [centroid–centroid distance = 4.681 (5) Å] is also observed.
format Text
id pubmed-2960573
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29605732010-12-30 4-Meth­oxy-2-[(E)-(phenyl­imino)meth­yl]phenol Uçan, Selma Öztürk, Aslı Sarıkavaklı, Nursabah Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Organic Papers In the mol­ecule of the title compound, C(14)H(13)NO(2), the two aromatic rings are oriented at a dihedral angle of 0.78 (20)°; with the exception of two methyl H atoms the mol­ecule is essentially planar. The intra­molecular O—H⋯N hydrogen bond results in the formation of a non-planar, six-membered ring, which adopts a flattened-boat conformation. In the crystal structure, inter­molecular C—H⋯O hydrogen bonds link the mol­ecules to form parallel networks. There is a C—H⋯π contact between the methyl group and the benzene ring. A π–π contact between the benzene and phenyl rings [centroid–centroid distance = 4.681 (5) Å] is also observed. International Union of Crystallography 2008-08-23 /pmc/articles/PMC2960573/ /pubmed/21201794 http://dx.doi.org/10.1107/S1600536808026883 Text en © Uçan et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Uçan, Selma
Öztürk, Aslı
Sarıkavaklı, Nursabah
Hökelek, Tuncer
4-Meth­oxy-2-[(E)-(phenyl­imino)meth­yl]phenol
title 4-Meth­oxy-2-[(E)-(phenyl­imino)meth­yl]phenol
title_full 4-Meth­oxy-2-[(E)-(phenyl­imino)meth­yl]phenol
title_fullStr 4-Meth­oxy-2-[(E)-(phenyl­imino)meth­yl]phenol
title_full_unstemmed 4-Meth­oxy-2-[(E)-(phenyl­imino)meth­yl]phenol
title_short 4-Meth­oxy-2-[(E)-(phenyl­imino)meth­yl]phenol
title_sort 4-meth­oxy-2-[(e)-(phenyl­imino)meth­yl]phenol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960573/
https://www.ncbi.nlm.nih.gov/pubmed/21201794
http://dx.doi.org/10.1107/S1600536808026883
work_keys_str_mv AT ucanselma 4methoxy2ephenyliminomethylphenol
AT ozturkaslı 4methoxy2ephenyliminomethylphenol
AT sarıkavaklınursabah 4methoxy2ephenyliminomethylphenol
AT hokelektuncer 4methoxy2ephenyliminomethylphenol