Bis{μ-5-(diethyl­amino)-2-[(2-oxidoeth­oxy)imino­meth­yl]phenolato}dicopper(II) acetone solvate

The title complex, [Cu(2)(C(13)H(18)N(2)O(3))(2)]·C(3)H(6)O, has been synthesized by the reaction of copper(II) acetate monohydrate with 5,5′-bis­(diethyl­amino)-2,2′-[ethyl­enedioxy­bis(nitrilo­methyl­idyne)]diphenol, where one of the N—O bonds of the ligand was cleaved during the reaction. The com...

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Detalles Bibliográficos
Autores principales: Dong, Wen-Kui, Chen, Xiao, He, Xue-Ni, Tang, Xiao-Lu, Lv, Zhong-Wu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960577/
https://www.ncbi.nlm.nih.gov/pubmed/21201591
http://dx.doi.org/10.1107/S1600536808024707
Descripción
Sumario:The title complex, [Cu(2)(C(13)H(18)N(2)O(3))(2)]·C(3)H(6)O, has been synthesized by the reaction of copper(II) acetate monohydrate with 5,5′-bis­(diethyl­amino)-2,2′-[ethyl­enedioxy­bis(nitrilo­methyl­idyne)]diphenol, where one of the N—O bonds of the ligand was cleaved during the reaction. The complex mol­ecule has a μ-dialkoxo-bridged binuclear structure with both Cu(II) centers exhibiting a square-planar coordination geometry.

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