Bis{μ-5-(diethyl­amino)-2-[(2-oxidoeth­oxy)imino­meth­yl]phenolato}dicopper(II) acetone solvate

The title complex, [Cu(2)(C(13)H(18)N(2)O(3))(2)]·C(3)H(6)O, has been synthesized by the reaction of copper(II) acetate monohydrate with 5,5′-bis­(diethyl­amino)-2,2′-[ethyl­enedioxy­bis(nitrilo­methyl­idyne)]diphenol, where one of the N—O bonds of the ligand was cleaved during the reaction. The com...

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Detalles Bibliográficos
Autores principales: Dong, Wen-Kui, Chen, Xiao, He, Xue-Ni, Tang, Xiao-Lu, Lv, Zhong-Wu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960577/
https://www.ncbi.nlm.nih.gov/pubmed/21201591
http://dx.doi.org/10.1107/S1600536808024707
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author Dong, Wen-Kui
Chen, Xiao
He, Xue-Ni
Tang, Xiao-Lu
Lv, Zhong-Wu
author_facet Dong, Wen-Kui
Chen, Xiao
He, Xue-Ni
Tang, Xiao-Lu
Lv, Zhong-Wu
author_sort Dong, Wen-Kui
collection PubMed
description The title complex, [Cu(2)(C(13)H(18)N(2)O(3))(2)]·C(3)H(6)O, has been synthesized by the reaction of copper(II) acetate monohydrate with 5,5′-bis­(diethyl­amino)-2,2′-[ethyl­enedioxy­bis(nitrilo­methyl­idyne)]diphenol, where one of the N—O bonds of the ligand was cleaved during the reaction. The complex mol­ecule has a μ-dialkoxo-bridged binuclear structure with both Cu(II) centers exhibiting a square-planar coordination geometry.
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spelling pubmed-29605772010-12-30 Bis{μ-5-(diethyl­amino)-2-[(2-oxidoeth­oxy)imino­meth­yl]phenolato}dicopper(II) acetone solvate Dong, Wen-Kui Chen, Xiao He, Xue-Ni Tang, Xiao-Lu Lv, Zhong-Wu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Cu(2)(C(13)H(18)N(2)O(3))(2)]·C(3)H(6)O, has been synthesized by the reaction of copper(II) acetate monohydrate with 5,5′-bis­(diethyl­amino)-2,2′-[ethyl­enedioxy­bis(nitrilo­methyl­idyne)]diphenol, where one of the N—O bonds of the ligand was cleaved during the reaction. The complex mol­ecule has a μ-dialkoxo-bridged binuclear structure with both Cu(II) centers exhibiting a square-planar coordination geometry. International Union of Crystallography 2008-08-06 /pmc/articles/PMC2960577/ /pubmed/21201591 http://dx.doi.org/10.1107/S1600536808024707 Text en © Dong et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Dong, Wen-Kui
Chen, Xiao
He, Xue-Ni
Tang, Xiao-Lu
Lv, Zhong-Wu
Bis{μ-5-(diethyl­amino)-2-[(2-oxidoeth­oxy)imino­meth­yl]phenolato}dicopper(II) acetone solvate
title Bis{μ-5-(diethyl­amino)-2-[(2-oxidoeth­oxy)imino­meth­yl]phenolato}dicopper(II) acetone solvate
title_full Bis{μ-5-(diethyl­amino)-2-[(2-oxidoeth­oxy)imino­meth­yl]phenolato}dicopper(II) acetone solvate
title_fullStr Bis{μ-5-(diethyl­amino)-2-[(2-oxidoeth­oxy)imino­meth­yl]phenolato}dicopper(II) acetone solvate
title_full_unstemmed Bis{μ-5-(diethyl­amino)-2-[(2-oxidoeth­oxy)imino­meth­yl]phenolato}dicopper(II) acetone solvate
title_short Bis{μ-5-(diethyl­amino)-2-[(2-oxidoeth­oxy)imino­meth­yl]phenolato}dicopper(II) acetone solvate
title_sort bis{μ-5-(diethyl­amino)-2-[(2-oxidoeth­oxy)imino­meth­yl]phenolato}dicopper(ii) acetone solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960577/
https://www.ncbi.nlm.nih.gov/pubmed/21201591
http://dx.doi.org/10.1107/S1600536808024707
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