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3-Methylsulfinyl-2-phenyl-1-benzofuran
The title compound, C(15)H(12)O(2)S, was prepared by the oxidation of 3-methylsulfanyl-2-phenyl-1-benzofuran with 3-chloroperoxybenzoic acid. The phenyl ring makes a dihedral angle of 37.65 (8)° with the plane of the benzofuran fragment. The O atom and the methyl group of the methylsulfinyl subs...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960582/ https://www.ncbi.nlm.nih.gov/pubmed/21201676 http://dx.doi.org/10.1107/S1600536808024276 |
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author | Choi, Hong Dae Seo, Pil Ja Son, Byeng Wha Lee, Uk |
author_facet | Choi, Hong Dae Seo, Pil Ja Son, Byeng Wha Lee, Uk |
author_sort | Choi, Hong Dae |
collection | PubMed |
description | The title compound, C(15)H(12)O(2)S, was prepared by the oxidation of 3-methylsulfanyl-2-phenyl-1-benzofuran with 3-chloroperoxybenzoic acid. The phenyl ring makes a dihedral angle of 37.65 (8)° with the plane of the benzofuran fragment. The O atom and the methyl group of the methylsulfinyl substituent lie on opposite sides of the plane of the benzofuran ring system. The crystal structure is stabilized by aromatic π–π interactions between the benzene rings of neighbouring molecules [centroid–centroid distance = 3.549 (2) Å] and by intermolecular C—H⋯O interactions. |
format | Text |
id | pubmed-2960582 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29605822010-12-30 3-Methylsulfinyl-2-phenyl-1-benzofuran Choi, Hong Dae Seo, Pil Ja Son, Byeng Wha Lee, Uk Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(12)O(2)S, was prepared by the oxidation of 3-methylsulfanyl-2-phenyl-1-benzofuran with 3-chloroperoxybenzoic acid. The phenyl ring makes a dihedral angle of 37.65 (8)° with the plane of the benzofuran fragment. The O atom and the methyl group of the methylsulfinyl substituent lie on opposite sides of the plane of the benzofuran ring system. The crystal structure is stabilized by aromatic π–π interactions between the benzene rings of neighbouring molecules [centroid–centroid distance = 3.549 (2) Å] and by intermolecular C—H⋯O interactions. International Union of Crystallography 2008-08-06 /pmc/articles/PMC2960582/ /pubmed/21201676 http://dx.doi.org/10.1107/S1600536808024276 Text en © Choi et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Choi, Hong Dae Seo, Pil Ja Son, Byeng Wha Lee, Uk 3-Methylsulfinyl-2-phenyl-1-benzofuran |
title | 3-Methylsulfinyl-2-phenyl-1-benzofuran |
title_full | 3-Methylsulfinyl-2-phenyl-1-benzofuran |
title_fullStr | 3-Methylsulfinyl-2-phenyl-1-benzofuran |
title_full_unstemmed | 3-Methylsulfinyl-2-phenyl-1-benzofuran |
title_short | 3-Methylsulfinyl-2-phenyl-1-benzofuran |
title_sort | 3-methylsulfinyl-2-phenyl-1-benzofuran |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960582/ https://www.ncbi.nlm.nih.gov/pubmed/21201676 http://dx.doi.org/10.1107/S1600536808024276 |
work_keys_str_mv | AT choihongdae 3methylsulfinyl2phenyl1benzofuran AT seopilja 3methylsulfinyl2phenyl1benzofuran AT sonbyengwha 3methylsulfinyl2phenyl1benzofuran AT leeuk 3methylsulfinyl2phenyl1benzofuran |