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2,2′-[1,1′-(Hexane-1,6-diyldioxydinitrilo)diethylidyne]diphenol
The molecule of the title compound, C(22)H(28)N(2)O(2), lies across an inversion centre with one half-molecule in the asymmetric unit. The molecule adopts an E configuration with respect to the azomethine C=N bond and the imino group is coplanar with the aromatic ring. Within the molecule, the pl...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960586/ https://www.ncbi.nlm.nih.gov/pubmed/21201709 http://dx.doi.org/10.1107/S1600536808024902 |
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author | Dong, Wen-Kui He, Xue-Ni Sun, Yin-Xia Xu, Li Tong, Jun-Feng |
author_facet | Dong, Wen-Kui He, Xue-Ni Sun, Yin-Xia Xu, Li Tong, Jun-Feng |
author_sort | Dong, Wen-Kui |
collection | PubMed |
description | The molecule of the title compound, C(22)H(28)N(2)O(2), lies across an inversion centre with one half-molecule in the asymmetric unit. The molecule adopts an E configuration with respect to the azomethine C=N bond and the imino group is coplanar with the aromatic ring. Within the molecule, the planar units are parallel, but extend in opposite directions from the hexamethylene bridge. There are intramolecular O—H⋯N hydrogen bonds between the hydroxyl groups and the oxime N atoms. There are also weak intermolecular C—H⋯O bonds that link each molecule to two others, forming chains along the a axis. |
format | Text |
id | pubmed-2960586 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29605862010-12-30 2,2′-[1,1′-(Hexane-1,6-diyldioxydinitrilo)diethylidyne]diphenol Dong, Wen-Kui He, Xue-Ni Sun, Yin-Xia Xu, Li Tong, Jun-Feng Acta Crystallogr Sect E Struct Rep Online Organic Papers The molecule of the title compound, C(22)H(28)N(2)O(2), lies across an inversion centre with one half-molecule in the asymmetric unit. The molecule adopts an E configuration with respect to the azomethine C=N bond and the imino group is coplanar with the aromatic ring. Within the molecule, the planar units are parallel, but extend in opposite directions from the hexamethylene bridge. There are intramolecular O—H⋯N hydrogen bonds between the hydroxyl groups and the oxime N atoms. There are also weak intermolecular C—H⋯O bonds that link each molecule to two others, forming chains along the a axis. International Union of Crystallography 2008-08-09 /pmc/articles/PMC2960586/ /pubmed/21201709 http://dx.doi.org/10.1107/S1600536808024902 Text en © Dong et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Dong, Wen-Kui He, Xue-Ni Sun, Yin-Xia Xu, Li Tong, Jun-Feng 2,2′-[1,1′-(Hexane-1,6-diyldioxydinitrilo)diethylidyne]diphenol |
title | 2,2′-[1,1′-(Hexane-1,6-diyldioxydinitrilo)diethylidyne]diphenol |
title_full | 2,2′-[1,1′-(Hexane-1,6-diyldioxydinitrilo)diethylidyne]diphenol |
title_fullStr | 2,2′-[1,1′-(Hexane-1,6-diyldioxydinitrilo)diethylidyne]diphenol |
title_full_unstemmed | 2,2′-[1,1′-(Hexane-1,6-diyldioxydinitrilo)diethylidyne]diphenol |
title_short | 2,2′-[1,1′-(Hexane-1,6-diyldioxydinitrilo)diethylidyne]diphenol |
title_sort | 2,2′-[1,1′-(hexane-1,6-diyldioxydinitrilo)diethylidyne]diphenol |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960586/ https://www.ncbi.nlm.nih.gov/pubmed/21201709 http://dx.doi.org/10.1107/S1600536808024902 |
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