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2,2′-[1,1′-(Hexane-1,6-diyldioxy­dinitrilo)diethyl­idyne]diphenol

The molecule of the title compound, C(22)H(28)N(2)O(2), lies across an inversion centre with one half-mol­ecule in the asymmetric unit. The mol­ecule adopts an E configuration with respect to the azomethine C=N bond and the imino group is coplanar with the aromatic ring. Within the mol­ecule, the pl...

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Detalles Bibliográficos
Autores principales: Dong, Wen-Kui, He, Xue-Ni, Sun, Yin-Xia, Xu, Li, Tong, Jun-Feng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960586/
https://www.ncbi.nlm.nih.gov/pubmed/21201709
http://dx.doi.org/10.1107/S1600536808024902
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author Dong, Wen-Kui
He, Xue-Ni
Sun, Yin-Xia
Xu, Li
Tong, Jun-Feng
author_facet Dong, Wen-Kui
He, Xue-Ni
Sun, Yin-Xia
Xu, Li
Tong, Jun-Feng
author_sort Dong, Wen-Kui
collection PubMed
description The molecule of the title compound, C(22)H(28)N(2)O(2), lies across an inversion centre with one half-mol­ecule in the asymmetric unit. The mol­ecule adopts an E configuration with respect to the azomethine C=N bond and the imino group is coplanar with the aromatic ring. Within the mol­ecule, the planar units are parallel, but extend in opposite directions from the hexa­methyl­ene bridge. There are intra­molecular O—H⋯N hydrogen bonds between the hydroxyl groups and the oxime N atoms. There are also weak inter­molecular C—H⋯O bonds that link each mol­ecule to two others, forming chains along the a axis.
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spelling pubmed-29605862010-12-30 2,2′-[1,1′-(Hexane-1,6-diyldioxy­dinitrilo)diethyl­idyne]diphenol Dong, Wen-Kui He, Xue-Ni Sun, Yin-Xia Xu, Li Tong, Jun-Feng Acta Crystallogr Sect E Struct Rep Online Organic Papers The molecule of the title compound, C(22)H(28)N(2)O(2), lies across an inversion centre with one half-mol­ecule in the asymmetric unit. The mol­ecule adopts an E configuration with respect to the azomethine C=N bond and the imino group is coplanar with the aromatic ring. Within the mol­ecule, the planar units are parallel, but extend in opposite directions from the hexa­methyl­ene bridge. There are intra­molecular O—H⋯N hydrogen bonds between the hydroxyl groups and the oxime N atoms. There are also weak inter­molecular C—H⋯O bonds that link each mol­ecule to two others, forming chains along the a axis. International Union of Crystallography 2008-08-09 /pmc/articles/PMC2960586/ /pubmed/21201709 http://dx.doi.org/10.1107/S1600536808024902 Text en © Dong et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Dong, Wen-Kui
He, Xue-Ni
Sun, Yin-Xia
Xu, Li
Tong, Jun-Feng
2,2′-[1,1′-(Hexane-1,6-diyldioxy­dinitrilo)diethyl­idyne]diphenol
title 2,2′-[1,1′-(Hexane-1,6-diyldioxy­dinitrilo)diethyl­idyne]diphenol
title_full 2,2′-[1,1′-(Hexane-1,6-diyldioxy­dinitrilo)diethyl­idyne]diphenol
title_fullStr 2,2′-[1,1′-(Hexane-1,6-diyldioxy­dinitrilo)diethyl­idyne]diphenol
title_full_unstemmed 2,2′-[1,1′-(Hexane-1,6-diyldioxy­dinitrilo)diethyl­idyne]diphenol
title_short 2,2′-[1,1′-(Hexane-1,6-diyldioxy­dinitrilo)diethyl­idyne]diphenol
title_sort 2,2′-[1,1′-(hexane-1,6-diyldioxy­dinitrilo)diethyl­idyne]diphenol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960586/
https://www.ncbi.nlm.nih.gov/pubmed/21201709
http://dx.doi.org/10.1107/S1600536808024902
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