Diaqua­bis(8-chloro-1,3-dimethyl-2,6-dioxo-1,2,3,6-tetra­hydro-7H-purinato-κN (7))copper(II) dihydrate

The title mononuclear copper(II) complex, [Cu(C(7)H(6)ClN(4)O(2))(2)(H(2)O)(2)]·2H(2)O, based on 8-chloro­theophylline (HCt), has the Cu atom at a center of symmetry in a slightly distorted trans square-planar geometry coordinated by two N atoms of two deprotonated HCt ligands and two O atoms of wat...

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Autores principales: Deng, Ji-Hua, Xiong, Zhi-Xing, Yi, Yan-Ping, Yuan, Lin, Guo, Hui-Rui, Guo, Meng-Ping, Liu, Lin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960592/
https://www.ncbi.nlm.nih.gov/pubmed/21201609
http://dx.doi.org/10.1107/S160053680802549X
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author Deng, Ji-Hua
Xiong, Zhi-Xing
Yi, Yan-Ping
Yuan, Lin
Guo, Hui-Rui
Guo, Meng-Ping
Liu, Lin
author_facet Deng, Ji-Hua
Xiong, Zhi-Xing
Yi, Yan-Ping
Yuan, Lin
Guo, Hui-Rui
Guo, Meng-Ping
Liu, Lin
author_sort Deng, Ji-Hua
collection PubMed
description The title mononuclear copper(II) complex, [Cu(C(7)H(6)ClN(4)O(2))(2)(H(2)O)(2)]·2H(2)O, based on 8-chloro­theophylline (HCt), has the Cu atom at a center of symmetry in a slightly distorted trans square-planar geometry coordinated by two N atoms of two deprotonated HCt ligands and two O atoms of water mol­ecules. The crystal packing is stabilized by hydrogen bonds involving deprotonated HCt ligands, coordinated water mol­ecules and uncoordinated solvent water mol­ecules.
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spelling pubmed-29605922010-12-30 Diaqua­bis(8-chloro-1,3-dimethyl-2,6-dioxo-1,2,3,6-tetra­hydro-7H-purinato-κN (7))copper(II) dihydrate Deng, Ji-Hua Xiong, Zhi-Xing Yi, Yan-Ping Yuan, Lin Guo, Hui-Rui Guo, Meng-Ping Liu, Lin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title mononuclear copper(II) complex, [Cu(C(7)H(6)ClN(4)O(2))(2)(H(2)O)(2)]·2H(2)O, based on 8-chloro­theophylline (HCt), has the Cu atom at a center of symmetry in a slightly distorted trans square-planar geometry coordinated by two N atoms of two deprotonated HCt ligands and two O atoms of water mol­ecules. The crystal packing is stabilized by hydrogen bonds involving deprotonated HCt ligands, coordinated water mol­ecules and uncoordinated solvent water mol­ecules. International Union of Crystallography 2008-08-13 /pmc/articles/PMC2960592/ /pubmed/21201609 http://dx.doi.org/10.1107/S160053680802549X Text en © Deng et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Deng, Ji-Hua
Xiong, Zhi-Xing
Yi, Yan-Ping
Yuan, Lin
Guo, Hui-Rui
Guo, Meng-Ping
Liu, Lin
Diaqua­bis(8-chloro-1,3-dimethyl-2,6-dioxo-1,2,3,6-tetra­hydro-7H-purinato-κN (7))copper(II) dihydrate
title Diaqua­bis(8-chloro-1,3-dimethyl-2,6-dioxo-1,2,3,6-tetra­hydro-7H-purinato-κN (7))copper(II) dihydrate
title_full Diaqua­bis(8-chloro-1,3-dimethyl-2,6-dioxo-1,2,3,6-tetra­hydro-7H-purinato-κN (7))copper(II) dihydrate
title_fullStr Diaqua­bis(8-chloro-1,3-dimethyl-2,6-dioxo-1,2,3,6-tetra­hydro-7H-purinato-κN (7))copper(II) dihydrate
title_full_unstemmed Diaqua­bis(8-chloro-1,3-dimethyl-2,6-dioxo-1,2,3,6-tetra­hydro-7H-purinato-κN (7))copper(II) dihydrate
title_short Diaqua­bis(8-chloro-1,3-dimethyl-2,6-dioxo-1,2,3,6-tetra­hydro-7H-purinato-κN (7))copper(II) dihydrate
title_sort diaqua­bis(8-chloro-1,3-dimethyl-2,6-dioxo-1,2,3,6-tetra­hydro-7h-purinato-κn (7))copper(ii) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960592/
https://www.ncbi.nlm.nih.gov/pubmed/21201609
http://dx.doi.org/10.1107/S160053680802549X
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