(E)-1-Ferrocenyl-3-(4-methoxy­phen­yl)­prop-2-en-1-one

In the title compound, [Fe(C(5)H(5))(C(15)H(13)O(2))], a conjugated substituent group bridges a five-membered η(5)-C(5)H(4) ring and a benzene ring. In the ferrocene unit, the substituted (Cps) and unsubstituted (Cp) cyclo­penta­dienyl rings are eclipsed and almost parallel [Cps—Fe—Cps angle = 176.1...

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Detalles Bibliográficos
Autores principales: Long, Shi-Jia, Liu, Xiao-Lan, Liu, Yong-Hong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960594/
https://www.ncbi.nlm.nih.gov/pubmed/21201612
http://dx.doi.org/10.1107/S1600536808025518
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author Long, Shi-Jia
Liu, Xiao-Lan
Liu, Yong-Hong
author_facet Long, Shi-Jia
Liu, Xiao-Lan
Liu, Yong-Hong
author_sort Long, Shi-Jia
collection PubMed
description In the title compound, [Fe(C(5)H(5))(C(15)H(13)O(2))], a conjugated substituent group bridges a five-membered η(5)-C(5)H(4) ring and a benzene ring. In the ferrocene unit, the substituted (Cps) and unsubstituted (Cp) cyclo­penta­dienyl rings are eclipsed and almost parallel [Cps—Fe—Cps angle = 176.1 (2)°]. The mol­ecule is linked into an S(5) motif via intra­molecular C—H⋯O hydrogen bonds. The mol­ecules are arranged into a three-dimensional framework by five inter­molecular C—H⋯O hydrogen bonds and one inter­molecular C—H⋯π(Cps) inter­action.
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spelling pubmed-29605942010-12-30 (E)-1-Ferrocenyl-3-(4-methoxy­phen­yl)­prop-2-en-1-one Long, Shi-Jia Liu, Xiao-Lan Liu, Yong-Hong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Fe(C(5)H(5))(C(15)H(13)O(2))], a conjugated substituent group bridges a five-membered η(5)-C(5)H(4) ring and a benzene ring. In the ferrocene unit, the substituted (Cps) and unsubstituted (Cp) cyclo­penta­dienyl rings are eclipsed and almost parallel [Cps—Fe—Cps angle = 176.1 (2)°]. The mol­ecule is linked into an S(5) motif via intra­molecular C—H⋯O hydrogen bonds. The mol­ecules are arranged into a three-dimensional framework by five inter­molecular C—H⋯O hydrogen bonds and one inter­molecular C—H⋯π(Cps) inter­action. International Union of Crystallography 2008-08-13 /pmc/articles/PMC2960594/ /pubmed/21201612 http://dx.doi.org/10.1107/S1600536808025518 Text en © Long et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Long, Shi-Jia
Liu, Xiao-Lan
Liu, Yong-Hong
(E)-1-Ferrocenyl-3-(4-methoxy­phen­yl)­prop-2-en-1-one
title (E)-1-Ferrocenyl-3-(4-methoxy­phen­yl)­prop-2-en-1-one
title_full (E)-1-Ferrocenyl-3-(4-methoxy­phen­yl)­prop-2-en-1-one
title_fullStr (E)-1-Ferrocenyl-3-(4-methoxy­phen­yl)­prop-2-en-1-one
title_full_unstemmed (E)-1-Ferrocenyl-3-(4-methoxy­phen­yl)­prop-2-en-1-one
title_short (E)-1-Ferrocenyl-3-(4-methoxy­phen­yl)­prop-2-en-1-one
title_sort (e)-1-ferrocenyl-3-(4-methoxy­phen­yl)­prop-2-en-1-one
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960594/
https://www.ncbi.nlm.nih.gov/pubmed/21201612
http://dx.doi.org/10.1107/S1600536808025518
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