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catena-Poly[[[diaquacopper(II)]-{μ-4,4′-[1,4-phenylenebis(methyleneimino)]dibenzoato}] monohydrate]
The asymmetric unit of the title polymeric compound, {[Cu(C(22)H(18)N(2)O(4))(H(2)O)(2)]·H(2)O}(n), contains a Cu ion situated on an inversion center, half of a centrosymmetric 4,4′-[1,4-phenylenebis(methyleneimino)]dibenzoate ligand, a coordinated water molecule in a general position and an unc...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960599/ https://www.ncbi.nlm.nih.gov/pubmed/21201580 http://dx.doi.org/10.1107/S1600536808024379 |
Sumario: | The asymmetric unit of the title polymeric compound, {[Cu(C(22)H(18)N(2)O(4))(H(2)O)(2)]·H(2)O}(n), contains a Cu ion situated on an inversion center, half of a centrosymmetric 4,4′-[1,4-phenylenebis(methyleneimino)]dibenzoate ligand, a coordinated water molecule in a general position and an uncoordinated water molecule situated on a twofold rotation axis. The distorted octahedral coordination geometry of the Cu(II) ion is formed by six O atoms. The –NH– groups of the ligand are involved in intramolecular N—H⋯O hydrogen bonds, while the water molecules participate in the formation of a three-dimensional supramolecular framework via intermolecular O—H⋯O hydrogen bonds. |
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