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catena-Poly[[[diaquacopper(II)]-{μ-4,4′-[1,4-phenylenebis(methyleneimino)]dibenzoato}] monohydrate]
The asymmetric unit of the title polymeric compound, {[Cu(C(22)H(18)N(2)O(4))(H(2)O)(2)]·H(2)O}(n), contains a Cu ion situated on an inversion center, half of a centrosymmetric 4,4′-[1,4-phenylenebis(methyleneimino)]dibenzoate ligand, a coordinated water molecule in a general position and an unc...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960599/ https://www.ncbi.nlm.nih.gov/pubmed/21201580 http://dx.doi.org/10.1107/S1600536808024379 |
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author | Wang, Qiu-sheng Ouyang, Jie |
author_facet | Wang, Qiu-sheng Ouyang, Jie |
author_sort | Wang, Qiu-sheng |
collection | PubMed |
description | The asymmetric unit of the title polymeric compound, {[Cu(C(22)H(18)N(2)O(4))(H(2)O)(2)]·H(2)O}(n), contains a Cu ion situated on an inversion center, half of a centrosymmetric 4,4′-[1,4-phenylenebis(methyleneimino)]dibenzoate ligand, a coordinated water molecule in a general position and an uncoordinated water molecule situated on a twofold rotation axis. The distorted octahedral coordination geometry of the Cu(II) ion is formed by six O atoms. The –NH– groups of the ligand are involved in intramolecular N—H⋯O hydrogen bonds, while the water molecules participate in the formation of a three-dimensional supramolecular framework via intermolecular O—H⋯O hydrogen bonds. |
format | Text |
id | pubmed-2960599 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29605992010-12-30 catena-Poly[[[diaquacopper(II)]-{μ-4,4′-[1,4-phenylenebis(methyleneimino)]dibenzoato}] monohydrate] Wang, Qiu-sheng Ouyang, Jie Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title polymeric compound, {[Cu(C(22)H(18)N(2)O(4))(H(2)O)(2)]·H(2)O}(n), contains a Cu ion situated on an inversion center, half of a centrosymmetric 4,4′-[1,4-phenylenebis(methyleneimino)]dibenzoate ligand, a coordinated water molecule in a general position and an uncoordinated water molecule situated on a twofold rotation axis. The distorted octahedral coordination geometry of the Cu(II) ion is formed by six O atoms. The –NH– groups of the ligand are involved in intramolecular N—H⋯O hydrogen bonds, while the water molecules participate in the formation of a three-dimensional supramolecular framework via intermolecular O—H⋯O hydrogen bonds. International Union of Crystallography 2008-08-06 /pmc/articles/PMC2960599/ /pubmed/21201580 http://dx.doi.org/10.1107/S1600536808024379 Text en © Wang and Ouyang 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wang, Qiu-sheng Ouyang, Jie catena-Poly[[[diaquacopper(II)]-{μ-4,4′-[1,4-phenylenebis(methyleneimino)]dibenzoato}] monohydrate] |
title |
catena-Poly[[[diaquacopper(II)]-{μ-4,4′-[1,4-phenylenebis(methyleneimino)]dibenzoato}] monohydrate] |
title_full |
catena-Poly[[[diaquacopper(II)]-{μ-4,4′-[1,4-phenylenebis(methyleneimino)]dibenzoato}] monohydrate] |
title_fullStr |
catena-Poly[[[diaquacopper(II)]-{μ-4,4′-[1,4-phenylenebis(methyleneimino)]dibenzoato}] monohydrate] |
title_full_unstemmed |
catena-Poly[[[diaquacopper(II)]-{μ-4,4′-[1,4-phenylenebis(methyleneimino)]dibenzoato}] monohydrate] |
title_short |
catena-Poly[[[diaquacopper(II)]-{μ-4,4′-[1,4-phenylenebis(methyleneimino)]dibenzoato}] monohydrate] |
title_sort | catena-poly[[[diaquacopper(ii)]-{μ-4,4′-[1,4-phenylenebis(methyleneimino)]dibenzoato}] monohydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960599/ https://www.ncbi.nlm.nih.gov/pubmed/21201580 http://dx.doi.org/10.1107/S1600536808024379 |
work_keys_str_mv | AT wangqiusheng catenapolydiaquacopperiim4414phenylenebismethyleneiminodibenzoatomonohydrate AT ouyangjie catenapolydiaquacopperiim4414phenylenebismethyleneiminodibenzoatomonohydrate |