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catena-Poly[[[diaqua­copper(II)]-{μ-4,4′-[1,4-phenyl­enebis(methyl­eneimino)]dibenzoato}] monohydrate]

The asymmetric unit of the title polymeric compound, {[Cu(C(22)H(18)N(2)O(4))(H(2)O)(2)]·H(2)O}(n), contains a Cu ion situated on an inversion center, half of a centrosymmetric 4,4′-[1,4-phenyl­enebis(methyl­eneimino)]dibenzoate ligand, a coordin­ated water mol­ecule in a general position and an unc...

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Detalles Bibliográficos
Autores principales: Wang, Qiu-sheng, Ouyang, Jie
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960599/
https://www.ncbi.nlm.nih.gov/pubmed/21201580
http://dx.doi.org/10.1107/S1600536808024379
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author Wang, Qiu-sheng
Ouyang, Jie
author_facet Wang, Qiu-sheng
Ouyang, Jie
author_sort Wang, Qiu-sheng
collection PubMed
description The asymmetric unit of the title polymeric compound, {[Cu(C(22)H(18)N(2)O(4))(H(2)O)(2)]·H(2)O}(n), contains a Cu ion situated on an inversion center, half of a centrosymmetric 4,4′-[1,4-phenyl­enebis(methyl­eneimino)]dibenzoate ligand, a coordin­ated water mol­ecule in a general position and an uncoordin­ated water mol­ecule situated on a twofold rotation axis. The distorted octa­hedral coordination geometry of the Cu(II) ion is formed by six O atoms. The –NH– groups of the ligand are involved in intra­molecular N—H⋯O hydrogen bonds, while the water mol­ecules participate in the formation of a three-dimensional supra­molecular framework via inter­molecular O—H⋯O hydrogen bonds.
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spelling pubmed-29605992010-12-30 catena-Poly[[[diaqua­copper(II)]-{μ-4,4′-[1,4-phenyl­enebis(methyl­eneimino)]dibenzoato}] monohydrate] Wang, Qiu-sheng Ouyang, Jie Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title polymeric compound, {[Cu(C(22)H(18)N(2)O(4))(H(2)O)(2)]·H(2)O}(n), contains a Cu ion situated on an inversion center, half of a centrosymmetric 4,4′-[1,4-phenyl­enebis(methyl­eneimino)]dibenzoate ligand, a coordin­ated water mol­ecule in a general position and an uncoordin­ated water mol­ecule situated on a twofold rotation axis. The distorted octa­hedral coordination geometry of the Cu(II) ion is formed by six O atoms. The –NH– groups of the ligand are involved in intra­molecular N—H⋯O hydrogen bonds, while the water mol­ecules participate in the formation of a three-dimensional supra­molecular framework via inter­molecular O—H⋯O hydrogen bonds. International Union of Crystallography 2008-08-06 /pmc/articles/PMC2960599/ /pubmed/21201580 http://dx.doi.org/10.1107/S1600536808024379 Text en © Wang and Ouyang 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Qiu-sheng
Ouyang, Jie
catena-Poly[[[diaqua­copper(II)]-{μ-4,4′-[1,4-phenyl­enebis(methyl­eneimino)]dibenzoato}] monohydrate]
title catena-Poly[[[diaqua­copper(II)]-{μ-4,4′-[1,4-phenyl­enebis(methyl­eneimino)]dibenzoato}] monohydrate]
title_full catena-Poly[[[diaqua­copper(II)]-{μ-4,4′-[1,4-phenyl­enebis(methyl­eneimino)]dibenzoato}] monohydrate]
title_fullStr catena-Poly[[[diaqua­copper(II)]-{μ-4,4′-[1,4-phenyl­enebis(methyl­eneimino)]dibenzoato}] monohydrate]
title_full_unstemmed catena-Poly[[[diaqua­copper(II)]-{μ-4,4′-[1,4-phenyl­enebis(methyl­eneimino)]dibenzoato}] monohydrate]
title_short catena-Poly[[[diaqua­copper(II)]-{μ-4,4′-[1,4-phenyl­enebis(methyl­eneimino)]dibenzoato}] monohydrate]
title_sort catena-poly[[[diaqua­copper(ii)]-{μ-4,4′-[1,4-phenyl­enebis(methyl­eneimino)]dibenzoato}] monohydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960599/
https://www.ncbi.nlm.nih.gov/pubmed/21201580
http://dx.doi.org/10.1107/S1600536808024379
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