Cargando…

Perchlorato[N,N,N′,N′-tetra­kis(2-pyridyl­meth­yl)cyclo­hexane-1,2-diamine]manganese(II) perchlorate

The asymmetric unit of the title compound, [Mn(ClO(4))(C(30)H(34)N(6))]ClO(4), consists of a cationic [Mn(ClO(4))(C(30)H(34)N(6))](+) complex and a perchlorate anion. In the complex, the Mn(2+) ion is seven-coordinated in an approximately penta­gonal–bipyramidal environment by six N atoms from the h...

Descripción completa

Detalles Bibliográficos
Autores principales: Hwang, In-Chul, Ha, Kwang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960601/
https://www.ncbi.nlm.nih.gov/pubmed/21201622
http://dx.doi.org/10.1107/S1600536808025804
Descripción
Sumario:The asymmetric unit of the title compound, [Mn(ClO(4))(C(30)H(34)N(6))]ClO(4), consists of a cationic [Mn(ClO(4))(C(30)H(34)N(6))](+) complex and a perchlorate anion. In the complex, the Mn(2+) ion is seven-coordinated in an approximately penta­gonal–bipyramidal environment by six N atoms from the hexa­dentate N,N,N′,N′-tetra­kis(2-pyridylmeth­yl)­cyclo­hexane-1,2-diamine (tpdach) ligand and one O atom from a perchlorate anion. The complex displays inter­molecular π–π inter­actions between adjacent pyridine rings (centroid-to-centroid distance 4.133 Å). Moreover, there are weak intra- and inter­molecular C—H⋯O hydrogen bonds. The Cl atom and two O atoms of the perchlorate are disordered, with a site-occupancy factor of 0.59 (2) for the major component.