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Perchlorato[N,N,N′,N′-tetra­kis(2-pyridyl­meth­yl)cyclo­hexane-1,2-diamine]manganese(II) perchlorate

The asymmetric unit of the title compound, [Mn(ClO(4))(C(30)H(34)N(6))]ClO(4), consists of a cationic [Mn(ClO(4))(C(30)H(34)N(6))](+) complex and a perchlorate anion. In the complex, the Mn(2+) ion is seven-coordinated in an approximately penta­gonal–bipyramidal environment by six N atoms from the h...

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Autores principales: Hwang, In-Chul, Ha, Kwang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960601/
https://www.ncbi.nlm.nih.gov/pubmed/21201622
http://dx.doi.org/10.1107/S1600536808025804
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author Hwang, In-Chul
Ha, Kwang
author_facet Hwang, In-Chul
Ha, Kwang
author_sort Hwang, In-Chul
collection PubMed
description The asymmetric unit of the title compound, [Mn(ClO(4))(C(30)H(34)N(6))]ClO(4), consists of a cationic [Mn(ClO(4))(C(30)H(34)N(6))](+) complex and a perchlorate anion. In the complex, the Mn(2+) ion is seven-coordinated in an approximately penta­gonal–bipyramidal environment by six N atoms from the hexa­dentate N,N,N′,N′-tetra­kis(2-pyridylmeth­yl)­cyclo­hexane-1,2-diamine (tpdach) ligand and one O atom from a perchlorate anion. The complex displays inter­molecular π–π inter­actions between adjacent pyridine rings (centroid-to-centroid distance 4.133 Å). Moreover, there are weak intra- and inter­molecular C—H⋯O hydrogen bonds. The Cl atom and two O atoms of the perchlorate are disordered, with a site-occupancy factor of 0.59 (2) for the major component.
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spelling pubmed-29606012010-12-30 Perchlorato[N,N,N′,N′-tetra­kis(2-pyridyl­meth­yl)cyclo­hexane-1,2-diamine]manganese(II) perchlorate Hwang, In-Chul Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Mn(ClO(4))(C(30)H(34)N(6))]ClO(4), consists of a cationic [Mn(ClO(4))(C(30)H(34)N(6))](+) complex and a perchlorate anion. In the complex, the Mn(2+) ion is seven-coordinated in an approximately penta­gonal–bipyramidal environment by six N atoms from the hexa­dentate N,N,N′,N′-tetra­kis(2-pyridylmeth­yl)­cyclo­hexane-1,2-diamine (tpdach) ligand and one O atom from a perchlorate anion. The complex displays inter­molecular π–π inter­actions between adjacent pyridine rings (centroid-to-centroid distance 4.133 Å). Moreover, there are weak intra- and inter­molecular C—H⋯O hydrogen bonds. The Cl atom and two O atoms of the perchlorate are disordered, with a site-occupancy factor of 0.59 (2) for the major component. International Union of Crystallography 2008-08-16 /pmc/articles/PMC2960601/ /pubmed/21201622 http://dx.doi.org/10.1107/S1600536808025804 Text en © Hwang and Ha 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hwang, In-Chul
Ha, Kwang
Perchlorato[N,N,N′,N′-tetra­kis(2-pyridyl­meth­yl)cyclo­hexane-1,2-diamine]manganese(II) perchlorate
title Perchlorato[N,N,N′,N′-tetra­kis(2-pyridyl­meth­yl)cyclo­hexane-1,2-diamine]manganese(II) perchlorate
title_full Perchlorato[N,N,N′,N′-tetra­kis(2-pyridyl­meth­yl)cyclo­hexane-1,2-diamine]manganese(II) perchlorate
title_fullStr Perchlorato[N,N,N′,N′-tetra­kis(2-pyridyl­meth­yl)cyclo­hexane-1,2-diamine]manganese(II) perchlorate
title_full_unstemmed Perchlorato[N,N,N′,N′-tetra­kis(2-pyridyl­meth­yl)cyclo­hexane-1,2-diamine]manganese(II) perchlorate
title_short Perchlorato[N,N,N′,N′-tetra­kis(2-pyridyl­meth­yl)cyclo­hexane-1,2-diamine]manganese(II) perchlorate
title_sort perchlorato[n,n,n′,n′-tetra­kis(2-pyridyl­meth­yl)cyclo­hexane-1,2-diamine]manganese(ii) perchlorate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960601/
https://www.ncbi.nlm.nih.gov/pubmed/21201622
http://dx.doi.org/10.1107/S1600536808025804
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