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Perchlorato[N,N,N′,N′-tetrakis(2-pyridylmethyl)cyclohexane-1,2-diamine]manganese(II) perchlorate
The asymmetric unit of the title compound, [Mn(ClO(4))(C(30)H(34)N(6))]ClO(4), consists of a cationic [Mn(ClO(4))(C(30)H(34)N(6))](+) complex and a perchlorate anion. In the complex, the Mn(2+) ion is seven-coordinated in an approximately pentagonal–bipyramidal environment by six N atoms from the h...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960601/ https://www.ncbi.nlm.nih.gov/pubmed/21201622 http://dx.doi.org/10.1107/S1600536808025804 |
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author | Hwang, In-Chul Ha, Kwang |
author_facet | Hwang, In-Chul Ha, Kwang |
author_sort | Hwang, In-Chul |
collection | PubMed |
description | The asymmetric unit of the title compound, [Mn(ClO(4))(C(30)H(34)N(6))]ClO(4), consists of a cationic [Mn(ClO(4))(C(30)H(34)N(6))](+) complex and a perchlorate anion. In the complex, the Mn(2+) ion is seven-coordinated in an approximately pentagonal–bipyramidal environment by six N atoms from the hexadentate N,N,N′,N′-tetrakis(2-pyridylmethyl)cyclohexane-1,2-diamine (tpdach) ligand and one O atom from a perchlorate anion. The complex displays intermolecular π–π interactions between adjacent pyridine rings (centroid-to-centroid distance 4.133 Å). Moreover, there are weak intra- and intermolecular C—H⋯O hydrogen bonds. The Cl atom and two O atoms of the perchlorate are disordered, with a site-occupancy factor of 0.59 (2) for the major component. |
format | Text |
id | pubmed-2960601 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29606012010-12-30 Perchlorato[N,N,N′,N′-tetrakis(2-pyridylmethyl)cyclohexane-1,2-diamine]manganese(II) perchlorate Hwang, In-Chul Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Mn(ClO(4))(C(30)H(34)N(6))]ClO(4), consists of a cationic [Mn(ClO(4))(C(30)H(34)N(6))](+) complex and a perchlorate anion. In the complex, the Mn(2+) ion is seven-coordinated in an approximately pentagonal–bipyramidal environment by six N atoms from the hexadentate N,N,N′,N′-tetrakis(2-pyridylmethyl)cyclohexane-1,2-diamine (tpdach) ligand and one O atom from a perchlorate anion. The complex displays intermolecular π–π interactions between adjacent pyridine rings (centroid-to-centroid distance 4.133 Å). Moreover, there are weak intra- and intermolecular C—H⋯O hydrogen bonds. The Cl atom and two O atoms of the perchlorate are disordered, with a site-occupancy factor of 0.59 (2) for the major component. International Union of Crystallography 2008-08-16 /pmc/articles/PMC2960601/ /pubmed/21201622 http://dx.doi.org/10.1107/S1600536808025804 Text en © Hwang and Ha 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Hwang, In-Chul Ha, Kwang Perchlorato[N,N,N′,N′-tetrakis(2-pyridylmethyl)cyclohexane-1,2-diamine]manganese(II) perchlorate |
title | Perchlorato[N,N,N′,N′-tetrakis(2-pyridylmethyl)cyclohexane-1,2-diamine]manganese(II) perchlorate |
title_full | Perchlorato[N,N,N′,N′-tetrakis(2-pyridylmethyl)cyclohexane-1,2-diamine]manganese(II) perchlorate |
title_fullStr | Perchlorato[N,N,N′,N′-tetrakis(2-pyridylmethyl)cyclohexane-1,2-diamine]manganese(II) perchlorate |
title_full_unstemmed | Perchlorato[N,N,N′,N′-tetrakis(2-pyridylmethyl)cyclohexane-1,2-diamine]manganese(II) perchlorate |
title_short | Perchlorato[N,N,N′,N′-tetrakis(2-pyridylmethyl)cyclohexane-1,2-diamine]manganese(II) perchlorate |
title_sort | perchlorato[n,n,n′,n′-tetrakis(2-pyridylmethyl)cyclohexane-1,2-diamine]manganese(ii) perchlorate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960601/ https://www.ncbi.nlm.nih.gov/pubmed/21201622 http://dx.doi.org/10.1107/S1600536808025804 |
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